A New Nano Silica Gel Supported by Thionyl Chloride as a Solid Acid for the Efficient Diazotization of Aniline Derivatives: Application and Synthesis of Azo Dyes

A new nano silicagel supported by thionyl chloride as a solid acid was synthesized and used as a increasing the production yield of dye to affect the efficient diazotization of arylamines. The diazonium salts thus obtained were coupled, using standard experimental procedures, to anilines and naphtho...

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Main Authors: Mohammad Mirjalili, Fatemeh Zahed, Alireza Hassanabadi
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2012/306137
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author Mohammad Mirjalili
Fatemeh Zahed
Alireza Hassanabadi
author_facet Mohammad Mirjalili
Fatemeh Zahed
Alireza Hassanabadi
author_sort Mohammad Mirjalili
collection DOAJ
description A new nano silicagel supported by thionyl chloride as a solid acid was synthesized and used as a increasing the production yield of dye to affect the efficient diazotization of arylamines. The diazonium salts thus obtained were coupled, using standard experimental procedures, to anilines and naphthols to afford the requisite azo dyes in good yield. The diazotization and subsequent azo-coupling generated the related azo dyes at low temperature in short reaction times with a simple experimental procedure.
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spelling doaj-art-b9c5d249db5443ee8167839020b436d82025-02-03T06:44:46ZengWileyE-Journal of Chemistry0973-49452090-98102012-01-01921042104610.1155/2012/306137A New Nano Silica Gel Supported by Thionyl Chloride as a Solid Acid for the Efficient Diazotization of Aniline Derivatives: Application and Synthesis of Azo DyesMohammad Mirjalili0Fatemeh Zahed1Alireza Hassanabadi2Faculty of Textile Engineering, Yazd Branch, Islamic Azad University, Yazd, IranFaculty of Textile Engineering, Yazd Branch, Islamic Azad University, Yazd, IranDepartment of Chemistry, Islamic Azad University, Zahedan Branch, P.O. Box 98135-978, Zahedan, IranA new nano silicagel supported by thionyl chloride as a solid acid was synthesized and used as a increasing the production yield of dye to affect the efficient diazotization of arylamines. The diazonium salts thus obtained were coupled, using standard experimental procedures, to anilines and naphthols to afford the requisite azo dyes in good yield. The diazotization and subsequent azo-coupling generated the related azo dyes at low temperature in short reaction times with a simple experimental procedure.http://dx.doi.org/10.1155/2012/306137
spellingShingle Mohammad Mirjalili
Fatemeh Zahed
Alireza Hassanabadi
A New Nano Silica Gel Supported by Thionyl Chloride as a Solid Acid for the Efficient Diazotization of Aniline Derivatives: Application and Synthesis of Azo Dyes
E-Journal of Chemistry
title A New Nano Silica Gel Supported by Thionyl Chloride as a Solid Acid for the Efficient Diazotization of Aniline Derivatives: Application and Synthesis of Azo Dyes
title_full A New Nano Silica Gel Supported by Thionyl Chloride as a Solid Acid for the Efficient Diazotization of Aniline Derivatives: Application and Synthesis of Azo Dyes
title_fullStr A New Nano Silica Gel Supported by Thionyl Chloride as a Solid Acid for the Efficient Diazotization of Aniline Derivatives: Application and Synthesis of Azo Dyes
title_full_unstemmed A New Nano Silica Gel Supported by Thionyl Chloride as a Solid Acid for the Efficient Diazotization of Aniline Derivatives: Application and Synthesis of Azo Dyes
title_short A New Nano Silica Gel Supported by Thionyl Chloride as a Solid Acid for the Efficient Diazotization of Aniline Derivatives: Application and Synthesis of Azo Dyes
title_sort new nano silica gel supported by thionyl chloride as a solid acid for the efficient diazotization of aniline derivatives application and synthesis of azo dyes
url http://dx.doi.org/10.1155/2012/306137
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