Synthesis and Structural Studies of First Row Transition Metal Complexes with Tetradentate ONNO Donor Schiff Base Derived from 5-Acetyl 2,4-dihydroxyacetophenone and Ethylenediamine
Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) complexes were prepared by template reaction of 5-acetyl 2,4-dihydroxyacetophenone (H2-ADA) and ethylenediamine in the presence of metal ions. The complexes have been characterized on the basis of elemental analyses, conductivity, magnetic...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2011-01-01
|
| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2011/536269 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832556408391860224 |
|---|---|
| author | Pulimamidi Saritha Reddy P. V. Ananthalakshmi V. Jayatyagaraju |
| author_facet | Pulimamidi Saritha Reddy P. V. Ananthalakshmi V. Jayatyagaraju |
| author_sort | Pulimamidi Saritha Reddy |
| collection | DOAJ |
| description | Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) complexes were prepared by template reaction of 5-acetyl 2,4-dihydroxyacetophenone (H2-ADA) and ethylenediamine in the presence of metal ions. The complexes have been characterized on the basis of elemental analyses, conductivity, magnetic moments, infrared and electronic spectral data. The Schiff base binds to metal ions in bis-multidentate ONNO mode leading to two dimensional Schiff base polymers. All the complexes have been assigned octahedral stereochemistry. |
| format | Article |
| id | doaj-art-bc284e01d2154e24af7a36fca93aea98 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2011-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-bc284e01d2154e24af7a36fca93aea982025-02-03T05:45:35ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-018141542010.1155/2011/536269Synthesis and Structural Studies of First Row Transition Metal Complexes with Tetradentate ONNO Donor Schiff Base Derived from 5-Acetyl 2,4-dihydroxyacetophenone and EthylenediaminePulimamidi Saritha Reddy0P. V. Ananthalakshmi1V. Jayatyagaraju2Department of Chemistry, University College for Women, Osmania University, Hyderabad-500001, Andhra Pradesh, IndiaDepartment of Chemistry, University College for Women, Osmania University, Hyderabad-500001, Andhra Pradesh, IndiaDepartment of Chemistry, Addis Ababa University, P.O .Box 1176, Addis Ababa, EthiopiaCr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) complexes were prepared by template reaction of 5-acetyl 2,4-dihydroxyacetophenone (H2-ADA) and ethylenediamine in the presence of metal ions. The complexes have been characterized on the basis of elemental analyses, conductivity, magnetic moments, infrared and electronic spectral data. The Schiff base binds to metal ions in bis-multidentate ONNO mode leading to two dimensional Schiff base polymers. All the complexes have been assigned octahedral stereochemistry.http://dx.doi.org/10.1155/2011/536269 |
| spellingShingle | Pulimamidi Saritha Reddy P. V. Ananthalakshmi V. Jayatyagaraju Synthesis and Structural Studies of First Row Transition Metal Complexes with Tetradentate ONNO Donor Schiff Base Derived from 5-Acetyl 2,4-dihydroxyacetophenone and Ethylenediamine E-Journal of Chemistry |
| title | Synthesis and Structural Studies of First Row Transition Metal Complexes with Tetradentate ONNO Donor Schiff Base Derived from 5-Acetyl 2,4-dihydroxyacetophenone and Ethylenediamine |
| title_full | Synthesis and Structural Studies of First Row Transition Metal Complexes with Tetradentate ONNO Donor Schiff Base Derived from 5-Acetyl 2,4-dihydroxyacetophenone and Ethylenediamine |
| title_fullStr | Synthesis and Structural Studies of First Row Transition Metal Complexes with Tetradentate ONNO Donor Schiff Base Derived from 5-Acetyl 2,4-dihydroxyacetophenone and Ethylenediamine |
| title_full_unstemmed | Synthesis and Structural Studies of First Row Transition Metal Complexes with Tetradentate ONNO Donor Schiff Base Derived from 5-Acetyl 2,4-dihydroxyacetophenone and Ethylenediamine |
| title_short | Synthesis and Structural Studies of First Row Transition Metal Complexes with Tetradentate ONNO Donor Schiff Base Derived from 5-Acetyl 2,4-dihydroxyacetophenone and Ethylenediamine |
| title_sort | synthesis and structural studies of first row transition metal complexes with tetradentate onno donor schiff base derived from 5 acetyl 2 4 dihydroxyacetophenone and ethylenediamine |
| url | http://dx.doi.org/10.1155/2011/536269 |
| work_keys_str_mv | AT pulimamidisarithareddy synthesisandstructuralstudiesoffirstrowtransitionmetalcomplexeswithtetradentateonnodonorschiffbasederivedfrom5acetyl24dihydroxyacetophenoneandethylenediamine AT pvananthalakshmi synthesisandstructuralstudiesoffirstrowtransitionmetalcomplexeswithtetradentateonnodonorschiffbasederivedfrom5acetyl24dihydroxyacetophenoneandethylenediamine AT vjayatyagaraju synthesisandstructuralstudiesoffirstrowtransitionmetalcomplexeswithtetradentateonnodonorschiffbasederivedfrom5acetyl24dihydroxyacetophenoneandethylenediamine |