Synthesis of Gold Nanoparticles Capped with Quaterthiophene for Transistor and Resistor Memory Devices

Recently, the fabrication of nonvolatile memory devices based on gold nanoparticles has been intensively investigated. In this work, we report on the design and synthesis of new semiconducting quaterthiophene incorporating hexyl thiol group (4TT). Gold nanoparticles capped with 4TT (4TTG) were prepa...

Full description

Saved in:
Bibliographic Details
Main Authors: Mai Ha Hoang, Toan Thanh Dao, Nguyen Thi Thu Trang, Phuong Hoai Nam Nguyen, Trinh Tung Ngo
Format: Article
Language:English
Published: Wiley 2016-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2016/1247175
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832548150129197056
author Mai Ha Hoang
Toan Thanh Dao
Nguyen Thi Thu Trang
Phuong Hoai Nam Nguyen
Trinh Tung Ngo
author_facet Mai Ha Hoang
Toan Thanh Dao
Nguyen Thi Thu Trang
Phuong Hoai Nam Nguyen
Trinh Tung Ngo
author_sort Mai Ha Hoang
collection DOAJ
description Recently, the fabrication of nonvolatile memory devices based on gold nanoparticles has been intensively investigated. In this work, we report on the design and synthesis of new semiconducting quaterthiophene incorporating hexyl thiol group (4TT). Gold nanoparticles capped with 4TT (4TTG) were prepared in a two-phase liquid-liquid system. These nanoparticles have diameters in the range 2–6 nm and are well dispersed in the poly(3-hexylthiophene) (P3HT) host matrix. The intermolecular interaction between 4TT and P3HT could enhance the charge-transport between gold nanoparticles and P3HT. Transfer curve of transistor memory device made of 4TTG/P3HT hybrid film exhibited significant current hysteresis, probably arising from the energy level barrier at 4TTG/P3HT interface. Additionally, the polymer memory resistor structure with an active layer consisting of 4TTG and P3HT displayed a remarkable electrical bistable behavior.
format Article
id doaj-art-ba93f68b134b4430a72e84ba7c4ead80
institution Kabale University
issn 2090-9063
2090-9071
language English
publishDate 2016-01-01
publisher Wiley
record_format Article
series Journal of Chemistry
spelling doaj-art-ba93f68b134b4430a72e84ba7c4ead802025-02-03T06:42:04ZengWileyJournal of Chemistry2090-90632090-90712016-01-01201610.1155/2016/12471751247175Synthesis of Gold Nanoparticles Capped with Quaterthiophene for Transistor and Resistor Memory DevicesMai Ha Hoang0Toan Thanh Dao1Nguyen Thi Thu Trang2Phuong Hoai Nam Nguyen3Trinh Tung Ngo4Institute of Chemistry, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, VietnamFaculty of Electrical-Electronic Engineering, University of Transport and Communications, No. 3 Cau Giay Street, Dong Da, Hanoi, VietnamInstitute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, VietnamFaculty of Engineering Physics and Nano-Technology, University of Engineering and Technology, Vietnam National University, 144 Xuan Thuy, Cau Giay, Hanoi, VietnamInstitute of Chemistry, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, VietnamRecently, the fabrication of nonvolatile memory devices based on gold nanoparticles has been intensively investigated. In this work, we report on the design and synthesis of new semiconducting quaterthiophene incorporating hexyl thiol group (4TT). Gold nanoparticles capped with 4TT (4TTG) were prepared in a two-phase liquid-liquid system. These nanoparticles have diameters in the range 2–6 nm and are well dispersed in the poly(3-hexylthiophene) (P3HT) host matrix. The intermolecular interaction between 4TT and P3HT could enhance the charge-transport between gold nanoparticles and P3HT. Transfer curve of transistor memory device made of 4TTG/P3HT hybrid film exhibited significant current hysteresis, probably arising from the energy level barrier at 4TTG/P3HT interface. Additionally, the polymer memory resistor structure with an active layer consisting of 4TTG and P3HT displayed a remarkable electrical bistable behavior.http://dx.doi.org/10.1155/2016/1247175
spellingShingle Mai Ha Hoang
Toan Thanh Dao
Nguyen Thi Thu Trang
Phuong Hoai Nam Nguyen
Trinh Tung Ngo
Synthesis of Gold Nanoparticles Capped with Quaterthiophene for Transistor and Resistor Memory Devices
Journal of Chemistry
title Synthesis of Gold Nanoparticles Capped with Quaterthiophene for Transistor and Resistor Memory Devices
title_full Synthesis of Gold Nanoparticles Capped with Quaterthiophene for Transistor and Resistor Memory Devices
title_fullStr Synthesis of Gold Nanoparticles Capped with Quaterthiophene for Transistor and Resistor Memory Devices
title_full_unstemmed Synthesis of Gold Nanoparticles Capped with Quaterthiophene for Transistor and Resistor Memory Devices
title_short Synthesis of Gold Nanoparticles Capped with Quaterthiophene for Transistor and Resistor Memory Devices
title_sort synthesis of gold nanoparticles capped with quaterthiophene for transistor and resistor memory devices
url http://dx.doi.org/10.1155/2016/1247175
work_keys_str_mv AT maihahoang synthesisofgoldnanoparticlescappedwithquaterthiophenefortransistorandresistormemorydevices
AT toanthanhdao synthesisofgoldnanoparticlescappedwithquaterthiophenefortransistorandresistormemorydevices
AT nguyenthithutrang synthesisofgoldnanoparticlescappedwithquaterthiophenefortransistorandresistormemorydevices
AT phuonghoainamnguyen synthesisofgoldnanoparticlescappedwithquaterthiophenefortransistorandresistormemorydevices
AT trinhtungngo synthesisofgoldnanoparticlescappedwithquaterthiophenefortransistorandresistormemorydevices