Dose-Dependent Differentiation of Gamma-Irradiated Hazelnut Samples by Mid-Infrared Spectroscopy Coupled with Chemometrics

Gamma irradiation is used as a food preservation method. It is known that high-dose irradiation causes several structural and functional damages. Therefore, the detection of high-dose irradiated food samples is a critical issue in international trade. The objective of this work is to evaluate the po...

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Main Authors: Ayca Dogan, Mete Severcan, Feride Severcan
Format: Article
Language:English
Published: Wiley 2020-01-01
Series:Journal of Spectroscopy
Online Access:http://dx.doi.org/10.1155/2020/8859104
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author Ayca Dogan
Mete Severcan
Feride Severcan
author_facet Ayca Dogan
Mete Severcan
Feride Severcan
author_sort Ayca Dogan
collection DOAJ
description Gamma irradiation is used as a food preservation method. It is known that high-dose irradiation causes several structural and functional damages. Therefore, the detection of high-dose irradiated food samples is a critical issue in international trade. The objective of this work is to evaluate the potential of Fourier transform infrared (FTIR) spectroscopy for the differentiation of γ-irradiated hazelnuts at higher doses (3 kGy and 10 kGy) from the lower (1.5 kGy) and nonirradiated ones using multivariate statistical analysis, namely, principal component analysis (PCA) and hierarchical cluster analysis (HCA). This study showed that high-dose irradiated hazelnut samples can be clearly differentiated from the low-dose irradiated samples using unsupervised methods based on the spectral differences. Furthermore, dose-dependent discrimination was also achieved. In conclusion, FTIR spectroscopy combined with multivariate statistical analysis has potential for the development of a reliable and fast methodology for separation of high-dose irradiated food samples.
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spelling doaj-art-b7293612e7db4f80a2600819cd4ee22c2025-02-03T06:00:48ZengWileyJournal of Spectroscopy2314-49202314-49392020-01-01202010.1155/2020/88591048859104Dose-Dependent Differentiation of Gamma-Irradiated Hazelnut Samples by Mid-Infrared Spectroscopy Coupled with ChemometricsAyca Dogan0Mete Severcan1Feride Severcan2Department of Physiology, Faculty of Medicine, Altinbas University, Istanbul 34145, TurkeyDepartment of Electrical and Electronics Engineering, Altinbas University, Istanbul 34145, TurkeyDepartment of Biophysics, Faculty of Medicine, Altinbas University, Istanbul 34145, TurkeyGamma irradiation is used as a food preservation method. It is known that high-dose irradiation causes several structural and functional damages. Therefore, the detection of high-dose irradiated food samples is a critical issue in international trade. The objective of this work is to evaluate the potential of Fourier transform infrared (FTIR) spectroscopy for the differentiation of γ-irradiated hazelnuts at higher doses (3 kGy and 10 kGy) from the lower (1.5 kGy) and nonirradiated ones using multivariate statistical analysis, namely, principal component analysis (PCA) and hierarchical cluster analysis (HCA). This study showed that high-dose irradiated hazelnut samples can be clearly differentiated from the low-dose irradiated samples using unsupervised methods based on the spectral differences. Furthermore, dose-dependent discrimination was also achieved. In conclusion, FTIR spectroscopy combined with multivariate statistical analysis has potential for the development of a reliable and fast methodology for separation of high-dose irradiated food samples.http://dx.doi.org/10.1155/2020/8859104
spellingShingle Ayca Dogan
Mete Severcan
Feride Severcan
Dose-Dependent Differentiation of Gamma-Irradiated Hazelnut Samples by Mid-Infrared Spectroscopy Coupled with Chemometrics
Journal of Spectroscopy
title Dose-Dependent Differentiation of Gamma-Irradiated Hazelnut Samples by Mid-Infrared Spectroscopy Coupled with Chemometrics
title_full Dose-Dependent Differentiation of Gamma-Irradiated Hazelnut Samples by Mid-Infrared Spectroscopy Coupled with Chemometrics
title_fullStr Dose-Dependent Differentiation of Gamma-Irradiated Hazelnut Samples by Mid-Infrared Spectroscopy Coupled with Chemometrics
title_full_unstemmed Dose-Dependent Differentiation of Gamma-Irradiated Hazelnut Samples by Mid-Infrared Spectroscopy Coupled with Chemometrics
title_short Dose-Dependent Differentiation of Gamma-Irradiated Hazelnut Samples by Mid-Infrared Spectroscopy Coupled with Chemometrics
title_sort dose dependent differentiation of gamma irradiated hazelnut samples by mid infrared spectroscopy coupled with chemometrics
url http://dx.doi.org/10.1155/2020/8859104
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AT metesevercan dosedependentdifferentiationofgammairradiatedhazelnutsamplesbymidinfraredspectroscopycoupledwithchemometrics
AT feridesevercan dosedependentdifferentiationofgammairradiatedhazelnutsamplesbymidinfraredspectroscopycoupledwithchemometrics