Biochar as a waste management strategy for cadmium contaminated cocoa pod husk residues

Purpose The role of cocoa pod husk waste in soil cadmium contamination has been largely overlooked. Hence, this study aims to provide a strategy for the management of cocoa pod husk waste when representing a pollution menace for cocoa plantations.Method Cocoa pod husks waste was subjected to compost...

Full description

Saved in:
Bibliographic Details
Main Authors: Diego Armando Pinzon-Nuñez, Carlos Alberto Adarme-Duran, Luz Vargas-Fiallo, Nelson Rodriguez-Lopez, Carlos Alberto Rios-Reyes
Format: Article
Language:English
Published: OICC Press 2022-03-01
Series:International Journal of Recycling of Organic Waste in Agriculture
Subjects:
Online Access:http://ijrowa.khuisf.ac.ir/article_686239_48c5e2fdd1ea04ec0e297d8c47a10009.pdf
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832568727071096832
author Diego Armando Pinzon-Nuñez
Carlos Alberto Adarme-Duran
Luz Vargas-Fiallo
Nelson Rodriguez-Lopez
Carlos Alberto Rios-Reyes
author_facet Diego Armando Pinzon-Nuñez
Carlos Alberto Adarme-Duran
Luz Vargas-Fiallo
Nelson Rodriguez-Lopez
Carlos Alberto Rios-Reyes
author_sort Diego Armando Pinzon-Nuñez
collection DOAJ
description Purpose The role of cocoa pod husk waste in soil cadmium contamination has been largely overlooked. Hence, this study aims to provide a strategy for the management of cocoa pod husk waste when representing a pollution menace for cocoa plantations.Method Cocoa pod husks waste was subjected to composting and pyrolysis for decreasing the heavy metal content. Biochar and compost were characterized using SEM-EDS, and FTIR-ATR. Macro and micronutrients (Mg, K, Zn, Fe, Cu, Zn, Mn, and Na), and Cd were measured by atomic absorption spectroscopy (AAS). Sorption experiments and soil incubation experiments for two months were also carried out looking for an application of CPH materials in Cd sorption and remediation.Results Pyrolysis showed more effectiveness for Cd reduction in cocoa pod husk waste (90%) than composting (66%), 700 ℃ was the optimal temperature. Equilibrium isotherm experiments showed maximum Cd adsorption of 21.58 mg g-1 for Bc700 in solution. Biochar showed a small reduction of available Cd in naturally contaminated soil. Both materials have the potential to be used as organic fertilizer because of their high nutrient contents.Conclusion Biochar is an alternative to compost for the management of post-harvest cocoa wastes contaminated with Cd.
format Article
id doaj-art-b27772e106d747f3ae1947af7849bfca
institution Kabale University
issn 2195-3228
2251-7715
language English
publishDate 2022-03-01
publisher OICC Press
record_format Article
series International Journal of Recycling of Organic Waste in Agriculture
spelling doaj-art-b27772e106d747f3ae1947af7849bfca2025-02-03T00:39:24ZengOICC PressInternational Journal of Recycling of Organic Waste in Agriculture2195-32282251-77152022-03-0111110111510.30486/ijrowa.2021.1920124.1192686239Biochar as a waste management strategy for cadmium contaminated cocoa pod husk residuesDiego Armando Pinzon-Nuñez0Carlos Alberto Adarme-Duran1Luz Vargas-Fiallo2Nelson Rodriguez-Lopez3Carlos Alberto Rios-Reyes4School of Geology, Universidad Industrial de Santander, Bucaramanga, ColombiaSchool of Chemistry, Universidad Industrial de Santander, Bucaramanga, ColombiaSchool of Chemistry, Universidad Industrial de Santander, Bucaramanga, ColombiaSchool of Biology, Universidad Industrial de Santander, Bucaramanga, ColombiaSchool of Geology, Universidad Industrial de Santander, Bucaramanga, ColombiaPurpose The role of cocoa pod husk waste in soil cadmium contamination has been largely overlooked. Hence, this study aims to provide a strategy for the management of cocoa pod husk waste when representing a pollution menace for cocoa plantations.Method Cocoa pod husks waste was subjected to composting and pyrolysis for decreasing the heavy metal content. Biochar and compost were characterized using SEM-EDS, and FTIR-ATR. Macro and micronutrients (Mg, K, Zn, Fe, Cu, Zn, Mn, and Na), and Cd were measured by atomic absorption spectroscopy (AAS). Sorption experiments and soil incubation experiments for two months were also carried out looking for an application of CPH materials in Cd sorption and remediation.Results Pyrolysis showed more effectiveness for Cd reduction in cocoa pod husk waste (90%) than composting (66%), 700 ℃ was the optimal temperature. Equilibrium isotherm experiments showed maximum Cd adsorption of 21.58 mg g-1 for Bc700 in solution. Biochar showed a small reduction of available Cd in naturally contaminated soil. Both materials have the potential to be used as organic fertilizer because of their high nutrient contents.Conclusion Biochar is an alternative to compost for the management of post-harvest cocoa wastes contaminated with Cd.http://ijrowa.khuisf.ac.ir/article_686239_48c5e2fdd1ea04ec0e297d8c47a10009.pdfbiomass valorizationpyrolysiscompostingsoil pollution: sustainable agriculture
spellingShingle Diego Armando Pinzon-Nuñez
Carlos Alberto Adarme-Duran
Luz Vargas-Fiallo
Nelson Rodriguez-Lopez
Carlos Alberto Rios-Reyes
Biochar as a waste management strategy for cadmium contaminated cocoa pod husk residues
International Journal of Recycling of Organic Waste in Agriculture
biomass valorization
pyrolysis
composting
soil pollution: sustainable agriculture
title Biochar as a waste management strategy for cadmium contaminated cocoa pod husk residues
title_full Biochar as a waste management strategy for cadmium contaminated cocoa pod husk residues
title_fullStr Biochar as a waste management strategy for cadmium contaminated cocoa pod husk residues
title_full_unstemmed Biochar as a waste management strategy for cadmium contaminated cocoa pod husk residues
title_short Biochar as a waste management strategy for cadmium contaminated cocoa pod husk residues
title_sort biochar as a waste management strategy for cadmium contaminated cocoa pod husk residues
topic biomass valorization
pyrolysis
composting
soil pollution: sustainable agriculture
url http://ijrowa.khuisf.ac.ir/article_686239_48c5e2fdd1ea04ec0e297d8c47a10009.pdf
work_keys_str_mv AT diegoarmandopinzonnunez biocharasawastemanagementstrategyforcadmiumcontaminatedcocoapodhuskresidues
AT carlosalbertoadarmeduran biocharasawastemanagementstrategyforcadmiumcontaminatedcocoapodhuskresidues
AT luzvargasfiallo biocharasawastemanagementstrategyforcadmiumcontaminatedcocoapodhuskresidues
AT nelsonrodriguezlopez biocharasawastemanagementstrategyforcadmiumcontaminatedcocoapodhuskresidues
AT carlosalbertoriosreyes biocharasawastemanagementstrategyforcadmiumcontaminatedcocoapodhuskresidues