Viscosities and Conductivities of [BMIM]Zn(Ac)xCly(x=0,1,2,3; y=3,2,1,0) Ionic Liquids at Different Temperatures

Viscosity and conductivity data of BMIMZnAcxCly(x=0,1,2,3;  y=3,2,1,0) ionic liquids were detected at temperature ranging from 323.15 to 353.15 K with an interval of 5 K. The conductivities of different ionic liquids at the same temperature followed the trend [BMIM][ZnAcCl2] > [BMIM][ZnAc2Cl] >...

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Main Authors: Hang Xu, Dandan Zhang
Format: Article
Language:English
Published: Wiley 2017-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2017/7428097
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author Hang Xu
Dandan Zhang
author_facet Hang Xu
Dandan Zhang
author_sort Hang Xu
collection DOAJ
description Viscosity and conductivity data of BMIMZnAcxCly(x=0,1,2,3;  y=3,2,1,0) ionic liquids were detected at temperature ranging from 323.15 to 353.15 K with an interval of 5 K. The conductivities of different ionic liquids at the same temperature followed the trend [BMIM][ZnAcCl2] > [BMIM][ZnAc2Cl] > [BMIM][ZnCl3] > [BMIM][ZnAc3]. The viscosities of different ionic liquid abided by the order [BMIM][ZnCl3] > [BMIM][ZnAcCl2] > [BMIM][ZnAc2Cl] > [BMIM][ZnAc3]. Acetate ion could reduce the viscosity of ionic liquids. The relationship between viscosity/conductivity and temperature obeyed the Arrhenius equation and Vogel-Fulcher-Tammann (VFT) equation very well with above 0.99 correlation coefficients.
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institution Kabale University
issn 2090-9063
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language English
publishDate 2017-01-01
publisher Wiley
record_format Article
series Journal of Chemistry
spelling doaj-art-b6ed791ab2f44ebcb966724d6b944ed32025-02-03T01:25:53ZengWileyJournal of Chemistry2090-90632090-90712017-01-01201710.1155/2017/74280977428097Viscosities and Conductivities of [BMIM]Zn(Ac)xCly(x=0,1,2,3; y=3,2,1,0) Ionic Liquids at Different TemperaturesHang Xu0Dandan Zhang1Chemical Engineering and Pharmaceutics School, Henan University of Science and Technology, Luoyang 471023, ChinaChemical Engineering and Pharmaceutics School, Henan University of Science and Technology, Luoyang 471023, ChinaViscosity and conductivity data of BMIMZnAcxCly(x=0,1,2,3;  y=3,2,1,0) ionic liquids were detected at temperature ranging from 323.15 to 353.15 K with an interval of 5 K. The conductivities of different ionic liquids at the same temperature followed the trend [BMIM][ZnAcCl2] > [BMIM][ZnAc2Cl] > [BMIM][ZnCl3] > [BMIM][ZnAc3]. The viscosities of different ionic liquid abided by the order [BMIM][ZnCl3] > [BMIM][ZnAcCl2] > [BMIM][ZnAc2Cl] > [BMIM][ZnAc3]. Acetate ion could reduce the viscosity of ionic liquids. The relationship between viscosity/conductivity and temperature obeyed the Arrhenius equation and Vogel-Fulcher-Tammann (VFT) equation very well with above 0.99 correlation coefficients.http://dx.doi.org/10.1155/2017/7428097
spellingShingle Hang Xu
Dandan Zhang
Viscosities and Conductivities of [BMIM]Zn(Ac)xCly(x=0,1,2,3; y=3,2,1,0) Ionic Liquids at Different Temperatures
Journal of Chemistry
title Viscosities and Conductivities of [BMIM]Zn(Ac)xCly(x=0,1,2,3; y=3,2,1,0) Ionic Liquids at Different Temperatures
title_full Viscosities and Conductivities of [BMIM]Zn(Ac)xCly(x=0,1,2,3; y=3,2,1,0) Ionic Liquids at Different Temperatures
title_fullStr Viscosities and Conductivities of [BMIM]Zn(Ac)xCly(x=0,1,2,3; y=3,2,1,0) Ionic Liquids at Different Temperatures
title_full_unstemmed Viscosities and Conductivities of [BMIM]Zn(Ac)xCly(x=0,1,2,3; y=3,2,1,0) Ionic Liquids at Different Temperatures
title_short Viscosities and Conductivities of [BMIM]Zn(Ac)xCly(x=0,1,2,3; y=3,2,1,0) Ionic Liquids at Different Temperatures
title_sort viscosities and conductivities of bmim zn ac xcly x 0 1 2 3 y 3 2 1 0 ionic liquids at different temperatures
url http://dx.doi.org/10.1155/2017/7428097
work_keys_str_mv AT hangxu viscositiesandconductivitiesofbmimznacxclyx0123y3210ionicliquidsatdifferenttemperatures
AT dandanzhang viscositiesandconductivitiesofbmimznacxclyx0123y3210ionicliquidsatdifferenttemperatures