New Plastitar Record for the Mediterranean Sea: Characterization of Plastics and Tar from the Salento Peninsula (Ionian Sea)

The various forms of anthropogenic pollution are regarded as a serious threat to marine coastal areas. The overproduction and mismanagement of petroleum derivatives, such as tar and plastics, have resulted in a significant correlation between these two pollutants. The aggregation of tar, microplasti...

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Main Authors: Silvia Fraissinet, Emanuele Mancini, Chiara Funiati, Caterina Martino, Giuseppe Egidio De Benedetto, Chiara Roberta Girelli, Francesco Paolo Fanizzi, Genuario Belmonte, Stefano Piraino
Format: Article
Language:English
Published: MDPI AG 2024-12-01
Series:Toxics
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Online Access:https://www.mdpi.com/2305-6304/13/1/13
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author Silvia Fraissinet
Emanuele Mancini
Chiara Funiati
Caterina Martino
Giuseppe Egidio De Benedetto
Chiara Roberta Girelli
Francesco Paolo Fanizzi
Genuario Belmonte
Stefano Piraino
author_facet Silvia Fraissinet
Emanuele Mancini
Chiara Funiati
Caterina Martino
Giuseppe Egidio De Benedetto
Chiara Roberta Girelli
Francesco Paolo Fanizzi
Genuario Belmonte
Stefano Piraino
author_sort Silvia Fraissinet
collection DOAJ
description The various forms of anthropogenic pollution are regarded as a serious threat to marine coastal areas. The overproduction and mismanagement of petroleum derivatives, such as tar and plastics, have resulted in a significant correlation between these two pollutants. The aggregation of tar, microplastics (MPs), and natural materials can create plastitar blocks, which are common in coastal areas. These raise concern about the undeniable negative impact on the marine ecosystem and the associated biota, and serve as a recognizable and understandable indication of environmental decline. Here, the composition of the 11 plastitar blocks collected on the Ionian side of the Apulia region (Italy) was characterized both in tar and plastics using nuclear magnetic resonance (NMR) spectroscopy and Fourier transform infrared (FTIR) spectroscopy, respectively. Of the 250 particles extracted from the tar, 208 were identified as plastics, predominantly Polyethylene. The majority of these were in the form of pellets (90%), with fragments accounting for 5% and films and filaments representing the remaining 5%. This study provides new data that can be used to enhance the understanding of the distribution and baseline information about this novel form of pollution in Italian waters.
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series Toxics
spelling doaj-art-b551a8aeb4e64b419d0b3e2eb69986492025-01-24T13:50:56ZengMDPI AGToxics2305-63042024-12-011311310.3390/toxics13010013New Plastitar Record for the Mediterranean Sea: Characterization of Plastics and Tar from the Salento Peninsula (Ionian Sea)Silvia Fraissinet0Emanuele Mancini1Chiara Funiati2Caterina Martino3Giuseppe Egidio De Benedetto4Chiara Roberta Girelli5Francesco Paolo Fanizzi6Genuario Belmonte7Stefano Piraino8Department of Biological and Environmental Science and Technology (Di.S.Te.B.A.), University of Salento, Campus Ecotekne, Via Prov. Lecce-Monteroni, 73100 Lecce, ItalyDepartment of Biological and Environmental Science and Technology (Di.S.Te.B.A.), University of Salento, Campus Ecotekne, Via Prov. Lecce-Monteroni, 73100 Lecce, ItalyAcademy of Fine Arts, Via Libertini, 3, 73100 Lecce, ItalyDepartment of Earth and Sea Sciences (DiSTeM), University of Palermo, 90100 Palermo, ItalyLaboratory of Analytical and Isotopic Mass Spectrometry, Department of Cultural Heritage, University of Salento, 73100 Lecce, ItalyDepartment of Biological and Environmental Science and Technology (Di.S.Te.B.A.), University of Salento, Campus Ecotekne, Via Prov. Lecce-Monteroni, 73100 Lecce, ItalyDepartment of Biological and Environmental Science and Technology (Di.S.Te.B.A.), University of Salento, Campus Ecotekne, Via Prov. Lecce-Monteroni, 73100 Lecce, ItalyDepartment of Biological and Environmental Science and Technology (Di.S.Te.B.A.), University of Salento, Campus Ecotekne, Via Prov. Lecce-Monteroni, 73100 Lecce, ItalyDepartment of Biological and Environmental Science and Technology (Di.S.Te.B.A.), University of Salento, Campus Ecotekne, Via Prov. Lecce-Monteroni, 73100 Lecce, ItalyThe various forms of anthropogenic pollution are regarded as a serious threat to marine coastal areas. The overproduction and mismanagement of petroleum derivatives, such as tar and plastics, have resulted in a significant correlation between these two pollutants. The aggregation of tar, microplastics (MPs), and natural materials can create plastitar blocks, which are common in coastal areas. These raise concern about the undeniable negative impact on the marine ecosystem and the associated biota, and serve as a recognizable and understandable indication of environmental decline. Here, the composition of the 11 plastitar blocks collected on the Ionian side of the Apulia region (Italy) was characterized both in tar and plastics using nuclear magnetic resonance (NMR) spectroscopy and Fourier transform infrared (FTIR) spectroscopy, respectively. Of the 250 particles extracted from the tar, 208 were identified as plastics, predominantly Polyethylene. The majority of these were in the form of pellets (90%), with fragments accounting for 5% and films and filaments representing the remaining 5%. This study provides new data that can be used to enhance the understanding of the distribution and baseline information about this novel form of pollution in Italian waters.https://www.mdpi.com/2305-6304/13/1/13Italian coatsmarine pollutiontarpolyethyleneoilmicroplastics
spellingShingle Silvia Fraissinet
Emanuele Mancini
Chiara Funiati
Caterina Martino
Giuseppe Egidio De Benedetto
Chiara Roberta Girelli
Francesco Paolo Fanizzi
Genuario Belmonte
Stefano Piraino
New Plastitar Record for the Mediterranean Sea: Characterization of Plastics and Tar from the Salento Peninsula (Ionian Sea)
Toxics
Italian coats
marine pollution
tar
polyethylene
oil
microplastics
title New Plastitar Record for the Mediterranean Sea: Characterization of Plastics and Tar from the Salento Peninsula (Ionian Sea)
title_full New Plastitar Record for the Mediterranean Sea: Characterization of Plastics and Tar from the Salento Peninsula (Ionian Sea)
title_fullStr New Plastitar Record for the Mediterranean Sea: Characterization of Plastics and Tar from the Salento Peninsula (Ionian Sea)
title_full_unstemmed New Plastitar Record for the Mediterranean Sea: Characterization of Plastics and Tar from the Salento Peninsula (Ionian Sea)
title_short New Plastitar Record for the Mediterranean Sea: Characterization of Plastics and Tar from the Salento Peninsula (Ionian Sea)
title_sort new plastitar record for the mediterranean sea characterization of plastics and tar from the salento peninsula ionian sea
topic Italian coats
marine pollution
tar
polyethylene
oil
microplastics
url https://www.mdpi.com/2305-6304/13/1/13
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