Photocatalytic Degradation of Organic Dyes under Visible Light on N-Doped TiO2 Photocatalysts

This study was focused on the application of white and blue light emitting diodes (LEDs) as sources for the photocatalytic degradation of organic dyes in liquid phase with visible light. The photocatalytic activity of N-doped titanium dioxide, synthesized by direct hydrolysis of titanium tetraisopro...

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Main Authors: Olga Sacco, Marco Stoller, Vincenzo Vaiano, Paolo Ciambelli, Angelo Chianese, Diana Sannino
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2012/626759
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author Olga Sacco
Marco Stoller
Vincenzo Vaiano
Paolo Ciambelli
Angelo Chianese
Diana Sannino
author_facet Olga Sacco
Marco Stoller
Vincenzo Vaiano
Paolo Ciambelli
Angelo Chianese
Diana Sannino
author_sort Olga Sacco
collection DOAJ
description This study was focused on the application of white and blue light emitting diodes (LEDs) as sources for the photocatalytic degradation of organic dyes in liquid phase with visible light. The photocatalytic activity of N-doped titanium dioxide, synthesized by direct hydrolysis of titanium tetraisopropoxide with ammonia, was evaluated by means of a batch photoreactor. The bandgap energy of titanium dioxide was moved in the visible range from 3.3 eV to 2.5 eV. The visible light responsive photocatalysts showed remarkably effective activity in decolorization process and in the removal of total organic carbon. Methylene blue was also used as a model dye to study the influence of several parameters such as catalyst weight and initial concentration. The effect of dye on the photocatalytic performance was verified with methyl orange (MO). The results demonstrated that the right selection of operating conditions allows to effectively degrade different dyes with the N-doped TiO2 photocatalysts irradiated with visible light emitted by LEDs.
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institution Kabale University
issn 1110-662X
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language English
publishDate 2012-01-01
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series International Journal of Photoenergy
spelling doaj-art-bdc31b54ec624ebe956ac3c5e6aa50602025-02-03T01:30:10ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2012-01-01201210.1155/2012/626759626759Photocatalytic Degradation of Organic Dyes under Visible Light on N-Doped TiO2 PhotocatalystsOlga Sacco0Marco Stoller1Vincenzo Vaiano2Paolo Ciambelli3Angelo Chianese4Diana Sannino5Department of Industrial Engineering, University of Salerno, Via Ponte Don Melillo, Salerno, 84084 Fisciano, ItalyDepartment of Chemical Engineering, University of Rome “La Sapienza”, Via Eudossiana 18, 00184 Rome, ItalyDepartment of Industrial Engineering, University of Salerno, Via Ponte Don Melillo, Salerno, 84084 Fisciano, ItalyDepartment of Industrial Engineering, University of Salerno, Via Ponte Don Melillo, Salerno, 84084 Fisciano, ItalyDepartment of Chemical Engineering, University of Rome “La Sapienza”, Via Eudossiana 18, 00184 Rome, ItalyDepartment of Industrial Engineering, University of Salerno, Via Ponte Don Melillo, Salerno, 84084 Fisciano, ItalyThis study was focused on the application of white and blue light emitting diodes (LEDs) as sources for the photocatalytic degradation of organic dyes in liquid phase with visible light. The photocatalytic activity of N-doped titanium dioxide, synthesized by direct hydrolysis of titanium tetraisopropoxide with ammonia, was evaluated by means of a batch photoreactor. The bandgap energy of titanium dioxide was moved in the visible range from 3.3 eV to 2.5 eV. The visible light responsive photocatalysts showed remarkably effective activity in decolorization process and in the removal of total organic carbon. Methylene blue was also used as a model dye to study the influence of several parameters such as catalyst weight and initial concentration. The effect of dye on the photocatalytic performance was verified with methyl orange (MO). The results demonstrated that the right selection of operating conditions allows to effectively degrade different dyes with the N-doped TiO2 photocatalysts irradiated with visible light emitted by LEDs.http://dx.doi.org/10.1155/2012/626759
spellingShingle Olga Sacco
Marco Stoller
Vincenzo Vaiano
Paolo Ciambelli
Angelo Chianese
Diana Sannino
Photocatalytic Degradation of Organic Dyes under Visible Light on N-Doped TiO2 Photocatalysts
International Journal of Photoenergy
title Photocatalytic Degradation of Organic Dyes under Visible Light on N-Doped TiO2 Photocatalysts
title_full Photocatalytic Degradation of Organic Dyes under Visible Light on N-Doped TiO2 Photocatalysts
title_fullStr Photocatalytic Degradation of Organic Dyes under Visible Light on N-Doped TiO2 Photocatalysts
title_full_unstemmed Photocatalytic Degradation of Organic Dyes under Visible Light on N-Doped TiO2 Photocatalysts
title_short Photocatalytic Degradation of Organic Dyes under Visible Light on N-Doped TiO2 Photocatalysts
title_sort photocatalytic degradation of organic dyes under visible light on n doped tio2 photocatalysts
url http://dx.doi.org/10.1155/2012/626759
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AT marcostoller photocatalyticdegradationoforganicdyesundervisiblelightonndopedtio2photocatalysts
AT vincenzovaiano photocatalyticdegradationoforganicdyesundervisiblelightonndopedtio2photocatalysts
AT paolociambelli photocatalyticdegradationoforganicdyesundervisiblelightonndopedtio2photocatalysts
AT angelochianese photocatalyticdegradationoforganicdyesundervisiblelightonndopedtio2photocatalysts
AT dianasannino photocatalyticdegradationoforganicdyesundervisiblelightonndopedtio2photocatalysts