Synthesis, Characterization, and Thermal Decomposition Kinetics of Manganese Complex of Methionine Hydroxy Analogue
The manganese complex of methionine hydroxy analogue was synthesized with methionine hydroxy analogue and manganese chloride as main raw materials. The composition and structure of the complex were characterized by elemental analyses, infrared spectra, and X-ray powder diffraction. The formula of th...
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| Format: | Article |
| Language: | English |
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Wiley
2015-01-01
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| Series: | International Journal of Chemical Engineering |
| Online Access: | http://dx.doi.org/10.1155/2015/874340 |
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| author | Mei-Ling Wang Zhi-Xian Wu Qing Zang Guo-Qing Zhong |
| author_facet | Mei-Ling Wang Zhi-Xian Wu Qing Zang Guo-Qing Zhong |
| author_sort | Mei-Ling Wang |
| collection | DOAJ |
| description | The manganese complex of methionine hydroxy analogue was synthesized with methionine hydroxy analogue and manganese chloride as main raw materials. The composition and structure of the complex were characterized by elemental analyses, infrared spectra, and X-ray powder diffraction. The formula of the complex was Mn(C5H9O3S)2. The experimental results indicated that the manganese ion was, respectively, coordinated by the carboxylic and hydroxyl oxygen atoms from the methionine hydroxy analogue ligand. The crystal structure of the complex belonged to monoclinic system with the lattice parameters of a = 1.2775 nm, b = 1.5764 nm, c = 1.5764 nm, and β = 94.06°. The thermal decomposition process of the complex was studied by thermogravimetry and differential thermal analysis. The decomposition of the complex has taken place above 200°C. The residue was mainly manganese sulfide, and the experimental and calculated percentage mass loss was also given. The parameters of thermal decomposition kinetics for the complex, such as activation energy, reaction order, and preexponential factor, were calculated by using Kissinger, Flynn-Wall-Ozawa, and Freeman-Carroll methods, and the kinetic equations of the thermal decomposition were obtained. |
| format | Article |
| id | doaj-art-bdd9a03e8f6b4adc8ddd9b90147901f8 |
| institution | Kabale University |
| issn | 1687-806X 1687-8078 |
| language | English |
| publishDate | 2015-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Chemical Engineering |
| spelling | doaj-art-bdd9a03e8f6b4adc8ddd9b90147901f82025-02-03T05:52:47ZengWileyInternational Journal of Chemical Engineering1687-806X1687-80782015-01-01201510.1155/2015/874340874340Synthesis, Characterization, and Thermal Decomposition Kinetics of Manganese Complex of Methionine Hydroxy AnalogueMei-Ling Wang0Zhi-Xian Wu1Qing Zang2Guo-Qing Zhong3School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, ChinaSchool of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, ChinaSchool of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, ChinaSchool of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, ChinaThe manganese complex of methionine hydroxy analogue was synthesized with methionine hydroxy analogue and manganese chloride as main raw materials. The composition and structure of the complex were characterized by elemental analyses, infrared spectra, and X-ray powder diffraction. The formula of the complex was Mn(C5H9O3S)2. The experimental results indicated that the manganese ion was, respectively, coordinated by the carboxylic and hydroxyl oxygen atoms from the methionine hydroxy analogue ligand. The crystal structure of the complex belonged to monoclinic system with the lattice parameters of a = 1.2775 nm, b = 1.5764 nm, c = 1.5764 nm, and β = 94.06°. The thermal decomposition process of the complex was studied by thermogravimetry and differential thermal analysis. The decomposition of the complex has taken place above 200°C. The residue was mainly manganese sulfide, and the experimental and calculated percentage mass loss was also given. The parameters of thermal decomposition kinetics for the complex, such as activation energy, reaction order, and preexponential factor, were calculated by using Kissinger, Flynn-Wall-Ozawa, and Freeman-Carroll methods, and the kinetic equations of the thermal decomposition were obtained.http://dx.doi.org/10.1155/2015/874340 |
| spellingShingle | Mei-Ling Wang Zhi-Xian Wu Qing Zang Guo-Qing Zhong Synthesis, Characterization, and Thermal Decomposition Kinetics of Manganese Complex of Methionine Hydroxy Analogue International Journal of Chemical Engineering |
| title | Synthesis, Characterization, and Thermal Decomposition Kinetics of Manganese Complex of Methionine Hydroxy Analogue |
| title_full | Synthesis, Characterization, and Thermal Decomposition Kinetics of Manganese Complex of Methionine Hydroxy Analogue |
| title_fullStr | Synthesis, Characterization, and Thermal Decomposition Kinetics of Manganese Complex of Methionine Hydroxy Analogue |
| title_full_unstemmed | Synthesis, Characterization, and Thermal Decomposition Kinetics of Manganese Complex of Methionine Hydroxy Analogue |
| title_short | Synthesis, Characterization, and Thermal Decomposition Kinetics of Manganese Complex of Methionine Hydroxy Analogue |
| title_sort | synthesis characterization and thermal decomposition kinetics of manganese complex of methionine hydroxy analogue |
| url | http://dx.doi.org/10.1155/2015/874340 |
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