Synthesis and Characterization of New Schiff Bases Derived from N (1)-Substituted Isatin with Dithiooxamide and Their Co(II), Ni(II), Cu(II), Pd(II), and Pt(IV) Complexes
Three new Schiff bases of N-substituted isatin LI, LII, and LIII = Schiff base of N-acetylisatin, N-benzylisatin, and N-benzoylisatin, respectively, and their metal complexes C1a,b=[Co2(LI)2Cl3]Cl, C2=[Ni(LI)2Cl2]0.4BuOH, C3=[CuLICl(H2O)]Cl⋅0.5BuOH, C4=[Pd(LI)2Cl]Cl, C5=[Pt(L1)2Cl2]Cl2⋅1.8EtO...
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| Format: | Article |
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Wiley
2009-01-01
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| Series: | Bioinorganic Chemistry and Applications |
| Online Access: | http://dx.doi.org/10.1155/2009/413175 |
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| author | Ahlam J. Abdul-Ghani Asmaa M. N. Khaleel |
| author_facet | Ahlam J. Abdul-Ghani Asmaa M. N. Khaleel |
| author_sort | Ahlam J. Abdul-Ghani |
| collection | DOAJ |
| description | Three new Schiff bases of N-substituted isatin LI, LII, and LIII = Schiff base of N-acetylisatin, N-benzylisatin, and N-benzoylisatin, respectively, and their metal complexes C1a,b=[Co2(LI)2Cl3]Cl, C2=[Ni(LI)2Cl2]0.4BuOH, C3=[CuLICl(H2O)]Cl⋅0.5BuOH,
C4=[Pd(LI)2Cl]Cl, C5=[Pt(L1)2Cl2]Cl2⋅1.8EtOH.H2O, C6a=[CoLIICl]Cl⋅0.4H2O⋅0.3DMSO, C6b=[CoLIICl]Cl⋅0.3H2O⋅0.1BuOH,C7=[NiLIICl2], C8=[CuLII]Cl2⋅H2O0𝑥000𝑎0, C9=[Pd(LII)2]Cl2, C10=[Pt(LII)2.5Cl]Cl3, C11a=[Co(LIII)]C12⋅H2O, C11b=[Co(LIII)]Cl2⋅0.2H2O, and C12=[Ni(LIII)2]Cl2, C13=[Ni(LIII)2]Cl2 were reported. The complexes were characterized by elemental analyses, metal and chloride content, spectroscopic methods, magnetic moments, conductivity measurements, and thermal studies. Some of these compounds were tested as antibacterial and antifungal agents against Staphylococcus aureus, Proteus vulgaris, Candida albicans, and Aspergillus niger. |
| format | Article |
| id | doaj-art-bdabb269d63a4e3591f6b781aae802b8 |
| institution | Kabale University |
| issn | 1565-3633 1687-479X |
| language | English |
| publishDate | 2009-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Bioinorganic Chemistry and Applications |
| spelling | doaj-art-bdabb269d63a4e3591f6b781aae802b82025-02-03T05:48:15ZengWileyBioinorganic Chemistry and Applications1565-36331687-479X2009-01-01200910.1155/2009/413175413175Synthesis and Characterization of New Schiff Bases Derived from N (1)-Substituted Isatin with Dithiooxamide and Their Co(II), Ni(II), Cu(II), Pd(II), and Pt(IV) ComplexesAhlam J. Abdul-Ghani0Asmaa M. N. Khaleel1Department of Chemistry, College of Science, University of Baghdad, Jaderiya, P.O. Box 47059 Baghdad, IraqDepartment of Chemistry, College of Science, University of Baghdad, Jaderiya, P.O. Box 47059 Baghdad, IraqThree new Schiff bases of N-substituted isatin LI, LII, and LIII = Schiff base of N-acetylisatin, N-benzylisatin, and N-benzoylisatin, respectively, and their metal complexes C1a,b=[Co2(LI)2Cl3]Cl, C2=[Ni(LI)2Cl2]0.4BuOH, C3=[CuLICl(H2O)]Cl⋅0.5BuOH, C4=[Pd(LI)2Cl]Cl, C5=[Pt(L1)2Cl2]Cl2⋅1.8EtOH.H2O, C6a=[CoLIICl]Cl⋅0.4H2O⋅0.3DMSO, C6b=[CoLIICl]Cl⋅0.3H2O⋅0.1BuOH,C7=[NiLIICl2], C8=[CuLII]Cl2⋅H2O0𝑥000𝑎0, C9=[Pd(LII)2]Cl2, C10=[Pt(LII)2.5Cl]Cl3, C11a=[Co(LIII)]C12⋅H2O, C11b=[Co(LIII)]Cl2⋅0.2H2O, and C12=[Ni(LIII)2]Cl2, C13=[Ni(LIII)2]Cl2 were reported. The complexes were characterized by elemental analyses, metal and chloride content, spectroscopic methods, magnetic moments, conductivity measurements, and thermal studies. Some of these compounds were tested as antibacterial and antifungal agents against Staphylococcus aureus, Proteus vulgaris, Candida albicans, and Aspergillus niger.http://dx.doi.org/10.1155/2009/413175 |
| spellingShingle | Ahlam J. Abdul-Ghani Asmaa M. N. Khaleel Synthesis and Characterization of New Schiff Bases Derived from N (1)-Substituted Isatin with Dithiooxamide and Their Co(II), Ni(II), Cu(II), Pd(II), and Pt(IV) Complexes Bioinorganic Chemistry and Applications |
| title | Synthesis and Characterization of New Schiff Bases Derived from N (1)-Substituted Isatin with Dithiooxamide and Their Co(II), Ni(II), Cu(II), Pd(II), and Pt(IV) Complexes |
| title_full | Synthesis and Characterization of New Schiff Bases Derived from N (1)-Substituted Isatin with Dithiooxamide and Their Co(II), Ni(II), Cu(II), Pd(II), and Pt(IV) Complexes |
| title_fullStr | Synthesis and Characterization of New Schiff Bases Derived from N (1)-Substituted Isatin with Dithiooxamide and Their Co(II), Ni(II), Cu(II), Pd(II), and Pt(IV) Complexes |
| title_full_unstemmed | Synthesis and Characterization of New Schiff Bases Derived from N (1)-Substituted Isatin with Dithiooxamide and Their Co(II), Ni(II), Cu(II), Pd(II), and Pt(IV) Complexes |
| title_short | Synthesis and Characterization of New Schiff Bases Derived from N (1)-Substituted Isatin with Dithiooxamide and Their Co(II), Ni(II), Cu(II), Pd(II), and Pt(IV) Complexes |
| title_sort | synthesis and characterization of new schiff bases derived from n 1 substituted isatin with dithiooxamide and their co ii ni ii cu ii pd ii and pt iv complexes |
| url | http://dx.doi.org/10.1155/2009/413175 |
| work_keys_str_mv | AT ahlamjabdulghani synthesisandcharacterizationofnewschiffbasesderivedfromn1substitutedisatinwithdithiooxamideandtheircoiiniiicuiipdiiandptivcomplexes AT asmaamnkhaleel synthesisandcharacterizationofnewschiffbasesderivedfromn1substitutedisatinwithdithiooxamideandtheircoiiniiicuiipdiiandptivcomplexes |