Uniform Decoration of Reduced Graphene Oxide Sheets with Gold Nanoparticles

A simple method employing ionic liquid functionalization is developed to achieve the uniform decoration of reduced graphene oxide sheets with gold nanoparticles. The synthesis of ionic liquid modified graphene oxide is accomplished by covalently binding 1-(3-Aminopropyl) imidazole with GO sheets. Th...

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Bibliographic Details
Main Authors: Huanping Yang, Weiwei Zhou, Bo Yu, Yingying Wang, Chunxiao Cong, Ting Yu
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:Journal of Nanotechnology
Online Access:http://dx.doi.org/10.1155/2012/328565
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Summary:A simple method employing ionic liquid functionalization is developed to achieve the uniform decoration of reduced graphene oxide sheets with gold nanoparticles. The synthesis of ionic liquid modified graphene oxide is accomplished by covalently binding 1-(3-Aminopropyl) imidazole with GO sheets. The formation mechanism of Au nanoparticles on RGO sheets is proposed to load AuCl4- onto the surface of GO sheets through anion exchange; then reduce AuCl4- to Au NPs and at the same time reduce GO sheets to RGO sheets via a one-step process. The presence of Au NPs is well identified by SEM, TEM, and XPS. As a concept, the RGO-supported Au NPs is applied to surface-enhanced Raman spectroscopy.
ISSN:1687-9503
1687-9511