Performance evaluation of biomass-derived hydrothermal carbonaceous material in cement based composites

Reducing CO2 emissions from cement production can be achieved by incorporating carbonaceous materials as partial replacements for traditional cement. However, the effects of these particles on cement composites are not fully understood. This study explores the potential of hydrothermally carbonized...

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Main Authors: Monika Sharma, İrfan Şehrullah Öztürk, Mehmet Emiroğlu, Aliye Suna Erses Yay
Format: Article
Language:English
Published: Elsevier 2025-07-01
Series:Case Studies in Construction Materials
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Online Access:http://www.sciencedirect.com/science/article/pii/S2214509525000907
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author Monika Sharma
İrfan Şehrullah Öztürk
Mehmet Emiroğlu
Aliye Suna Erses Yay
author_facet Monika Sharma
İrfan Şehrullah Öztürk
Mehmet Emiroğlu
Aliye Suna Erses Yay
author_sort Monika Sharma
collection DOAJ
description Reducing CO2 emissions from cement production can be achieved by incorporating carbonaceous materials as partial replacements for traditional cement. However, the effects of these particles on cement composites are not fully understood. This study explores the potential of hydrothermally carbonized nanospheres (HCN) obtained through green synthesis from discarded pomegranate peel as a partial replacement for cement. HCN were added to cement using two mixing techniques: dry mixing and wet mixing in four dosages: 0.1 %, 0.25 %, 0.5 %, and 1 % by weight, replacing cement. The study investigated the impact of both HCN dosages and mixing techniques on the 7- and 28-day properties of the cement composites. Workability improved for all samples while density decreased upto 6.67 % after 7 days and upto ≅ 5 % after 28 days. Wet-mixed samples showed significant increases in flexural strength after 7 days, with the HCN0.1 %W sample showing a 37.18 % increase, while the dry-mixed HCN1 %D sample showed a 25.34 % increase. There was a reduction in compressive strength for all samples, but it remained within a comparable range, with a significant increase from 7 to 28 days, reaching up to 70.93 % for the HCN0.5 %W sample. Overall, HCN has the potential to significantly affect the properties of cement composites even at very low doses, however, it should be properly optimized to enhance the properties of the cement composite as well as contribute to sustainability.
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spelling doaj-art-bdb113c2c00c4f6b8d0e34fc19b34d5c2025-01-28T04:14:37ZengElsevierCase Studies in Construction Materials2214-50952025-07-0122e04291Performance evaluation of biomass-derived hydrothermal carbonaceous material in cement based compositesMonika Sharma0İrfan Şehrullah Öztürk1Mehmet Emiroğlu2Aliye Suna Erses Yay3Sakarya University, Department of Nanoscience and Nanoengineering, Sakarya, Turkey; Sakarya University Research, Development and Application Center (SARGEM), Sakarya, TurkeySakarya University, Civil Engineering Department, Sakarya, TurkeySakarya University, Civil Engineering Department, Sakarya, TurkeySakarya University, Environmental Engineering Department, Sakarya, Turkey; Sakarya University Research, Development and Application Center (SARGEM), Sakarya, Turkey; Corresponding author at: Sakarya University, Environmental Engineering Department, Sakarya, Turkey.Reducing CO2 emissions from cement production can be achieved by incorporating carbonaceous materials as partial replacements for traditional cement. However, the effects of these particles on cement composites are not fully understood. This study explores the potential of hydrothermally carbonized nanospheres (HCN) obtained through green synthesis from discarded pomegranate peel as a partial replacement for cement. HCN were added to cement using two mixing techniques: dry mixing and wet mixing in four dosages: 0.1 %, 0.25 %, 0.5 %, and 1 % by weight, replacing cement. The study investigated the impact of both HCN dosages and mixing techniques on the 7- and 28-day properties of the cement composites. Workability improved for all samples while density decreased upto 6.67 % after 7 days and upto ≅ 5 % after 28 days. Wet-mixed samples showed significant increases in flexural strength after 7 days, with the HCN0.1 %W sample showing a 37.18 % increase, while the dry-mixed HCN1 %D sample showed a 25.34 % increase. There was a reduction in compressive strength for all samples, but it remained within a comparable range, with a significant increase from 7 to 28 days, reaching up to 70.93 % for the HCN0.5 %W sample. Overall, HCN has the potential to significantly affect the properties of cement composites even at very low doses, however, it should be properly optimized to enhance the properties of the cement composite as well as contribute to sustainability.http://www.sciencedirect.com/science/article/pii/S2214509525000907Hydrothermal carbonizationCarbon-cement compositesCarbonaceous nanospheresBiomass valorizationSustainable construction
spellingShingle Monika Sharma
İrfan Şehrullah Öztürk
Mehmet Emiroğlu
Aliye Suna Erses Yay
Performance evaluation of biomass-derived hydrothermal carbonaceous material in cement based composites
Case Studies in Construction Materials
Hydrothermal carbonization
Carbon-cement composites
Carbonaceous nanospheres
Biomass valorization
Sustainable construction
title Performance evaluation of biomass-derived hydrothermal carbonaceous material in cement based composites
title_full Performance evaluation of biomass-derived hydrothermal carbonaceous material in cement based composites
title_fullStr Performance evaluation of biomass-derived hydrothermal carbonaceous material in cement based composites
title_full_unstemmed Performance evaluation of biomass-derived hydrothermal carbonaceous material in cement based composites
title_short Performance evaluation of biomass-derived hydrothermal carbonaceous material in cement based composites
title_sort performance evaluation of biomass derived hydrothermal carbonaceous material in cement based composites
topic Hydrothermal carbonization
Carbon-cement composites
Carbonaceous nanospheres
Biomass valorization
Sustainable construction
url http://www.sciencedirect.com/science/article/pii/S2214509525000907
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AT mehmetemiroglu performanceevaluationofbiomassderivedhydrothermalcarbonaceousmaterialincementbasedcomposites
AT aliyesunaersesyay performanceevaluationofbiomassderivedhydrothermalcarbonaceousmaterialincementbasedcomposites