Characterisation and Properties of Lithium Disilicate Glass Ceramics in the SiO2-Li2O-K2O-Al2O3 System for Dental Applications

This work proposes four different glass formulas derived from the SiO2-Li2O-K2O-Al2O3 system to investigate the effect of glass composition on their crystal formations and properties. Glass LD1 was SiO2-Li2O-K2O-Al2O3 system with the addition of P2O5 and CaF2 as nucleating agents. In Glass LD2, a sl...

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Main Authors: Naruporn Monmaturapoj, Pornchanok Lawita, Witoon Thepsuwan
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2013/763838
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author Naruporn Monmaturapoj
Pornchanok Lawita
Witoon Thepsuwan
author_facet Naruporn Monmaturapoj
Pornchanok Lawita
Witoon Thepsuwan
author_sort Naruporn Monmaturapoj
collection DOAJ
description This work proposes four different glass formulas derived from the SiO2-Li2O-K2O-Al2O3 system to investigate the effect of glass composition on their crystal formations and properties. Glass LD1 was SiO2-Li2O-K2O-Al2O3 system with the addition of P2O5 and CaF2 as nucleating agents. In Glass LD2, a slight amount of MgO was mixed in order to increase the viscosity of the melting glass. Finally, the important factor of Si : Li ratio was increased in Glasses LD3 and LD4 with compositions otherwise the same as LD1 and LD2. The results found that P2O5 and CaF2 served as a nucleating site for lithium phosphate and fluorapatite to encourage heterogenous nucleation and produce a fine-grained interlocking microstructure of lithium disilicate glass ceramics. MgO content in this system seemed to increase the viscosity of the melting glass and thermal expansion coefficient including the chemical solubility. Increasing the Si : Li ratio in glass compositions resulted in the change of the microstructure of Li2Si2O5 crystals.
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institution Kabale University
issn 1687-8434
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publishDate 2013-01-01
publisher Wiley
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series Advances in Materials Science and Engineering
spelling doaj-art-b8c2677b532443329bc59b78470977962025-02-03T06:11:25ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422013-01-01201310.1155/2013/763838763838Characterisation and Properties of Lithium Disilicate Glass Ceramics in the SiO2-Li2O-K2O-Al2O3 System for Dental ApplicationsNaruporn Monmaturapoj0Pornchanok Lawita1Witoon Thepsuwan2National Metal and Materials Technology Center, 114 Thailand Science Park, Pathumthani 12120, ThailandNational Metal and Materials Technology Center, 114 Thailand Science Park, Pathumthani 12120, ThailandNational Metal and Materials Technology Center, 114 Thailand Science Park, Pathumthani 12120, ThailandThis work proposes four different glass formulas derived from the SiO2-Li2O-K2O-Al2O3 system to investigate the effect of glass composition on their crystal formations and properties. Glass LD1 was SiO2-Li2O-K2O-Al2O3 system with the addition of P2O5 and CaF2 as nucleating agents. In Glass LD2, a slight amount of MgO was mixed in order to increase the viscosity of the melting glass. Finally, the important factor of Si : Li ratio was increased in Glasses LD3 and LD4 with compositions otherwise the same as LD1 and LD2. The results found that P2O5 and CaF2 served as a nucleating site for lithium phosphate and fluorapatite to encourage heterogenous nucleation and produce a fine-grained interlocking microstructure of lithium disilicate glass ceramics. MgO content in this system seemed to increase the viscosity of the melting glass and thermal expansion coefficient including the chemical solubility. Increasing the Si : Li ratio in glass compositions resulted in the change of the microstructure of Li2Si2O5 crystals.http://dx.doi.org/10.1155/2013/763838
spellingShingle Naruporn Monmaturapoj
Pornchanok Lawita
Witoon Thepsuwan
Characterisation and Properties of Lithium Disilicate Glass Ceramics in the SiO2-Li2O-K2O-Al2O3 System for Dental Applications
Advances in Materials Science and Engineering
title Characterisation and Properties of Lithium Disilicate Glass Ceramics in the SiO2-Li2O-K2O-Al2O3 System for Dental Applications
title_full Characterisation and Properties of Lithium Disilicate Glass Ceramics in the SiO2-Li2O-K2O-Al2O3 System for Dental Applications
title_fullStr Characterisation and Properties of Lithium Disilicate Glass Ceramics in the SiO2-Li2O-K2O-Al2O3 System for Dental Applications
title_full_unstemmed Characterisation and Properties of Lithium Disilicate Glass Ceramics in the SiO2-Li2O-K2O-Al2O3 System for Dental Applications
title_short Characterisation and Properties of Lithium Disilicate Glass Ceramics in the SiO2-Li2O-K2O-Al2O3 System for Dental Applications
title_sort characterisation and properties of lithium disilicate glass ceramics in the sio2 li2o k2o al2o3 system for dental applications
url http://dx.doi.org/10.1155/2013/763838
work_keys_str_mv AT narupornmonmaturapoj characterisationandpropertiesoflithiumdisilicateglassceramicsinthesio2li2ok2oal2o3systemfordentalapplications
AT pornchanoklawita characterisationandpropertiesoflithiumdisilicateglassceramicsinthesio2li2ok2oal2o3systemfordentalapplications
AT witoonthepsuwan characterisationandpropertiesoflithiumdisilicateglassceramicsinthesio2li2ok2oal2o3systemfordentalapplications