Incorporation of κ-carrageenan improves the practical features of agar/konjac glucomannan/κ-carrageenan ternary system

Three materials (agar, konjac glucomannan (KGM) and κ-carrageenan) were used to prepare ternary systems, i.e., sol-gels and their dried composites conditioned at varied relative humidity (RH) (33 %, 54 % and 75 %). Combined methods, e.g., scanning electron microscopy, small-angle X-ray scattering, i...

Full description

Saved in:
Bibliographic Details
Main Authors: Dongling Qiao, Hao Li, Fatang Jiang, Siming Zhao, Sheng Chen, Binjia Zhang
Format: Article
Language:English
Published: Tsinghua University Press 2023-03-01
Series:Food Science and Human Wellness
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2213453022001653
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832546422205972480
author Dongling Qiao
Hao Li
Fatang Jiang
Siming Zhao
Sheng Chen
Binjia Zhang
author_facet Dongling Qiao
Hao Li
Fatang Jiang
Siming Zhao
Sheng Chen
Binjia Zhang
author_sort Dongling Qiao
collection DOAJ
description Three materials (agar, konjac glucomannan (KGM) and κ-carrageenan) were used to prepare ternary systems, i.e., sol-gels and their dried composites conditioned at varied relative humidity (RH) (33 %, 54 % and 75 %). Combined methods, e.g., scanning electron microscopy, small-angle X-ray scattering, infrared spectroscopy (IR) and X-ray diffraction (XRD), were used to disclose how κ-carrageenan addition tailors the features of agar/KGM/κ-carrageenan ternary system. As affirmed by IR and XRD, the ternary systems with κ-carrageenan below 25 % (agar/KGM/carrageenan, 50:25:25, m/m) displayed proper component interactions, which increased the sol-gel transition temperature and the hardness of obtained gels. For instance, the ternary composites could show hardness about 3 to 4 times higher than that for binary counterpart. These gels were dehydrated to acquire ternary composites. Compared to agar/KGM composite, the ternary composites showed fewer crystallites and nanoscale orders, and newly-formed nanoscale structures from chain assembly. Such multi-scale structures, for composites with κ-carrageenan below 25 %, showed weaker changes with RH, as revealed by especially morphologic and crystalline features. Consequently, the ternary composites with less κ-carrageenan (below 25 %) exhibited stabilized elongation at break and hydrophilicity at different RHs. This hints to us that agar/KGM/κ-carrageenan composite systems can display series applications with improved features, e.g., increased sol-gel transition point.
format Article
id doaj-art-bb9878fbd72f494c8f3d04a4d19f8e42
institution Kabale University
issn 2213-4530
language English
publishDate 2023-03-01
publisher Tsinghua University Press
record_format Article
series Food Science and Human Wellness
spelling doaj-art-bb9878fbd72f494c8f3d04a4d19f8e422025-02-03T06:55:49ZengTsinghua University PressFood Science and Human Wellness2213-45302023-03-01122512519Incorporation of κ-carrageenan improves the practical features of agar/konjac glucomannan/κ-carrageenan ternary systemDongling Qiao0Hao Li1Fatang Jiang2Siming Zhao3Sheng Chen4Binjia Zhang5Chongqing Key Laboratory of Speciality Food Co-Built by Sichuan and Chongqing, College of Food Science, Southwest University, Chongqing 400715, ChinaGlyn O. Phillips Hydrocolloid Research Centre at HBUT, School of Food and Biological Engineering, Hubei University of Technology, Wuhan 430068, ChinaGlyn O. Phillips Hydrocolloid Research Centre at HBUT, School of Food and Biological Engineering, Hubei University of Technology, Wuhan 430068, ChinaGroup for Cereals and Oils Processing, College of Food Science and Technology, Key Laboratory of Environment Correlative Dietology (Ministry of Education), Huazhong Agricultural University, Wuhan 430070, ChinaYellow Crane Tower Science and Technology Park (Group) Co., Ltd., Wuhan 430040, China; Corresponding authors.Chongqing