Dielectric, Thermodynamic, and Computational Studies of Hydrogen Bonded Binary Mixtures of N-Methylaniline with Propan-1-ol and Isopropyl Alcohol
The molecular interactions between the polar systems N-methylaniline with alcohols, propan-1-ol, and isopropyl alcohol for various mole fractions at different temperatures are studied by determining the dielectric permittivity using LF impedance analyzer, microwave bench, and Abbe's refractomet...
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| Format: | Article |
| Language: | English |
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Wiley
2013-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2013/425893 |
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| author | T. Vijaya Krishna S. Sreehari Sastry Sie Tiong Ha V. R. K. Murthy |
| author_facet | T. Vijaya Krishna S. Sreehari Sastry Sie Tiong Ha V. R. K. Murthy |
| author_sort | T. Vijaya Krishna |
| collection | DOAJ |
| description | The molecular interactions between the polar systems N-methylaniline with alcohols, propan-1-ol, and isopropyl alcohol for various mole fractions at different temperatures are studied by determining the dielectric permittivity using LF impedance analyzer, microwave bench, and Abbe's refractometer in radio, microwave, and optic frequency regions, respectively. Dipole moment, excess dipole moment, excess Helmholtz free energy, excess permittivity, excess inverse relaxation time, and excess thermodynamical values are calculated using experimental data. Hamiltonian quantum mechanical calculations are performed using PC Spartan and ArgusLab modeling softwares for both pure and equimolar binary systems of N-methyl aniline with alcohols. |
| format | Article |
| id | doaj-art-bf36734faa4a4a7c8a86bfb593004fa1 |
| institution | DOAJ |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2013-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-bf36734faa4a4a7c8a86bfb593004fa12025-08-20T03:23:10ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/425893425893Dielectric, Thermodynamic, and Computational Studies of Hydrogen Bonded Binary Mixtures of N-Methylaniline with Propan-1-ol and Isopropyl AlcoholT. Vijaya Krishna0S. Sreehari Sastry1Sie Tiong Ha2V. R. K. Murthy3Department of Physics, Vasireddy Venkatadri Institute of Technology, Nambur 522508, IndiaDepartment of Physics, Acharya Nagarjuna University, Nagarjunanagar 522510, IndiaDepartment of Chemical Science, Faculty of Science, University Tunku Abdul Rahman, Jalan University, Bandar Barat, 31900 Kampar, MalaysiaDepartment of Physics, Indian Institute of Technology, Chennai 600036, IndiaThe molecular interactions between the polar systems N-methylaniline with alcohols, propan-1-ol, and isopropyl alcohol for various mole fractions at different temperatures are studied by determining the dielectric permittivity using LF impedance analyzer, microwave bench, and Abbe's refractometer in radio, microwave, and optic frequency regions, respectively. Dipole moment, excess dipole moment, excess Helmholtz free energy, excess permittivity, excess inverse relaxation time, and excess thermodynamical values are calculated using experimental data. Hamiltonian quantum mechanical calculations are performed using PC Spartan and ArgusLab modeling softwares for both pure and equimolar binary systems of N-methyl aniline with alcohols.http://dx.doi.org/10.1155/2013/425893 |
| spellingShingle | T. Vijaya Krishna S. Sreehari Sastry Sie Tiong Ha V. R. K. Murthy Dielectric, Thermodynamic, and Computational Studies of Hydrogen Bonded Binary Mixtures of N-Methylaniline with Propan-1-ol and Isopropyl Alcohol Journal of Chemistry |
| title | Dielectric, Thermodynamic, and Computational Studies of Hydrogen Bonded Binary Mixtures of N-Methylaniline with Propan-1-ol and Isopropyl Alcohol |
| title_full | Dielectric, Thermodynamic, and Computational Studies of Hydrogen Bonded Binary Mixtures of N-Methylaniline with Propan-1-ol and Isopropyl Alcohol |
| title_fullStr | Dielectric, Thermodynamic, and Computational Studies of Hydrogen Bonded Binary Mixtures of N-Methylaniline with Propan-1-ol and Isopropyl Alcohol |
| title_full_unstemmed | Dielectric, Thermodynamic, and Computational Studies of Hydrogen Bonded Binary Mixtures of N-Methylaniline with Propan-1-ol and Isopropyl Alcohol |
| title_short | Dielectric, Thermodynamic, and Computational Studies of Hydrogen Bonded Binary Mixtures of N-Methylaniline with Propan-1-ol and Isopropyl Alcohol |
| title_sort | dielectric thermodynamic and computational studies of hydrogen bonded binary mixtures of n methylaniline with propan 1 ol and isopropyl alcohol |
| url | http://dx.doi.org/10.1155/2013/425893 |
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