Membrane Fouling and Chemical Cleaning in Three Full-Scale Reverse Osmosis Plants Producing Demineralized Water

Membrane fouling and cleaning were studied in three reverse osmosis (RO) plants. Feed water was secondary wastewater effluent, river water, and surface water. Membrane autopsies were used for fouling characterization. Fouling layer measurements included total organic carbon (TOC), adenosine triphosp...

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Main Authors: Florian Beyer, Judita Laurinonyte, Arie Zwijnenburg, Alfons J. M. Stams, Caroline M. Plugge
Format: Article
Language:English
Published: Wiley 2017-01-01
Series:Journal of Engineering
Online Access:http://dx.doi.org/10.1155/2017/6356751
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author Florian Beyer
Judita Laurinonyte
Arie Zwijnenburg
Alfons J. M. Stams
Caroline M. Plugge
author_facet Florian Beyer
Judita Laurinonyte
Arie Zwijnenburg
Alfons J. M. Stams
Caroline M. Plugge
author_sort Florian Beyer
collection DOAJ
description Membrane fouling and cleaning were studied in three reverse osmosis (RO) plants. Feed water was secondary wastewater effluent, river water, and surface water. Membrane autopsies were used for fouling characterization. Fouling layer measurements included total organic carbon (TOC), adenosine triphosphate, polysaccharides, proteins, and heterotrophic plate counts. In all locations, membrane and spacer fouling was (bio)organic. Plant chemical cleaning efficiencies were evaluated from full-scale operational data and cleaning trials in a laboratory setup. Standard cleaning procedures were compared to two cleaning procedures specifically adapted to treat (bio)organic fouling using commercial blend cleaners (mixtures of active substances). The three RO plants were impacted by irreversible foulants causing permanently decreased performance in normalized pressure drop and water permeability even after thorough chemical cleaning. The standard plant and adapted cleaning procedures reduced the TOC by 45% on average, with a maximum of ~80%. In general, around 20% higher biomass removal could be achieved with adapted procedure I compared to adapted procedure II. TOC measurements and SEM showed that none of cleaning procedures applied could remove foulants completely from the membrane elements. This study underlines the need for novel cleaning approaches targeting resistant foulants, as none of the procedures applied resulted in highly effective membrane regeneration.
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issn 2314-4904
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language English
publishDate 2017-01-01
publisher Wiley
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series Journal of Engineering
spelling doaj-art-b4342a945fd14f8b82abd272b503c4ca2025-02-03T05:51:26ZengWileyJournal of Engineering2314-49042314-49122017-01-01201710.1155/2017/63567516356751Membrane Fouling and Chemical Cleaning in Three Full-Scale Reverse Osmosis Plants Producing Demineralized WaterFlorian Beyer0Judita Laurinonyte1Arie Zwijnenburg2Alfons J. M. Stams3Caroline M. Plugge4Laboratory of Microbiology, Wageningen University, Stippeneng 4, 6708 WE Wageningen, NetherlandsWetsus, European Centre of Excellence for Sustainable Water Technology, Oostergoweg 9, 8911 MA Leeuwarden, NetherlandsWetsus, European Centre of Excellence for Sustainable Water Technology, Oostergoweg 9, 8911 MA Leeuwarden, NetherlandsLaboratory of Microbiology, Wageningen University, Stippeneng 4, 6708 WE Wageningen, NetherlandsLaboratory of Microbiology, Wageningen University, Stippeneng 4, 6708 WE Wageningen, NetherlandsMembrane fouling and cleaning were studied in three reverse osmosis (RO) plants. Feed water was secondary wastewater effluent, river water, and surface water. Membrane autopsies were used for fouling characterization. Fouling layer measurements included total organic carbon (TOC), adenosine triphosphate, polysaccharides, proteins, and heterotrophic plate counts. In all locations, membrane and spacer fouling was (bio)organic. Plant chemical cleaning efficiencies were evaluated from full-scale operational data and cleaning trials in a laboratory setup. Standard cleaning procedures were compared to two cleaning procedures specifically adapted to treat (bio)organic fouling using commercial blend cleaners (mixtures of active substances). The three RO plants were impacted by irreversible foulants causing permanently decreased performance in normalized pressure drop and water permeability even after thorough chemical cleaning. The standard plant and adapted cleaning procedures reduced the TOC by 45% on average, with a maximum of ~80%. In general, around 20% higher biomass removal could be achieved with adapted procedure I compared to adapted procedure II. TOC measurements and SEM showed that none of cleaning procedures applied could remove foulants completely from the membrane elements. This study underlines the need for novel cleaning approaches targeting resistant foulants, as none of the procedures applied resulted in highly effective membrane regeneration.http://dx.doi.org/10.1155/2017/6356751
spellingShingle Florian Beyer
Judita Laurinonyte
Arie Zwijnenburg
Alfons J. M. Stams
Caroline M. Plugge
Membrane Fouling and Chemical Cleaning in Three Full-Scale Reverse Osmosis Plants Producing Demineralized Water
Journal of Engineering
title Membrane Fouling and Chemical Cleaning in Three Full-Scale Reverse Osmosis Plants Producing Demineralized Water
title_full Membrane Fouling and Chemical Cleaning in Three Full-Scale Reverse Osmosis Plants Producing Demineralized Water
title_fullStr Membrane Fouling and Chemical Cleaning in Three Full-Scale Reverse Osmosis Plants Producing Demineralized Water
title_full_unstemmed Membrane Fouling and Chemical Cleaning in Three Full-Scale Reverse Osmosis Plants Producing Demineralized Water
title_short Membrane Fouling and Chemical Cleaning in Three Full-Scale Reverse Osmosis Plants Producing Demineralized Water
title_sort membrane fouling and chemical cleaning in three full scale reverse osmosis plants producing demineralized water
url http://dx.doi.org/10.1155/2017/6356751
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