Protection of Steel Rebar in Salt-Contaminated Cement Mortar Using Epoxy Nanocomposite Coatings

Epoxy reinforced with two kinds of nanoparticles dealing with nano-SiO2 and nano-Fe2O3 was coated on steel rebar embedded in a chloride contaminated cement mortar. NaCl was added to the fresh Portland cement paste (at 0.3% and 0.5% by weight of cement) to simulate the chloride contamination at the c...

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Main Authors: The Huu Nguyen, Tuan Anh Nguyen
Format: Article
Language:English
Published: Wiley 2018-01-01
Series:International Journal of Electrochemistry
Online Access:http://dx.doi.org/10.1155/2018/8386426
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author The Huu Nguyen
Tuan Anh Nguyen
author_facet The Huu Nguyen
Tuan Anh Nguyen
author_sort The Huu Nguyen
collection DOAJ
description Epoxy reinforced with two kinds of nanoparticles dealing with nano-SiO2 and nano-Fe2O3 was coated on steel rebar embedded in a chloride contaminated cement mortar. NaCl was added to the fresh Portland cement paste (at 0.3% and 0.5% by weight of cement) to simulate the chloride contamination at the critical level. The effect of incorporating nanoparticles on the corrosion resistance of epoxy-coated steel rebar was investigated by linear potentiodynamic polarization and electrochemical impedance spectroscopy. For the 0.3 wt.% chloride mortars, the electrochemical monitoring of the coated steel rebars during immersion for 56 days in 0.1 M NaOH solutions suggested the beneficial role of nano-Fe2O3 particles in significantly improving the corrosion resistance of the epoxy-coated rebar. After 56 days of immersion, the nano-Fe2O3 reduced the corrosion current of epoxy-coated rebar by a factor of 7.9. When the chloride concentration in the cement mortar was 0.5 wt.%, the incorporation of nanoparticles into the epoxy matrix did not enhance the corrosion resistance of epoxy coating for the rebar. At this critical level, chloride ions initiated rebar corrosion through nanoparticles at the epoxy/rebar interface.
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spelling doaj-art-b2e15499d66140aaaec5ea6df53d60822025-02-03T06:06:37ZengWileyInternational Journal of Electrochemistry2090-35292090-35372018-01-01201810.1155/2018/83864268386426Protection of Steel Rebar in Salt-Contaminated Cement Mortar Using Epoxy Nanocomposite CoatingsThe Huu Nguyen0Tuan Anh Nguyen1Faculty of Chemical Technology, Hanoi University of Industry, Bac Tu Liem, Hanoi, VietnamInstitute for Tropical Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, VietnamEpoxy reinforced with two kinds of nanoparticles dealing with nano-SiO2 and nano-Fe2O3 was coated on steel rebar embedded in a chloride contaminated cement mortar. NaCl was added to the fresh Portland cement paste (at 0.3% and 0.5% by weight of cement) to simulate the chloride contamination at the critical level. The effect of incorporating nanoparticles on the corrosion resistance of epoxy-coated steel rebar was investigated by linear potentiodynamic polarization and electrochemical impedance spectroscopy. For the 0.3 wt.% chloride mortars, the electrochemical monitoring of the coated steel rebars during immersion for 56 days in 0.1 M NaOH solutions suggested the beneficial role of nano-Fe2O3 particles in significantly improving the corrosion resistance of the epoxy-coated rebar. After 56 days of immersion, the nano-Fe2O3 reduced the corrosion current of epoxy-coated rebar by a factor of 7.9. When the chloride concentration in the cement mortar was 0.5 wt.%, the incorporation of nanoparticles into the epoxy matrix did not enhance the corrosion resistance of epoxy coating for the rebar. At this critical level, chloride ions initiated rebar corrosion through nanoparticles at the epoxy/rebar interface.http://dx.doi.org/10.1155/2018/8386426
spellingShingle The Huu Nguyen
Tuan Anh Nguyen
Protection of Steel Rebar in Salt-Contaminated Cement Mortar Using Epoxy Nanocomposite Coatings
International Journal of Electrochemistry
title Protection of Steel Rebar in Salt-Contaminated Cement Mortar Using Epoxy Nanocomposite Coatings
title_full Protection of Steel Rebar in Salt-Contaminated Cement Mortar Using Epoxy Nanocomposite Coatings
title_fullStr Protection of Steel Rebar in Salt-Contaminated Cement Mortar Using Epoxy Nanocomposite Coatings
title_full_unstemmed Protection of Steel Rebar in Salt-Contaminated Cement Mortar Using Epoxy Nanocomposite Coatings
title_short Protection of Steel Rebar in Salt-Contaminated Cement Mortar Using Epoxy Nanocomposite Coatings
title_sort protection of steel rebar in salt contaminated cement mortar using epoxy nanocomposite coatings
url http://dx.doi.org/10.1155/2018/8386426
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AT tuananhnguyen protectionofsteelrebarinsaltcontaminatedcementmortarusingepoxynanocompositecoatings