Ru (III) Catalyzed Oxidation of Aliphatic Ketones by N-Bromosuccinimide in Aqueous Acetic Acid: A Kinetic Study
Kinetics of Ru (III) catalyzed oxidation of aliphatic ketones such as acetone, ethyl methyl ketone, diethyl ketone, iso-butylmethyl ketone by N-bromosuccinimide in the presence of Hg(II) acetate have been studied in aqueous acid medium. The order of [N-bromosuccinimide] was found to be zero both in...
Saved in:
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2012-01-01
|
| Series: | The Scientific World Journal |
| Online Access: | http://dx.doi.org/10.1100/2012/456516 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832554383765667840 |
|---|---|
| author | P. Giridhar Reddy K. Ramesh S. Shylaja K. C. Rajanna S. Kandlikar |
| author_facet | P. Giridhar Reddy K. Ramesh S. Shylaja K. C. Rajanna S. Kandlikar |
| author_sort | P. Giridhar Reddy |
| collection | DOAJ |
| description | Kinetics of Ru (III) catalyzed oxidation of aliphatic ketones such as acetone, ethyl methyl ketone, diethyl ketone, iso-butylmethyl ketone by N-bromosuccinimide in the presence of Hg(II) acetate have been studied in aqueous acid medium. The order of [N-bromosuccinimide] was found to be zero both in catalyzed as well as uncatalyzed reactions. However, the order of [ketone] changed from unity to a fractional one in the presence of Ru (III). On the basis of kinetic features, the probable mechanisms are discussed and individual rate parameters evaluated. |
| format | Article |
| id | doaj-art-bef45f3897054a4ebf36c5aa3c94d59c |
| institution | Kabale University |
| issn | 1537-744X |
| language | English |
| publishDate | 2012-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | The Scientific World Journal |
| spelling | doaj-art-bef45f3897054a4ebf36c5aa3c94d59c2025-02-03T05:51:42ZengWileyThe Scientific World Journal1537-744X2012-01-01201210.1100/2012/456516456516Ru (III) Catalyzed Oxidation of Aliphatic Ketones by N-Bromosuccinimide in Aqueous Acetic Acid: A Kinetic StudyP. Giridhar Reddy0K. Ramesh1S. Shylaja2K. C. Rajanna3S. Kandlikar4Department of Chemistry, Osmania University, Hyderabad 500 007, IndiaDepartment of Chemistry, Osmania University, Hyderabad 500 007, IndiaDepartment of Chemistry, Osmania University, Hyderabad 500 007, IndiaDepartment of Chemistry, Osmania University, Hyderabad 500 007, IndiaDepartment of Chemistry, Osmania University, Hyderabad 500 007, IndiaKinetics of Ru (III) catalyzed oxidation of aliphatic ketones such as acetone, ethyl methyl ketone, diethyl ketone, iso-butylmethyl ketone by N-bromosuccinimide in the presence of Hg(II) acetate have been studied in aqueous acid medium. The order of [N-bromosuccinimide] was found to be zero both in catalyzed as well as uncatalyzed reactions. However, the order of [ketone] changed from unity to a fractional one in the presence of Ru (III). On the basis of kinetic features, the probable mechanisms are discussed and individual rate parameters evaluated.http://dx.doi.org/10.1100/2012/456516 |
| spellingShingle | P. Giridhar Reddy K. Ramesh S. Shylaja K. C. Rajanna S. Kandlikar Ru (III) Catalyzed Oxidation of Aliphatic Ketones by N-Bromosuccinimide in Aqueous Acetic Acid: A Kinetic Study The Scientific World Journal |
| title | Ru (III) Catalyzed Oxidation of Aliphatic Ketones by N-Bromosuccinimide in Aqueous Acetic Acid: A Kinetic Study |
| title_full | Ru (III) Catalyzed Oxidation of Aliphatic Ketones by N-Bromosuccinimide in Aqueous Acetic Acid: A Kinetic Study |
| title_fullStr | Ru (III) Catalyzed Oxidation of Aliphatic Ketones by N-Bromosuccinimide in Aqueous Acetic Acid: A Kinetic Study |
| title_full_unstemmed | Ru (III) Catalyzed Oxidation of Aliphatic Ketones by N-Bromosuccinimide in Aqueous Acetic Acid: A Kinetic Study |
| title_short | Ru (III) Catalyzed Oxidation of Aliphatic Ketones by N-Bromosuccinimide in Aqueous Acetic Acid: A Kinetic Study |
| title_sort | ru iii catalyzed oxidation of aliphatic ketones by n bromosuccinimide in aqueous acetic acid a kinetic study |
| url | http://dx.doi.org/10.1100/2012/456516 |
| work_keys_str_mv | AT pgiridharreddy ruiiicatalyzedoxidationofaliphaticketonesbynbromosuccinimideinaqueousaceticacidakineticstudy AT kramesh ruiiicatalyzedoxidationofaliphaticketonesbynbromosuccinimideinaqueousaceticacidakineticstudy AT sshylaja ruiiicatalyzedoxidationofaliphaticketonesbynbromosuccinimideinaqueousaceticacidakineticstudy AT kcrajanna ruiiicatalyzedoxidationofaliphaticketonesbynbromosuccinimideinaqueousaceticacidakineticstudy AT skandlikar ruiiicatalyzedoxidationofaliphaticketonesbynbromosuccinimideinaqueousaceticacidakineticstudy |