Influence of quartz types on mechanical parameters in the early silurian Longmaxi shale, Sichuan Basin

Abstract Quartz is one of the most abundant minerals in shales, occurring predominantly in three forms: biogenic quartz (BQ), detrital quartz (DQ) and clay-transformed quartz (CTQ). The content of quartz is typically correlated with the fracability of shale gas reservoirs. However, the origins of qu...

Full description

Saved in:
Bibliographic Details
Main Authors: Qin Zhang, Feng Liang, Qun Zhao, Wen Liu, Weiliang Kong, Wanli Gao, Xinyu Zhang, Guangyin Cai, Tianquan Qu, Zhen Qiu
Format: Article
Language:English
Published: Nature Portfolio 2024-12-01
Series:Scientific Reports
Subjects:
Online Access:https://doi.org/10.1038/s41598-024-80776-6
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832571677677977600
author Qin Zhang
Feng Liang
Qun Zhao
Wen Liu
Weiliang Kong
Wanli Gao
Xinyu Zhang
Guangyin Cai
Tianquan Qu
Zhen Qiu
author_facet Qin Zhang
Feng Liang
Qun Zhao
Wen Liu
Weiliang Kong
Wanli Gao
Xinyu Zhang
Guangyin Cai
Tianquan Qu
Zhen Qiu
author_sort Qin Zhang
collection DOAJ
description Abstract Quartz is one of the most abundant minerals in shales, occurring predominantly in three forms: biogenic quartz (BQ), detrital quartz (DQ) and clay-transformed quartz (CTQ). The content of quartz is typically correlated with the fracability of shale gas reservoirs. However, the origins of quartz and its influence on mechanical properties remain not fully elucidated. To address this gap, this study examines shale samples from LM1-LM8 graptolite zones in well W202 of the Weiyuan shale gas field, the Sichuan Basin as the research object. After systematic analysis of organic geochemistry, mineral composition, cathodoluminescence observation, major/trace elements, and log interpretation and calculation of shale mechanical parameters, the genetic mechanism of quartz was analyzed and the percentage of quartz of different origins and the influence on rock mechanical properties were evaluated quantitatively. The results indicate that the three types of quartz (BQ, DQ and CTQ) were variably present in the Longmaxi shale across different graptolite zones. The LM1-LM3 graptolite zones exhibit the highest abundance of BQ, with contents ranging from 58.3 to 79.6%, with an average of 65.7%. DQ predominates in the LM4-LM5 and LM6-LM8 graptolite zones, with average contents of 38.7% and 34.9%, respectively. The BQ content is marginally higher in the LM4-LM5 zone compared to the LM6-LM8 zone, averaging 12.7% and 6.1%, respectively. The three types of quartz exert a dual influence on Young’s modulus, and a single linear effect on Poisson’s ratio. An increase BQ content correlates with a decreased in Poisson’s ratio, whereas increased contents of DQ and CTQ correlate with an increased Poisson’s ratio. With the highest Young’s modulus and the lowest Poisson’s ratio, the LM1-LM3 shale is the most favorable interval for hydraulic fracturing. Furthermore, BQ is positively correlated with the Brittleness index (BI), whereas the contents of DQ and CTQ are negatively correlated with BI. When the quartz content falls between 52% and 85%, the ratio of DQ to BQ is optimal for fracture development coinciding with high BI values, which are most conducive to fracturing stimulation.
format Article
id doaj-art-b763360b599e4cab8d64b260805eb961
institution Kabale University
issn 2045-2322
language English
publishDate 2024-12-01
publisher Nature Portfolio
record_format Article
series Scientific Reports
spelling doaj-art-b763360b599e4cab8d64b260805eb9612025-02-02T12:24:56ZengNature PortfolioScientific Reports2045-23222024-12-0114111710.1038/s41598-024-80776-6Influence of quartz types on mechanical parameters in the early silurian Longmaxi shale, Sichuan BasinQin Zhang0Feng Liang1Qun Zhao2Wen Liu3Weiliang Kong4Wanli Gao5Xinyu Zhang6Guangyin Cai7Tianquan Qu8Zhen Qiu9PetroChina Research Institute of Petroleum Exploration and DevelopmentPetroChina Research Institute of Petroleum Exploration and DevelopmentPetroChina Research Institute of Petroleum Exploration and DevelopmentPetroChina Research Institute of Petroleum Exploration and DevelopmentPetroChina Research Institute of Petroleum Exploration and DevelopmentPetroChina Research Institute of Petroleum Exploration and DevelopmentCollege of Mining Engineering, Taiyuan University of TechnologyPetroChina Research Institute of Petroleum Exploration and DevelopmentPetroChina Research Institute of Petroleum Exploration and DevelopmentPetroChina Research Institute of