UV Radiation Induced Cross-Linking of Whey Protein Isolate-Based Films

Casted whey protein films exposed to ultraviolet irradiation were analyzed for their cross-linking properties and mechanical and barrier performance. Expected mechanical and barrier improvements are discussed with regard to quantification of the cross-linking in the UV-treated whey protein films. Sw...

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Main Authors: Markus Schmid, Tobias Konrad Prinz, Kerstin Müller, Andreas Haas
Format: Article
Language:English
Published: Wiley 2017-01-01
Series:International Journal of Polymer Science
Online Access:http://dx.doi.org/10.1155/2017/1846031
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author Markus Schmid
Tobias Konrad Prinz
Kerstin Müller
Andreas Haas
author_facet Markus Schmid
Tobias Konrad Prinz
Kerstin Müller
Andreas Haas
author_sort Markus Schmid
collection DOAJ
description Casted whey protein films exposed to ultraviolet irradiation were analyzed for their cross-linking properties and mechanical and barrier performance. Expected mechanical and barrier improvements are discussed with regard to quantification of the cross-linking in the UV-treated whey protein films. Swelling tests were used to determine the degree of swelling, degree of cross-linking, and cross-linking density. When the UV radiation dosage was raised, a significant increase of the tensile strength as well as an increase in Young’s modulus was observed. No significant changes in water vapor and oxygen barrier properties between the UV-treated films and an untreated reference sample could be observed. The cross-linking density and the degree of cross-linking significantly increased due to UV radiation. Combined results indicate a disordered protein network in cast films showing locally free volume and therefore only minor mechanical and barrier improvements.
format Article
id doaj-art-b48d1761241c4c4eb5a108013771ecce
institution Kabale University
issn 1687-9422
1687-9430
language English
publishDate 2017-01-01
publisher Wiley
record_format Article
series International Journal of Polymer Science
spelling doaj-art-b48d1761241c4c4eb5a108013771ecce2025-02-03T05:45:27ZengWileyInternational Journal of Polymer Science1687-94221687-94302017-01-01201710.1155/2017/18460311846031UV Radiation Induced Cross-Linking of Whey Protein Isolate-Based FilmsMarkus Schmid0Tobias Konrad Prinz1Kerstin Müller2Andreas Haas3Fraunhofer Institute for Process Engineering and Packaging IVV, Giggenhauser Strasse 35, 85354 Freising, GermanyFraunhofer Institute for Process Engineering and Packaging IVV, Giggenhauser Strasse 35, 85354 Freising, GermanyFraunhofer Institute for Process Engineering and Packaging IVV, Giggenhauser Strasse 35, 85354 Freising, GermanyFraunhofer Institute for Process Engineering and Packaging IVV, Giggenhauser Strasse 35, 85354 Freising, GermanyCasted whey protein films exposed to ultraviolet irradiation were analyzed for their cross-linking properties and mechanical and barrier performance. Expected mechanical and barrier improvements are discussed with regard to quantification of the cross-linking in the UV-treated whey protein films. Swelling tests were used to determine the degree of swelling, degree of cross-linking, and cross-linking density. When the UV radiation dosage was raised, a significant increase of the tensile strength as well as an increase in Young’s modulus was observed. No significant changes in water vapor and oxygen barrier properties between the UV-treated films and an untreated reference sample could be observed. The cross-linking density and the degree of cross-linking significantly increased due to UV radiation. Combined results indicate a disordered protein network in cast films showing locally free volume and therefore only minor mechanical and barrier improvements.http://dx.doi.org/10.1155/2017/1846031
spellingShingle Markus Schmid
Tobias Konrad Prinz
Kerstin Müller
Andreas Haas
UV Radiation Induced Cross-Linking of Whey Protein Isolate-Based Films
International Journal of Polymer Science
title UV Radiation Induced Cross-Linking of Whey Protein Isolate-Based Films
title_full UV Radiation Induced Cross-Linking of Whey Protein Isolate-Based Films
title_fullStr UV Radiation Induced Cross-Linking of Whey Protein Isolate-Based Films
title_full_unstemmed UV Radiation Induced Cross-Linking of Whey Protein Isolate-Based Films
title_short UV Radiation Induced Cross-Linking of Whey Protein Isolate-Based Films
title_sort uv radiation induced cross linking of whey protein isolate based films
url http://dx.doi.org/10.1155/2017/1846031
work_keys_str_mv AT markusschmid uvradiationinducedcrosslinkingofwheyproteinisolatebasedfilms
AT tobiaskonradprinz uvradiationinducedcrosslinkingofwheyproteinisolatebasedfilms
AT kerstinmuller uvradiationinducedcrosslinkingofwheyproteinisolatebasedfilms
AT andreashaas uvradiationinducedcrosslinkingofwheyproteinisolatebasedfilms