Ion Exchange Properties of Resins Derived from p-Hydroxybenzaldehyde, Resorcinol and Formaldehyde

The terpolymeric resins were prepared by base catalyzed polycondensation of p-hydroxybenzaldehyde, resorcinol and formaldehyde. Resin obtained by molar monomer composition, p-hydroxybenzaldehyde: resorcinol: formaldehyde as 1:1:3 was abbreviated as PHBRF-I and that prepared by 1:2:4 composition was...

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Main Authors: V. V. Hiwase, A. B. Kalambe, K. M. Khedkar, S. D. Deosarkar
Format: Article
Language:English
Published: Wiley 2010-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2010/830484
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author V. V. Hiwase
A. B. Kalambe
K. M. Khedkar
S. D. Deosarkar
author_facet V. V. Hiwase
A. B. Kalambe
K. M. Khedkar
S. D. Deosarkar
author_sort V. V. Hiwase
collection DOAJ
description The terpolymeric resins were prepared by base catalyzed polycondensation of p-hydroxybenzaldehyde, resorcinol and formaldehyde. Resin obtained by molar monomer composition, p-hydroxybenzaldehyde: resorcinol: formaldehyde as 1:1:3 was abbreviated as PHBRF-I and that prepared by 1:2:4 composition was abbreviated as PHBRF-II. These resins were characterized by physicochemical methods such as elemental analysis, UV-Vis, IR and NMR. ion-exchange study was carried out with Cu2+, Zn2+, Ni2+, Co2+, Pb2+ & Cd2+ by batch equilibrium method. The rate of metal ion uptake by PHBRF-II terpolymeric resin was higher than that of PHBRF-I. Effect of pH and electrolytes under specified condition were also studied. The terpolymeric resins show high selectivity for Cu2+, Zn2+ and Co2+ as compared to Ni2+, Pb2+, and Cd2+.
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institution Kabale University
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series E-Journal of Chemistry
spelling doaj-art-bb3c81746d1444e784bfa89aaf15938c2025-02-03T01:12:08ZengWileyE-Journal of Chemistry0973-49452090-98102010-01-017128729410.1155/2010/830484Ion Exchange Properties of Resins Derived from p-Hydroxybenzaldehyde, Resorcinol and FormaldehydeV. V. Hiwase0A. B. Kalambe1K. M. Khedkar2S. D. Deosarkar3Arts, Commerce & Science College, Arvi, Dist- Wardha, IndiaInstitute of Science, Nagpur, IndiaInstitute of Science, Nagpur, IndiaS.F.S. College, Nagpur, IndiaThe terpolymeric resins were prepared by base catalyzed polycondensation of p-hydroxybenzaldehyde, resorcinol and formaldehyde. Resin obtained by molar monomer composition, p-hydroxybenzaldehyde: resorcinol: formaldehyde as 1:1:3 was abbreviated as PHBRF-I and that prepared by 1:2:4 composition was abbreviated as PHBRF-II. These resins were characterized by physicochemical methods such as elemental analysis, UV-Vis, IR and NMR. ion-exchange study was carried out with Cu2+, Zn2+, Ni2+, Co2+, Pb2+ & Cd2+ by batch equilibrium method. The rate of metal ion uptake by PHBRF-II terpolymeric resin was higher than that of PHBRF-I. Effect of pH and electrolytes under specified condition were also studied. The terpolymeric resins show high selectivity for Cu2+, Zn2+ and Co2+ as compared to Ni2+, Pb2+, and Cd2+.http://dx.doi.org/10.1155/2010/830484
spellingShingle V. V. Hiwase
A. B. Kalambe
K. M. Khedkar
S. D. Deosarkar
Ion Exchange Properties of Resins Derived from p-Hydroxybenzaldehyde, Resorcinol and Formaldehyde
E-Journal of Chemistry
title Ion Exchange Properties of Resins Derived from p-Hydroxybenzaldehyde, Resorcinol and Formaldehyde
title_full Ion Exchange Properties of Resins Derived from p-Hydroxybenzaldehyde, Resorcinol and Formaldehyde
title_fullStr Ion Exchange Properties of Resins Derived from p-Hydroxybenzaldehyde, Resorcinol and Formaldehyde
title_full_unstemmed Ion Exchange Properties of Resins Derived from p-Hydroxybenzaldehyde, Resorcinol and Formaldehyde
title_short Ion Exchange Properties of Resins Derived from p-Hydroxybenzaldehyde, Resorcinol and Formaldehyde
title_sort ion exchange properties of resins derived from p hydroxybenzaldehyde resorcinol and formaldehyde
url http://dx.doi.org/10.1155/2010/830484
work_keys_str_mv AT vvhiwase ionexchangepropertiesofresinsderivedfromphydroxybenzaldehyderesorcinolandformaldehyde
AT abkalambe ionexchangepropertiesofresinsderivedfromphydroxybenzaldehyderesorcinolandformaldehyde
AT kmkhedkar ionexchangepropertiesofresinsderivedfromphydroxybenzaldehyderesorcinolandformaldehyde
AT sddeosarkar ionexchangepropertiesofresinsderivedfromphydroxybenzaldehyderesorcinolandformaldehyde