Preparation and Characterization of Nanocrystalline Hard Chromium Coatings Using Eco-Friendly Trivalent Chromium Bath
A new aqueous sulfate trivalent chromium bath is described. The chromium bath contains formic acid and carbamide as complexing agents. Chromium was deposited at a temperature of 30÷40 oC and a cathode current density of 10÷25 A dm-2. The bath allows obtaining thick (up to several hundred micrometers...
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Language: | English |
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2011-01-01
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Series: | E-Journal of Chemistry |
Online Access: | http://dx.doi.org/10.1155/2011/253203 |
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author | V. S. Protsenko V. O Gordiienko F. I. Danilov S. C. Kwon |
author_facet | V. S. Protsenko V. O Gordiienko F. I. Danilov S. C. Kwon |
author_sort | V. S. Protsenko |
collection | DOAJ |
description | A new aqueous sulfate trivalent chromium bath is described. The chromium bath contains formic acid and carbamide as complexing agents. Chromium was deposited at a temperature of 30÷40 oC and a cathode current density of 10÷25 A dm-2. The bath allows obtaining thick (up to several hundred micrometers) hard chromium coatings with nanocrystalline structure. The electrodeposition rate reaches 0.8÷0.9 µm min-1. |
format | Article |
id | doaj-art-bbbd6f676e564d919d030916882ff113 |
institution | Kabale University |
issn | 0973-4945 2090-9810 |
language | English |
publishDate | 2011-01-01 |
publisher | Wiley |
record_format | Article |
series | E-Journal of Chemistry |
spelling | doaj-art-bbbd6f676e564d919d030916882ff1132025-02-03T01:13:11ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-01841925192910.1155/2011/253203Preparation and Characterization of Nanocrystalline Hard Chromium Coatings Using Eco-Friendly Trivalent Chromium BathV. S. Protsenko0V. O Gordiienko1F. I. Danilov2S. C. Kwon3Department of Physical Chemistry, Ukrainian State University of Chemical Technology, Gagarin Av. 8, Dnepropetrovsk, 49005, UkraineDepartment of Physical Chemistry, Ukrainian State University of Chemical Technology, Gagarin Av. 8, Dnepropetrovsk, 49005, UkraineDepartment of Physical Chemistry, Ukrainian State University of Chemical Technology, Gagarin Av. 8, Dnepropetrovsk, 49005, UkraineSurface Engineering Department, Korea Institute of Machinery and Materials, 66 Sangnam-dong, Changwon, Gyeongnam 641-010, Republic of KoreaA new aqueous sulfate trivalent chromium bath is described. The chromium bath contains formic acid and carbamide as complexing agents. Chromium was deposited at a temperature of 30÷40 oC and a cathode current density of 10÷25 A dm-2. The bath allows obtaining thick (up to several hundred micrometers) hard chromium coatings with nanocrystalline structure. The electrodeposition rate reaches 0.8÷0.9 µm min-1.http://dx.doi.org/10.1155/2011/253203 |
spellingShingle | V. S. Protsenko V. O Gordiienko F. I. Danilov S. C. Kwon Preparation and Characterization of Nanocrystalline Hard Chromium Coatings Using Eco-Friendly Trivalent Chromium Bath E-Journal of Chemistry |
title | Preparation and Characterization of Nanocrystalline Hard Chromium Coatings Using Eco-Friendly Trivalent Chromium Bath |
title_full | Preparation and Characterization of Nanocrystalline Hard Chromium Coatings Using Eco-Friendly Trivalent Chromium Bath |
title_fullStr | Preparation and Characterization of Nanocrystalline Hard Chromium Coatings Using Eco-Friendly Trivalent Chromium Bath |
title_full_unstemmed | Preparation and Characterization of Nanocrystalline Hard Chromium Coatings Using Eco-Friendly Trivalent Chromium Bath |
title_short | Preparation and Characterization of Nanocrystalline Hard Chromium Coatings Using Eco-Friendly Trivalent Chromium Bath |
title_sort | preparation and characterization of nanocrystalline hard chromium coatings using eco friendly trivalent chromium bath |
url | http://dx.doi.org/10.1155/2011/253203 |
work_keys_str_mv | AT vsprotsenko preparationandcharacterizationofnanocrystallinehardchromiumcoatingsusingecofriendlytrivalentchromiumbath AT vogordiienko preparationandcharacterizationofnanocrystallinehardchromiumcoatingsusingecofriendlytrivalentchromiumbath AT fidanilov preparationandcharacterizationofnanocrystallinehardchromiumcoatingsusingecofriendlytrivalentchromiumbath AT sckwon preparationandcharacterizationofnanocrystallinehardchromiumcoatingsusingecofriendlytrivalentchromiumbath |