Ultrathin Anode Buffer Layer for Enhancing Performance of Polymer Solar Cells
A series of polymer solar cells (PSCs) based on poly[(4,8-bis-(2-ethylhexyloxy)-benzo[1,2-b:4,5-b′(dithiophene)-2,6-diyl-alt-(4-(2-ethylhexanoyl)-thieno[3,4-b]thiophene)-2,6-diyl] (PBDTTT-C) and [6,6]phenyl-C71-butyric acid methyl ester (PC71BM) were fabricated with various anode buffer layers. The...
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Format: | Article |
Language: | English |
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Wiley
2014-01-01
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Series: | International Journal of Photoenergy |
Online Access: | http://dx.doi.org/10.1155/2014/846581 |
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author | Dun Wang Jian Wang Ling-liang Li Qiao-shi An Hui Huang Chao-qun Jiao Yang Liu Fu-jun Zhang |
author_facet | Dun Wang Jian Wang Ling-liang Li Qiao-shi An Hui Huang Chao-qun Jiao Yang Liu Fu-jun Zhang |
author_sort | Dun Wang |
collection | DOAJ |
description | A series of polymer solar cells (PSCs) based on poly[(4,8-bis-(2-ethylhexyloxy)-benzo[1,2-b:4,5-b′(dithiophene)-2,6-diyl-alt-(4-(2-ethylhexanoyl)-thieno[3,4-b]thiophene)-2,6-diyl] (PBDTTT-C) and [6,6]phenyl-C71-butyric acid methyl ester (PC71BM) were fabricated with various anode buffer layers. The power conversion efficiency (PCE) of PSCs was improved to 4.91% for the cells with PEDOT:PSS/LiF (1 nm) as anode buffer layer, which corresponds to 26.2% efficiency improvement compared with the cells with PEDOT:PSS as anode buffer layer. The PSCs with PEDOT:PSS/LiF as anode buffer layer show a maximum short-circuit density (Jsc) of 13.70 mA/cm2, with open circuit voltage (Voc) of 0.73 V and fill factor (FF) of 49.1% under illumination 100 mW/cm2 AM 1.5 G simulated solar light. The dominant mechanism for the performance improvement of PSCs could be attributed to the increased charge carrier collection ability by anode buffer layers. |
format | Article |
id | doaj-art-b2cdbb87704f4b56b71fc1f45e1bb4f6 |
institution | Kabale University |
issn | 1110-662X 1687-529X |
language | English |
publishDate | 2014-01-01 |
publisher | Wiley |
record_format | Article |
series | International Journal of Photoenergy |
spelling | doaj-art-b2cdbb87704f4b56b71fc1f45e1bb4f62025-02-03T05:58:33ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2014-01-01201410.1155/2014/846581846581Ultrathin Anode Buffer Layer for Enhancing Performance of Polymer Solar CellsDun Wang0Jian Wang1Ling-liang Li2Qiao-shi An3Hui Huang4Chao-qun Jiao5Yang Liu6Fu-jun Zhang7Key Laboratory of Luminescence and Optical Information, Ministry of Education, Beijing Jiaotong University, Beijing 100044, ChinaKey Laboratory of Luminescence and Optical Information, Ministry of Education, Beijing Jiaotong University, Beijing 100044, ChinaKey Laboratory of Luminescence and Optical Information, Ministry of Education, Beijing Jiaotong University, Beijing 100044, ChinaKey Laboratory of Luminescence and Optical Information, Ministry of Education, Beijing Jiaotong University, Beijing 100044, ChinaSchool of Electrical Engineering, Beijing Jiaotong University, Beijing 100044, ChinaSchool of Electrical Engineering, Beijing Jiaotong University, Beijing 100044, ChinaKey Laboratory of Luminescence and Optical Information, Ministry of Education, Beijing Jiaotong University, Beijing 100044, ChinaKey Laboratory of Luminescence and Optical Information, Ministry of Education, Beijing Jiaotong University, Beijing 100044, ChinaA series of polymer solar cells (PSCs) based on poly[(4,8-bis-(2-ethylhexyloxy)-benzo[1,2-b:4,5-b′(dithiophene)-2,6-diyl-alt-(4-(2-ethylhexanoyl)-thieno[3,4-b]thiophene)-2,6-diyl] (PBDTTT-C) and [6,6]phenyl-C71-butyric acid methyl ester (PC71BM) were fabricated with various anode buffer layers. The power conversion efficiency (PCE) of PSCs was improved to 4.91% for the cells with PEDOT:PSS/LiF (1 nm) as anode buffer layer, which corresponds to 26.2% efficiency improvement compared with the cells with PEDOT:PSS as anode buffer layer. The PSCs with PEDOT:PSS/LiF as anode buffer layer show a maximum short-circuit density (Jsc) of 13.70 mA/cm2, with open circuit voltage (Voc) of 0.73 V and fill factor (FF) of 49.1% under illumination 100 mW/cm2 AM 1.5 G simulated solar light. The dominant mechanism for the performance improvement of PSCs could be attributed to the increased charge carrier collection ability by anode buffer layers.http://dx.doi.org/10.1155/2014/846581 |
spellingShingle | Dun Wang Jian Wang Ling-liang Li Qiao-shi An Hui Huang Chao-qun Jiao Yang Liu Fu-jun Zhang Ultrathin Anode Buffer Layer for Enhancing Performance of Polymer Solar Cells International Journal of Photoenergy |
title | Ultrathin Anode Buffer Layer for Enhancing Performance of Polymer Solar Cells |
title_full | Ultrathin Anode Buffer Layer for Enhancing Performance of Polymer Solar Cells |
title_fullStr | Ultrathin Anode Buffer Layer for Enhancing Performance of Polymer Solar Cells |
title_full_unstemmed | Ultrathin Anode Buffer Layer for Enhancing Performance of Polymer Solar Cells |
title_short | Ultrathin Anode Buffer Layer for Enhancing Performance of Polymer Solar Cells |
title_sort | ultrathin anode buffer layer for enhancing performance of polymer solar cells |
url | http://dx.doi.org/10.1155/2014/846581 |
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