Transformation of NO in Combustion Gases by DC Corona

This study investigates the performance of DC corona discharge electrostatic precipitators (ESPs) for NO conversion to increase DeNO<sub>x</sub> technologies’ efficiency for small-scale biomass combustion systems. Experiments were conducted using a 5 kW automatic wood pellet domestic hea...

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Main Authors: Oleksandr Molchanov, Kamil Krpec, Jiří Horák, Lenka Kuboňová, František Hopan, Jiří Ryšavý, Marcelina Bury
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Fire
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Online Access:https://www.mdpi.com/2571-6255/8/1/21
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author Oleksandr Molchanov
Kamil Krpec
Jiří Horák
Lenka Kuboňová
František Hopan
Jiří Ryšavý
Marcelina Bury
author_facet Oleksandr Molchanov
Kamil Krpec
Jiří Horák
Lenka Kuboňová
František Hopan
Jiří Ryšavý
Marcelina Bury
author_sort Oleksandr Molchanov
collection DOAJ
description This study investigates the performance of DC corona discharge electrostatic precipitators (ESPs) for NO conversion to increase DeNO<sub>x</sub> technologies’ efficiency for small-scale biomass combustion systems. Experiments were conducted using a 5 kW automatic wood pellet domestic heat source with combustion gas treated in a specially designed ESP operated in both positive and negative corona modes, resulting in a reduction in NO concentrations from 130 mg/m<sup>3</sup> to 27/29 mg/m<sup>3</sup> for positive/negative polarities (at 0 °C and 101.3 kPa). NO conversion efficiency was evaluated across a range of specific input energies (SIEs) from 0 to 50 J/L. The results demonstrate that DC corona ESPs can achieve up to 78% NO reduction, with positive corona demonstrating a greater energy efficiency, requiring a lower SIE (35 J/L) compared to the negative corona mode (48 J/L). A detailed analysis of reaction pathways revealed distinct conversion mechanisms between the two modes. In positive corona, dispersed active species distribution led to more uniform NO conversion, while negative corona exhibited concentrated reaction zones with about 20% higher ozone production. The reactions involving O and OH radicals were more important in positive corona, whereas ozone-mediated oxidation dominated in negative corona. The research results demonstrate that ESP technology with DC corona offers a promising, energy-efficient solution for NO<sub>x</sub> control in small-scale combustion systems.
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publishDate 2025-01-01
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spelling doaj-art-b63d9b591aca41cfa72a1b6d6f73b7eb2025-01-24T13:32:19ZengMDPI AGFire2571-62552025-01-01812110.3390/fire8010021Transformation of NO in Combustion Gases by DC CoronaOleksandr Molchanov0Kamil Krpec1Jiří Horák2Lenka Kuboňová3František Hopan4Jiří Ryšavý5Marcelina Bury6Energy Research Centre, Centre for Energy and Environmental Technologies, VSB—Technical University of Ostrava, 17. listopadu 2172/15, 708 00 Ostrava, Czech RepublicEnergy Research Centre, Centre for Energy and Environmental Technologies, VSB—Technical University of Ostrava, 17. listopadu 2172/15, 708 00 Ostrava, Czech RepublicEnergy Research Centre, Centre for Energy and Environmental Technologies, VSB—Technical University of Ostrava, 17. listopadu 2172/15, 708 00 Ostrava, Czech RepublicEnergy Research Centre, Centre for Energy and Environmental Technologies, VSB—Technical University of Ostrava, 17. listopadu 2172/15, 708 00 Ostrava, Czech RepublicEnergy Research Centre, Centre for Energy and Environmental Technologies, VSB—Technical University of Ostrava, 17. listopadu 2172/15, 708 00 Ostrava, Czech RepublicEnergy Research Centre, Centre for Energy and Environmental Technologies, VSB—Technical University of Ostrava, 17. listopadu 2172/15, 708 00 Ostrava, Czech RepublicFaculty of Energy and Fuels, Department of Fuels Technology, AGH University of Krakow, al. A. Mickiewicza 30, 30-059 Krakow, PolandThis study investigates the performance of DC corona discharge electrostatic precipitators (ESPs) for NO conversion to increase DeNO<sub>x</sub> technologies’ efficiency for small-scale biomass combustion systems. Experiments were conducted using a 5 kW automatic wood pellet domestic heat source with combustion gas treated in a specially designed ESP operated in both positive and negative corona modes, resulting in a reduction in NO concentrations from 130 mg/m<sup>3</sup> to 27/29 mg/m<sup>3</sup> for positive/negative polarities (at 0 °C and 101.3 kPa). NO conversion efficiency was evaluated across a range of specific input energies (SIEs) from 0 to 50 J/L. The results demonstrate that DC corona ESPs can achieve up to 78% NO reduction, with positive corona demonstrating a greater energy efficiency, requiring a lower SIE (35 J/L) compared to the negative corona mode (48 J/L). A detailed analysis of reaction pathways revealed distinct conversion mechanisms between the two modes. In positive corona, dispersed active species distribution led to more uniform NO conversion, while negative corona exhibited concentrated reaction zones with about 20% higher ozone production. The reactions involving O and OH radicals were more important in positive corona, whereas ozone-mediated oxidation dominated in negative corona. The research results demonstrate that ESP technology with DC corona offers a promising, energy-efficient solution for NO<sub>x</sub> control in small-scale combustion systems.https://www.mdpi.com/2571-6255/8/1/21electrostatic precipitatorsmall-scale combustionpollution controlNO<sub>x</sub>PM
spellingShingle Oleksandr Molchanov
Kamil Krpec
Jiří Horák
Lenka Kuboňová
František Hopan
Jiří Ryšavý
Marcelina Bury
Transformation of NO in Combustion Gases by DC Corona
Fire
electrostatic precipitator
small-scale combustion
pollution control
NO<sub>x</sub>
PM
title Transformation of NO in Combustion Gases by DC Corona
title_full Transformation of NO in Combustion Gases by DC Corona
title_fullStr Transformation of NO in Combustion Gases by DC Corona
title_full_unstemmed Transformation of NO in Combustion Gases by DC Corona
title_short Transformation of NO in Combustion Gases by DC Corona
title_sort transformation of no in combustion gases by dc corona
topic electrostatic precipitator
small-scale combustion
pollution control
NO<sub>x</sub>
PM
url https://www.mdpi.com/2571-6255/8/1/21
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