Valorization of Wasted Black Tea as a Low-Cost Adsorbent for Nickel and Zinc Removal from Aqueous Solution

Characteristics and efficiency of wasted black tea (WBT) were investigated as a low-cost sorbent in removal of Ni2+ and Zn2+ ions from aqueous solution. Initial findings showed WBT potential to be applied as an effective sorbent due to high concentrations of carbon and calcium and high porosity and...

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Main Authors: Amirhossein Malakahmad, Sandee Tan, Saba Yavari
Format: Article
Language:English
Published: Wiley 2016-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2016/5680983
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author Amirhossein Malakahmad
Sandee Tan
Saba Yavari
author_facet Amirhossein Malakahmad
Sandee Tan
Saba Yavari
author_sort Amirhossein Malakahmad
collection DOAJ
description Characteristics and efficiency of wasted black tea (WBT) were investigated as a low-cost sorbent in removal of Ni2+ and Zn2+ ions from aqueous solution. Initial findings showed WBT potential to be applied as an effective sorbent due to high concentrations of carbon and calcium and high porosity and availability of functional groups. Sorption dynamics were studied with varying pH, contact time, and adsorbent dose. Maximum percentages of metal ions removal were recorded at pH 5, contact time 250 min, and 20 g/L of adsorbent concentration. Binary metal sorption studies showed that Ni2+ and Zn2+ do not compete with each other for available sorption sites, so the adsorption trend in binary system appears similar to monocomponent metal adsorption. Evaluation of the isotherms confirmed that WBT has high value of adsorption capacity. Sorption data fitted well with both Freundlich and Langmuir models. In the optimum conditions, maximum capacity of WBT could reach up to 90.91 mg-Ni/g adsorbent and 166.67 mg-Zn/g adsorbent. This experiment demonstrated the ability of tea waste as an effective, sustainable, and low-cost adsorbent for removal of the heavy metal ions.
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spelling doaj-art-b646d99c68df44fdacebd9530ffb1ef92025-02-03T05:59:36ZengWileyJournal of Chemistry2090-90632090-90712016-01-01201610.1155/2016/56809835680983Valorization of Wasted Black Tea as a Low-Cost Adsorbent for Nickel and Zinc Removal from Aqueous SolutionAmirhossein Malakahmad0Sandee Tan1Saba Yavari2Department of Civil and Environmental Engineering, Universiti Teknologi PETRONAS, 32610 Bandar Seri Iskandar, MalaysiaDepartment of Civil and Environmental Engineering, Universiti Teknologi PETRONAS, 32610 Bandar Seri Iskandar, MalaysiaDepartment of Civil and Environmental Engineering, Universiti Teknologi PETRONAS, 32610 Bandar Seri Iskandar, MalaysiaCharacteristics and efficiency of wasted black tea (WBT) were investigated as a low-cost sorbent in removal of Ni2+ and Zn2+ ions from aqueous solution. Initial findings showed WBT potential to be applied as an effective sorbent due to high concentrations of carbon and calcium and high porosity and availability of functional groups. Sorption dynamics were studied with varying pH, contact time, and adsorbent dose. Maximum percentages of metal ions removal were recorded at pH 5, contact time 250 min, and 20 g/L of adsorbent concentration. Binary metal sorption studies showed that Ni2+ and Zn2+ do not compete with each other for available sorption sites, so the adsorption trend in binary system appears similar to monocomponent metal adsorption. Evaluation of the isotherms confirmed that WBT has high value of adsorption capacity. Sorption data fitted well with both Freundlich and Langmuir models. In the optimum conditions, maximum capacity of WBT could reach up to 90.91 mg-Ni/g adsorbent and 166.67 mg-Zn/g adsorbent. This experiment demonstrated the ability of tea waste as an effective, sustainable, and low-cost adsorbent for removal of the heavy metal ions.http://dx.doi.org/10.1155/2016/5680983
spellingShingle Amirhossein Malakahmad
Sandee Tan
Saba Yavari
Valorization of Wasted Black Tea as a Low-Cost Adsorbent for Nickel and Zinc Removal from Aqueous Solution
Journal of Chemistry
title Valorization of Wasted Black Tea as a Low-Cost Adsorbent for Nickel and Zinc Removal from Aqueous Solution
title_full Valorization of Wasted Black Tea as a Low-Cost Adsorbent for Nickel and Zinc Removal from Aqueous Solution
title_fullStr Valorization of Wasted Black Tea as a Low-Cost Adsorbent for Nickel and Zinc Removal from Aqueous Solution
title_full_unstemmed Valorization of Wasted Black Tea as a Low-Cost Adsorbent for Nickel and Zinc Removal from Aqueous Solution
title_short Valorization of Wasted Black Tea as a Low-Cost Adsorbent for Nickel and Zinc Removal from Aqueous Solution
title_sort valorization of wasted black tea as a low cost adsorbent for nickel and zinc removal from aqueous solution
url http://dx.doi.org/10.1155/2016/5680983
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AT sandeetan valorizationofwastedblackteaasalowcostadsorbentfornickelandzincremovalfromaqueoussolution
AT sabayavari valorizationofwastedblackteaasalowcostadsorbentfornickelandzincremovalfromaqueoussolution