Activity measurement of Ga in liquid Ga-Pb alloys by EMF method with zirconia solid electrolyte
EMF measurement of the electrochemical cell with zirconia as solid electrolyte was performed to determine the gallium activity from 950 to 1150K in the entire composition range of liquid Ga-Pb alloys. In the whole concentration range, activity of Ga shows moderately positive deviations from ideality...
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| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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University of Belgrade, Technical Faculty, Bor
2002-01-01
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| Series: | Journal of Mining and Metallurgy. Section B: Metallurgy |
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| Online Access: | http://www.doiserbia.nb.rs/img/doi/1450-5339/2002/1450-53390204229K.pdf |
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| author | Katayama I. Živković Dragana Manasijević Dragan Oishi T. Živković Živan D. Iida T. |
| author_facet | Katayama I. Živković Dragana Manasijević Dragan Oishi T. Živković Živan D. Iida T. |
| author_sort | Katayama I. |
| collection | DOAJ |
| description | EMF measurement of the electrochemical cell with zirconia as solid electrolyte was performed to determine the gallium activity from 950 to 1150K in the entire composition range of liquid Ga-Pb alloys. In the whole concentration range, activity of Ga shows moderately positive deviations from ideality, and activity of Pb which is derived by Gibbs- Duhem equation shows also positive deviation from ideality. These are compared with published data obtained by different experimental methods. |
| format | Article |
| id | doaj-art-bcc3e88b28b3439cae50f96dec98ff52 |
| institution | Kabale University |
| issn | 1450-5339 |
| language | English |
| publishDate | 2002-01-01 |
| publisher | University of Belgrade, Technical Faculty, Bor |
| record_format | Article |
| series | Journal of Mining and Metallurgy. Section B: Metallurgy |
| spelling | doaj-art-bcc3e88b28b3439cae50f96dec98ff522025-02-02T09:29:41ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392002-01-01383-422923610.2298/JMMB0204229KActivity measurement of Ga in liquid Ga-Pb alloys by EMF method with zirconia solid electrolyteKatayama I.Živković DraganaManasijević DraganOishi T.Živković Živan D.Iida T.EMF measurement of the electrochemical cell with zirconia as solid electrolyte was performed to determine the gallium activity from 950 to 1150K in the entire composition range of liquid Ga-Pb alloys. In the whole concentration range, activity of Ga shows moderately positive deviations from ideality, and activity of Pb which is derived by Gibbs- Duhem equation shows also positive deviation from ideality. These are compared with published data obtained by different experimental methods.http://www.doiserbia.nb.rs/img/doi/1450-5339/2002/1450-53390204229K.pdfthermodynamicsactivityGa-Pb alloyemf methodzirconia solid electrolyteliquid binary alloy |
| spellingShingle | Katayama I. Živković Dragana Manasijević Dragan Oishi T. Živković Živan D. Iida T. Activity measurement of Ga in liquid Ga-Pb alloys by EMF method with zirconia solid electrolyte Journal of Mining and Metallurgy. Section B: Metallurgy thermodynamics activity Ga-Pb alloy emf method zirconia solid electrolyte liquid binary alloy |
| title | Activity measurement of Ga in liquid Ga-Pb alloys by EMF method with zirconia solid electrolyte |
| title_full | Activity measurement of Ga in liquid Ga-Pb alloys by EMF method with zirconia solid electrolyte |
| title_fullStr | Activity measurement of Ga in liquid Ga-Pb alloys by EMF method with zirconia solid electrolyte |
| title_full_unstemmed | Activity measurement of Ga in liquid Ga-Pb alloys by EMF method with zirconia solid electrolyte |
| title_short | Activity measurement of Ga in liquid Ga-Pb alloys by EMF method with zirconia solid electrolyte |
| title_sort | activity measurement of ga in liquid ga pb alloys by emf method with zirconia solid electrolyte |
| topic | thermodynamics activity Ga-Pb alloy emf method zirconia solid electrolyte liquid binary alloy |
| url | http://www.doiserbia.nb.rs/img/doi/1450-5339/2002/1450-53390204229K.pdf |
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