Nucleation of Gold in the Electric Field on the Surface of Template

The comparative study of gold nanoclusters phase formation processes in the matrix of poly-N-vinil-carbazole ( PVCa) at co-condensation from the gas phase in local electric field near the surface of the template and on the surface of neutral substrates is investigated. TEM studies have directly obse...

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Main Authors: M.Yu. Barabash, E.L. Martynchuk, D.A. Grynko, R.V. Litvin
Format: Article
Language:English
Published: Sumy State University 2014-04-01
Series:Журнал нано- та електронної фізики
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Online Access:http://jnep.sumdu.edu.ua/download/numbers/2014/1/articles/jnep_2014_V6_01029.pdf
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author M.Yu. Barabash
E.L. Martynchuk
D.A. Grynko
R.V. Litvin
author_facet M.Yu. Barabash
E.L. Martynchuk
D.A. Grynko
R.V. Litvin
author_sort M.Yu. Barabash
collection DOAJ
description The comparative study of gold nanoclusters phase formation processes in the matrix of poly-N-vinil-carbazole ( PVCa) at co-condensation from the gas phase in local electric field near the surface of the template and on the surface of neutral substrates is investigated. TEM studies have directly observed the golden critical nuclei in the PVCa matrix and determine their size. Experimentally proved that the size of the gold critical nuclei is 1.9 nm, whereas in the non-uniform electric field of the template is reduced it to 1.2 nm. Modelling the influence of polarization component on Au nucleation within the thermodynamic approach to electrically charged and neutral gold nanoclusters showed the possibility of the existence of the measured changes in the critical nucleus size in the field 108-1010 V/m.
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id doaj-art-b74b11b83dba40e3a285f71f57b3c96f
institution OA Journals
issn 2077-6772
language English
publishDate 2014-04-01
publisher Sumy State University
record_format Article
series Журнал нано- та електронної фізики
spelling doaj-art-b74b11b83dba40e3a285f71f57b3c96f2025-08-20T02:19:19ZengSumy State UniversityЖурнал нано- та електронної фізики2077-67722014-04-016101029-101029-6Nucleation of Gold in the Electric Field on the Surface of TemplateM.Yu. Barabash0E.L. Martynchuk1D.A. Grynko2R.V. Litvin3Technical Centre National Academy of Science of Ukraine, 13 Pokrovskaya Str., 04070 Kiev, UkraineTechnical Centre National Academy of Science of Ukraine, 13 Pokrovskaya Str., 04070 Kiev, UkraineInstitute of Semiconductor Physics NAS of Ukraine 41 Nauki. Pr., 03680, Kiev, UkraineI. M. Frantsevich Institute for Problems of Materials Sciences of NAS Ukraine, 3, Krzhizhanovskoho Str., 03680, Kyiv, UkraineThe comparative study of gold nanoclusters phase formation processes in the matrix of poly-N-vinil-carbazole ( PVCa) at co-condensation from the gas phase in local electric field near the surface of the template and on the surface of neutral substrates is investigated. TEM studies have directly observed the golden critical nuclei in the PVCa matrix and determine their size. Experimentally proved that the size of the gold critical nuclei is 1.9 nm, whereas in the non-uniform electric field of the template is reduced it to 1.2 nm. Modelling the influence of polarization component on Au nucleation within the thermodynamic approach to electrically charged and neutral gold nanoclusters showed the possibility of the existence of the measured changes in the critical nucleus size in the field 108-1010 V/m.http://jnep.sumdu.edu.ua/download/numbers/2014/1/articles/jnep_2014_V6_01029.pdfElectrostatic TemplateNanoclustersElectric fieldNanocomposit
spellingShingle M.Yu. Barabash
E.L. Martynchuk
D.A. Grynko
R.V. Litvin
Nucleation of Gold in the Electric Field on the Surface of Template
Журнал нано- та електронної фізики
Electrostatic Template
Nanoclusters
Electric field
Nanocomposit
title Nucleation of Gold in the Electric Field on the Surface of Template
title_full Nucleation of Gold in the Electric Field on the Surface of Template
title_fullStr Nucleation of Gold in the Electric Field on the Surface of Template
title_full_unstemmed Nucleation of Gold in the Electric Field on the Surface of Template
title_short Nucleation of Gold in the Electric Field on the Surface of Template
title_sort nucleation of gold in the electric field on the surface of template
topic Electrostatic Template
Nanoclusters
Electric field
Nanocomposit
url http://jnep.sumdu.edu.ua/download/numbers/2014/1/articles/jnep_2014_V6_01029.pdf
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AT elmartynchuk nucleationofgoldintheelectricfieldonthesurfaceoftemplate
AT dagrynko nucleationofgoldintheelectricfieldonthesurfaceoftemplate
AT rvlitvin nucleationofgoldintheelectricfieldonthesurfaceoftemplate