Viscosity and structure evolution of the SiO2-MgO-FeO-CaO-Al2O3 slag in ferronickel smelting process from laterite

The SiO2 fractions in laterite-nickel ores are quite high, thus certain amount of lime should be used as fluxing material to achieve good fluidity and desulfurization capacity in industrial smelting process. However, this operation leads to an additional cost of lime. In addition, the incre...

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Main Authors: Lv X.M., Lv X.W., Wang L.W., Qiu J., Liu M.
Format: Article
Language:English
Published: University of Belgrade, Technical Faculty, Bor 2017-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2017/1450-53391700002L.pdf
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author Lv X.M.
Lv X.W.
Wang L.W.
Qiu J.
Liu M.
author_facet Lv X.M.
Lv X.W.
Wang L.W.
Qiu J.
Liu M.
author_sort Lv X.M.
collection DOAJ
description The SiO2 fractions in laterite-nickel ores are quite high, thus certain amount of lime should be used as fluxing material to achieve good fluidity and desulfurization capacity in industrial smelting process. However, this operation leads to an additional cost of lime. In addition, the increase of slag volume decreases the effective furnace volume. To avoid such problem, partial reduction of FeO has been suggested. Therefore, the high SiO2, low MgO and FeO and very little CaO slag is formed, which was less studied in the previous literature. Therefore, the viscosity and slag structure are investigated in the present study through FT-IR and Raman analysis methods. Experimental results show that the slag is a mixture of liquid and solid phases under the experimental temperature. The FT-IR and Raman spectra show that the fractions of the complex polymerization structure decrease significantly with the increase of FeO content and slag basicity, resulting in the decrease of apparent viscosity.
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issn 1450-5339
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language English
publishDate 2017-01-01
publisher University of Belgrade, Technical Faculty, Bor
record_format Article
series Journal of Mining and Metallurgy. Section B: Metallurgy
spelling doaj-art-b7e0f491e6124bbda8df06ea3b203d5b2025-02-02T17:47:11ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392217-71752017-01-0153214715410.2298/JMMB150911002L1450-53391700002LViscosity and structure evolution of the SiO2-MgO-FeO-CaO-Al2O3 slag in ferronickel smelting process from lateriteLv X.M.0Lv X.W.1Wang L.W.2Qiu J.3Liu M.4Chongqing University, School of Materials Science and Engineering, Chongqing, ChinaChongqing University, School of Materials Science and Engineering, Chongqing, ChinaChongqing University, School of Materials Science and Engineering, Chongqing, ChinaChongqing University, School of Materials Science and Engineering, Chongqing, ChinaChongqing University, School of Materials Science and Engineering, Chongqing, ChinaThe SiO2 fractions in laterite-nickel ores are quite high, thus certain amount of lime should be used as fluxing material to achieve good fluidity and desulfurization capacity in industrial smelting process. However, this operation leads to an additional cost of lime. In addition, the increase of slag volume decreases the effective furnace volume. To avoid such problem, partial reduction of FeO has been suggested. Therefore, the high SiO2, low MgO and FeO and very little CaO slag is formed, which was less studied in the previous literature. Therefore, the viscosity and slag structure are investigated in the present study through FT-IR and Raman analysis methods. Experimental results show that the slag is a mixture of liquid and solid phases under the experimental temperature. The FT-IR and Raman spectra show that the fractions of the complex polymerization structure decrease significantly with the increase of FeO content and slag basicity, resulting in the decrease of apparent viscosity.http://www.doiserbia.nb.rs/img/doi/1450-5339/2017/1450-53391700002L.pdflaterite-nickel oreslag structureviscositybasicity
spellingShingle Lv X.M.
Lv X.W.
Wang L.W.
Qiu J.
Liu M.
Viscosity and structure evolution of the SiO2-MgO-FeO-CaO-Al2O3 slag in ferronickel smelting process from laterite
Journal of Mining and Metallurgy. Section B: Metallurgy
laterite-nickel ore
slag structure
viscosity
basicity
title Viscosity and structure evolution of the SiO2-MgO-FeO-CaO-Al2O3 slag in ferronickel smelting process from laterite
title_full Viscosity and structure evolution of the SiO2-MgO-FeO-CaO-Al2O3 slag in ferronickel smelting process from laterite
title_fullStr Viscosity and structure evolution of the SiO2-MgO-FeO-CaO-Al2O3 slag in ferronickel smelting process from laterite
title_full_unstemmed Viscosity and structure evolution of the SiO2-MgO-FeO-CaO-Al2O3 slag in ferronickel smelting process from laterite
title_short Viscosity and structure evolution of the SiO2-MgO-FeO-CaO-Al2O3 slag in ferronickel smelting process from laterite
title_sort viscosity and structure evolution of the sio2 mgo feo cao al2o3 slag in ferronickel smelting process from laterite
topic laterite-nickel ore
slag structure
viscosity
basicity
url http://www.doiserbia.nb.rs/img/doi/1450-5339/2017/1450-53391700002L.pdf
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