Key Laboratory of Speciality Food Co-Built by Sichuan and Chongqing, College of Food Science, Southwest University, Chongqing 400715, China; Corresponding authors.Three materials (agar, konjac glucomannan (KGM) and κ-carrageenan) were used to prepare ternary systems, i.e., sol-gels and their dried composites conditioned at varied relative humidity (RH) (33 %, 54 % and 75 %). Combined methods, e.g., scanning electron microscopy, small-angle X-ray scattering, infrared spectroscopy (IR) and X-ray diffraction (XRD), were used to disclose how κ-carrageenan addition tailors the features of agar/KGM/κ-carrageenan ternary system. As affirmed by IR and XRD, the ternary systems with κ-carrageenan below 25 % (agar/KGM/carrageenan, 50:25:25, m/m) displayed proper component interactions, which increased the sol-gel transition temperature and the hardness of obtained gels. For instance, the ternary composites could show hardness about 3 to 4 times higher than that for binary counterpart. These gels were dehydrated to acquire ternary composites. Compared to agar/KGM composite, the ternary composites showed fewer crystallites and nanoscale orders, and newly-formed nanoscale structures from chain assembly. Such multi-scale structures, for composites with κ-carrageenan below 25 %, showed weaker changes with RH, as revealed by especially morphologic and crystalline features. Consequently, the ternary composites with less κ-carrageenan (below 25 %) exhibited stabilized elongation at break and hydrophilicity at different RHs. This hints to us that agar/KGM/κ-carrageenan composite systems can display series applications with improved features, e.g., increased sol-gel transition point.http://www.sciencedirect.com/science/article/pii/S2213453022001653Agar/konjac glucomannan/κ-carrageenan ternary systemComponent interactionMulti-scale structurePractical features
spellingShingle Dongling Qiao
Hao Li
Fatang Jiang
Siming Zhao
Sheng Chen
Binjia Zhang
Incorporation of κ-carrageenan improves the practical features of agar/konjac glucomannan/κ-carrageenan ternary system
Food Science and Human Wellness
Agar/konjac glucomannan/κ-carrageenan ternary system
Component interaction
Multi-scale structure
Practical features
title Incorporation of κ-carrageenan improves the practical features of agar/konjac glucomannan/κ-carrageenan ternary system
title_full Incorporation of κ-carrageenan improves the practical features of agar/konjac glucomannan/κ-carrageenan ternary system
title_fullStr Incorporation of κ-carrageenan improves the practical features of agar/konjac glucomannan/κ-carrageenan ternary system
title_full_unstemmed Incorporation of κ-carrageenan improves the practical features of agar/konjac glucomannan/κ-carrageenan ternary system
title_short Incorporation of κ-carrageenan improves the practical features of agar/konjac glucomannan/κ-carrageenan ternary system
title_sort incorporation of κ carrageenan improves the practical features of agar konjac glucomannan κ carrageenan ternary system
topic Agar/konjac glucomannan/κ-carrageenan ternary system
Component interaction
Multi-scale structure
Practical features
url http://www.sciencedirect.com/science/article/pii/S2213453022001653
work_keys_str_mv AT donglingqiao incorporationofkcarrageenanimprovesthepracticalfeaturesofagarkonjacglucomannankcarrageenanternarysystem
AT haoli incorporationofkcarrageenanimprovesthepracticalfeaturesofagarkonjacglucomannankcarrageenanternarysystem
AT fatangjiang incorporationofkcarrageenanimprovesthepracticalfeaturesofagarkonjacglucomannankcarrageenanternarysystem
AT simingzhao incorporationofkcarrageenanimprovesthepracticalfeaturesofagarkonjacglucomannankcarrageenanternarysystem
AT shengchen incorporationofkcarrageenanimprovesthepracticalfeaturesofagarkonjacglucomannankcarrageenanternarysystem
AT binjiazhang incorporationofkcarrageenanimprovesthepracticalfeaturesofagarkonjacglucomannankcarrageenanternarysystem