PRODUÇÃO DE BIONAFTA A PARTIR DE ÁLCOOIS PRIMÁRIOS (C3-C5) VIA PROCESSOS DE DESIDROGENAÇÃO/DESIDRATAÇÃO CATALÍTICA
PRODUCTION OF BIONAPHTHA FROM (C3-C5) PRIMARY ALCOHOLS VIA CATALYTIC DEHYDROGENATION/DEHYDRATION PROCESSES. A sequence of dehydrogenation/dehydration reactions of homologous alcohols: propanol, butanol and pentanol was conducted using heterogeneous catalysts composed of mixed metal oxides basically...
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| Format: | Article |
| Language: | English |
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Sociedade Brasileira de Química
2025-02-01
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| Series: | Química Nova |
| Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422025000400306&lng=pt&tlng=pt |
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| author | Adônis Coelho Gustavo Metzker Lívia P. de Lima Eleni Gomes Mauricio Boscolo |
| author_facet | Adônis Coelho Gustavo Metzker Lívia P. de Lima Eleni Gomes Mauricio Boscolo |
| author_sort | Adônis Coelho |
| collection | DOAJ |
| description | PRODUCTION OF BIONAPHTHA FROM (C3-C5) PRIMARY ALCOHOLS VIA CATALYTIC DEHYDROGENATION/DEHYDRATION PROCESSES. A sequence of dehydrogenation/dehydration reactions of homologous alcohols: propanol, butanol and pentanol was conducted using heterogeneous catalysts composed of mixed metal oxides basically of Mg and Al derived from hydrotalcites in the ratio M2+/Al3+ = 3, with 10 and 20% of the Mg substituted by Cu. The reactions were carried out in a fixed-bed reactor over a duration of 6 h at temperatures of 450 and 500 °C and yielded products of significant interest to the chemical industry. Product identification and quantification were achieved through gas chromatography coupled with mass spectrometry (GC-MS). A range of compounds were obtained, including alcohols, aldehydes, ethers, carboxylic acids, ketones, and hydrocarbons, with condensed alcohols and aldehydes being the predominant products. Reaction pathways were proposed for conversion of alcohols into their respective products, based on the Guerbet reaction mechanism. Catalysts containing copper proved to be more efficient in selectivity and stability throughout the reaction. |
| format | Article |
| id | doaj-art-beef5f58ef3846f2ad056832ff806ef7 |
| institution | Kabale University |
| issn | 1678-7064 |
| language | English |
| publishDate | 2025-02-01 |
| publisher | Sociedade Brasileira de Química |
| record_format | Article |
| series | Química Nova |
| spelling | doaj-art-beef5f58ef3846f2ad056832ff806ef72025-02-04T07:39:26ZengSociedade Brasileira de QuímicaQuímica Nova1678-70642025-02-0148410.21577/0100-4042.20250094PRODUÇÃO DE BIONAFTA A PARTIR DE ÁLCOOIS PRIMÁRIOS (C3-C5) VIA PROCESSOS DE DESIDROGENAÇÃO/DESIDRATAÇÃO CATALÍTICAAdônis CoelhoGustavo Metzkerhttps://orcid.org/0000-0002-1586-7462Lívia P. de Limahttps://orcid.org/0000-0002-2565-644XEleni GomesMauricio Boscolohttps://orcid.org/0000-0003-4541-6352PRODUCTION OF BIONAPHTHA FROM (C3-C5) PRIMARY ALCOHOLS VIA CATALYTIC DEHYDROGENATION/DEHYDRATION PROCESSES. A sequence of dehydrogenation/dehydration reactions of homologous alcohols: propanol, butanol and pentanol was conducted using heterogeneous catalysts composed of mixed metal oxides basically of Mg and Al derived from hydrotalcites in the ratio M2+/Al3+ = 3, with 10 and 20% of the Mg substituted by Cu. The reactions were carried out in a fixed-bed reactor over a duration of 6 h at temperatures of 450 and 500 °C and yielded products of significant interest to the chemical industry. Product identification and quantification were achieved through gas chromatography coupled with mass spectrometry (GC-MS). A range of compounds were obtained, including alcohols, aldehydes, ethers, carboxylic acids, ketones, and hydrocarbons, with condensed alcohols and aldehydes being the predominant products. Reaction pathways were proposed for conversion of alcohols into their respective products, based on the Guerbet reaction mechanism. Catalysts containing copper proved to be more efficient in selectivity and stability throughout the reaction.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422025000400306&lng=pt&tlng=pt |
| spellingShingle | Adônis Coelho Gustavo Metzker Lívia P. de Lima Eleni Gomes Mauricio Boscolo PRODUÇÃO DE BIONAFTA A PARTIR DE ÁLCOOIS PRIMÁRIOS (C3-C5) VIA PROCESSOS DE DESIDROGENAÇÃO/DESIDRATAÇÃO CATALÍTICA Química Nova |
| title | PRODUÇÃO DE BIONAFTA A PARTIR DE ÁLCOOIS PRIMÁRIOS (C3-C5) VIA PROCESSOS DE DESIDROGENAÇÃO/DESIDRATAÇÃO CATALÍTICA |
| title_full | PRODUÇÃO DE BIONAFTA A PARTIR DE ÁLCOOIS PRIMÁRIOS (C3-C5) VIA PROCESSOS DE DESIDROGENAÇÃO/DESIDRATAÇÃO CATALÍTICA |
| title_fullStr | PRODUÇÃO DE BIONAFTA A PARTIR DE ÁLCOOIS PRIMÁRIOS (C3-C5) VIA PROCESSOS DE DESIDROGENAÇÃO/DESIDRATAÇÃO CATALÍTICA |
| title_full_unstemmed | PRODUÇÃO DE BIONAFTA A PARTIR DE ÁLCOOIS PRIMÁRIOS (C3-C5) VIA PROCESSOS DE DESIDROGENAÇÃO/DESIDRATAÇÃO CATALÍTICA |
| title_short | PRODUÇÃO DE BIONAFTA A PARTIR DE ÁLCOOIS PRIMÁRIOS (C3-C5) VIA PROCESSOS DE DESIDROGENAÇÃO/DESIDRATAÇÃO CATALÍTICA |
| title_sort | producao de bionafta a partir de alcoois primarios c3 c5 via processos de desidrogenacao desidratacao catalitica |
| url | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422025000400306&lng=pt&tlng=pt |
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