High-performance triboelectric nanogenerators based on Ag-doped ZnO loaded electrospun PVDF nanofiber mats for energy harvesting and healthcare monitoring

Abstract This study investigates the potential of zinc oxide (ZnO) and Ag-doped zinc oxide (Ag-ZnO) nanoparticles (NPs) (1, 3 and 5 wt%) electrospun into poly(vinylidene fluoride) (PVDF) based triboelectric nanogenerators (TENGs) to harness electrical energy from ambient mechanical vibrations. ZnO a...

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Main Authors: Hema Malini Venkatesan, Anand Prabu Arun
Format: Article
Language:English
Published: Nature Portfolio 2025-01-01
Series:Scientific Reports
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Online Access:https://doi.org/10.1038/s41598-025-87148-8
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author Hema Malini Venkatesan
Anand Prabu Arun
author_facet Hema Malini Venkatesan
Anand Prabu Arun
author_sort Hema Malini Venkatesan
collection DOAJ
description Abstract This study investigates the potential of zinc oxide (ZnO) and Ag-doped zinc oxide (Ag-ZnO) nanoparticles (NPs) (1, 3 and 5 wt%) electrospun into poly(vinylidene fluoride) (PVDF) based triboelectric nanogenerators (TENGs) to harness electrical energy from ambient mechanical vibrations. ZnO and Ag-ZnO NPs were developed using a co-precipitation method. 3 wt% Ag-ZnO doping was optimized to exhibit a higher β-crystalline phase in PVDF (PAZ3). The electrospun ZnO and Ag-ZnO loaded PVDF nanofiber mats (NFMs) served as tribo-negative layer, while thermoplastic polyurethane (TPU) served as tribo-positive layer in the TENG device fabrication. The electrical measurement results revealed that pristine PVDF/TPU-based TENG device exhibited lower performance (V oc = 9.0 V and I sc = 0.6 µA) compared to the optimized PAZ3/TPU-based TENG (V oc = 51 V and I sc = 1.2 µA), and utilized for concurrent applications such as powering over 10 light-emitting diodes, energy harvesting and healthcare monitoring applications. Overall, the study not only reveals the significant potential of PAZ3/TPU-based TENG for excellent output performance, but also provides a new insight into next-generation clean, affordable and sustainable energy harvesting materials.
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spelling doaj-art-b77d3eca6871486591b3621650a92fe52025-02-02T12:23:47ZengNature PortfolioScientific Reports2045-23222025-01-0115111710.1038/s41598-025-87148-8High-performance triboelectric nanogenerators based on Ag-doped ZnO loaded electrospun PVDF nanofiber mats for energy harvesting and healthcare monitoringHema Malini Venkatesan0Anand Prabu Arun1Department of Chemistry, School of Advanced Sciences, Vellore Institute of TechnologyDepartment of Chemistry, School of Advanced Sciences, Vellore Institute of TechnologyAbstract This study investigates the potential of zinc oxide (ZnO) and Ag-doped zinc oxide (Ag-ZnO) nanoparticles (NPs) (1, 3 and 5 wt%) electrospun into poly(vinylidene fluoride) (PVDF) based triboelectric nanogenerators (TENGs) to harness electrical energy from ambient mechanical vibrations. ZnO and Ag-ZnO NPs were developed using a co-precipitation method. 3 wt% Ag-ZnO doping was optimized to exhibit a higher β-crystalline phase in PVDF (PAZ3). The electrospun ZnO and Ag-ZnO loaded PVDF nanofiber mats (NFMs) served as tribo-negative layer, while thermoplastic polyurethane (TPU) served as tribo-positive layer in the TENG device fabrication. The electrical measurement results revealed that pristine PVDF/TPU-based TENG device exhibited lower performance (V oc = 9.0 V and I sc = 0.6 µA) compared to the optimized PAZ3/TPU-based TENG (V oc = 51 V and I sc = 1.2 µA), and utilized for concurrent applications such as powering over 10 light-emitting diodes, energy harvesting and healthcare monitoring applications. Overall, the study not only reveals the significant potential of PAZ3/TPU-based TENG for excellent output performance, but also provides a new insight into next-generation clean, affordable and sustainable energy harvesting materials.https://doi.org/10.1038/s41598-025-87148-8Silver doped zinc oxidePoly(vinylidene fluoride)ElectrospinningTriboelectric nanogeneratorEnergy harvestingHealthcare monitoring
spellingShingle Hema Malini Venkatesan
Anand Prabu Arun
High-performance triboelectric nanogenerators based on Ag-doped ZnO loaded electrospun PVDF nanofiber mats for energy harvesting and healthcare monitoring
Scientific Reports
Silver doped zinc oxide
Poly(vinylidene fluoride)
Electrospinning
Triboelectric nanogenerator
Energy harvesting
Healthcare monitoring
title High-performance triboelectric nanogenerators based on Ag-doped ZnO loaded electrospun PVDF nanofiber mats for energy harvesting and healthcare monitoring
title_full High-performance triboelectric nanogenerators based on Ag-doped ZnO loaded electrospun PVDF nanofiber mats for energy harvesting and healthcare monitoring
title_fullStr High-performance triboelectric nanogenerators based on Ag-doped ZnO loaded electrospun PVDF nanofiber mats for energy harvesting and healthcare monitoring
title_full_unstemmed High-performance triboelectric nanogenerators based on Ag-doped ZnO loaded electrospun PVDF nanofiber mats for energy harvesting and healthcare monitoring
title_short High-performance triboelectric nanogenerators based on Ag-doped ZnO loaded electrospun PVDF nanofiber mats for energy harvesting and healthcare monitoring
title_sort high performance triboelectric nanogenerators based on ag doped zno loaded electrospun pvdf nanofiber mats for energy harvesting and healthcare monitoring
topic Silver doped zinc oxide
Poly(vinylidene fluoride)
Electrospinning
Triboelectric nanogenerator
Energy harvesting
Healthcare monitoring
url https://doi.org/10.1038/s41598-025-87148-8
work_keys_str_mv AT hemamalinivenkatesan highperformancetriboelectricnanogeneratorsbasedonagdopedznoloadedelectrospunpvdfnanofibermatsforenergyharvestingandhealthcaremonitoring
AT anandprabuarun highperformancetriboelectricnanogeneratorsbasedonagdopedznoloadedelectrospunpvdfnanofibermatsforenergyharvestingandhealthcaremonitoring