Petroleum Exploration and DevelopmentAbstract Quartz is one of the most abundant minerals in shales, occurring predominantly in three forms: biogenic quartz (BQ), detrital quartz (DQ) and clay-transformed quartz (CTQ). The content of quartz is typically correlated with the fracability of shale gas reservoirs. However, the origins of quartz and its influence on mechanical properties remain not fully elucidated. To address this gap, this study examines shale samples from LM1-LM8 graptolite zones in well W202 of the Weiyuan shale gas field, the Sichuan Basin as the research object. After systematic analysis of organic geochemistry, mineral composition, cathodoluminescence observation, major/trace elements, and log interpretation and calculation of shale mechanical parameters, the genetic mechanism of quartz was analyzed and the percentage of quartz of different origins and the influence on rock mechanical properties were evaluated quantitatively. The results indicate that the three types of quartz (BQ, DQ and CTQ) were variably present in the Longmaxi shale across different graptolite zones. The LM1-LM3 graptolite zones exhibit the highest abundance of BQ, with contents ranging from 58.3 to 79.6%, with an average of 65.7%. DQ predominates in the LM4-LM5 and LM6-LM8 graptolite zones, with average contents of 38.7% and 34.9%, respectively. The BQ content is marginally higher in the LM4-LM5 zone compared to the LM6-LM8 zone, averaging 12.7% and 6.1%, respectively. The three types of quartz exert a dual influence on Young’s modulus, and a single linear effect on Poisson’s ratio. An increase BQ content correlates with a decreased in Poisson’s ratio, whereas increased contents of DQ and CTQ correlate with an increased Poisson’s ratio. With the highest Young’s modulus and the lowest Poisson’s ratio, the LM1-LM3 shale is the most favorable interval for hydraulic fracturing. Furthermore, BQ is positively correlated with the Brittleness index (BI), whereas the contents of DQ and CTQ are negatively correlated with BI. When the quartz content falls between 52% and 85%, the ratio of DQ to BQ is optimal for fracture development coinciding with high BI values, which are most conducive to fracturing stimulation.https://doi.org/10.1038/s41598-024-80776-6Quartz typesYoung’s modulusPoisson’s ratioBrittleness indexLongmaxi ShaleSichuan Basin
spellingShingle Qin Zhang
Feng Liang
Qun Zhao
Wen Liu
Weiliang Kong
Wanli Gao
Xinyu Zhang
Guangyin Cai
Tianquan Qu
Zhen Qiu
Influence of quartz types on mechanical parameters in the early silurian Longmaxi shale, Sichuan Basin
Scientific Reports
Quartz types
Young’s modulus
Poisson’s ratio
Brittleness index
Longmaxi Shale
Sichuan Basin
title Influence of quartz types on mechanical parameters in the early silurian Longmaxi shale, Sichuan Basin
title_full Influence of quartz types on mechanical parameters in the early silurian Longmaxi shale, Sichuan Basin
title_fullStr Influence of quartz types on mechanical parameters in the early silurian Longmaxi shale, Sichuan Basin
title_full_unstemmed Influence of quartz types on mechanical parameters in the early silurian Longmaxi shale, Sichuan Basin
title_short Influence of quartz types on mechanical parameters in the early silurian Longmaxi shale, Sichuan Basin
title_sort influence of quartz types on mechanical parameters in the early silurian longmaxi shale sichuan basin
topic Quartz types
Young’s modulus
Poisson’s ratio
Brittleness index
Longmaxi Shale
Sichuan Basin
url https://doi.org/10.1038/s41598-024-80776-6
work_keys_str_mv AT qinzhang influenceofquartztypesonmechanicalparametersintheearlysilurianlongmaxishalesichuanbasin
AT fengliang influenceofquartztypesonmechanicalparametersintheearlysilurianlongmaxishalesichuanbasin
AT qunzhao influenceofquartztypesonmechanicalparametersintheearlysilurianlongmaxishalesichuanbasin
AT wenliu influenceofquartztypesonmechanicalparametersintheearlysilurianlongmaxishalesichuanbasin
AT weiliangkong influenceofquartztypesonmechanicalparametersintheearlysilurianlongmaxishalesichuanbasin
AT wanligao influenceofquartztypesonmechanicalparametersintheearlysilurianlongmaxishalesichuanbasin
AT xinyuzhang influenceofquartztypesonmechanicalparametersintheearlysilurianlongmaxishalesichuanbasin
AT guangyincai influenceofquartztypesonmechanicalparametersintheearlysilurianlongmaxishalesichuanbasin
AT tianquanqu influenceofquartztypesonmechanicalparametersintheearlysilurianlongmaxishalesichuanbasin
AT zhenqiu influenceofquartztypesonmechanicalparametersintheearlysilurianlongmaxishalesichuanbasin