Controlled Morphology and Mechanical Characterisation of Electrospun Cellulose Acetate Fibre Webs
The purpose was to interpret the varying morphology of electrospun cellulose acetate (CA) fibres produced from single and binary solvent systems based on solubility parameters to identify processing conditions for the production of defect-free CA fibrous webs by electrospinning. The Hildebrand solub...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2013-01-01
|
| Series: | International Journal of Polymer Science |
| Online Access: | http://dx.doi.org/10.1155/2013/256161 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832545944524029952 |
|---|---|
| author | B. Ghorani S. J. Russell P. Goswami |
| author_facet | B. Ghorani S. J. Russell P. Goswami |
| author_sort | B. Ghorani |
| collection | DOAJ |
| description | The purpose was to interpret the varying morphology of electrospun cellulose acetate (CA) fibres produced from single and binary solvent systems based on solubility parameters to identify processing conditions for the production of defect-free CA fibrous webs by electrospinning. The Hildebrand solubility parameter () and the radius of the sphere in the Hansen space () of acetone, acetic acid, water, N,N-dimethylacetamide (DMAc), methanol, and chloroform were examined and discussed for the electrospinning of CA. The Hildebrand solubility parameter () of acetone and DMAc were found to be within an appropriate range for the dissolution of CA. The suitability of the binary solvent system of acetone: DMAc (2 : 1) for the continuous electrospinning of defect-free CA fibres was confirmed. Electrospun webs exhibited improved tensile strength and modulus after heat and alkali treatment (deacetylation) of the as-spun material, and no major fibre morphological degradation occurred during the deacetylation process. |
| format | Article |
| id | doaj-art-b129a68da3c54bac85aa38936c68f717 |
| institution | Kabale University |
| issn | 1687-9422 1687-9430 |
| language | English |
| publishDate | 2013-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Polymer Science |
| spelling | doaj-art-b129a68da3c54bac85aa38936c68f7172025-02-03T07:24:21ZengWileyInternational Journal of Polymer Science1687-94221687-94302013-01-01201310.1155/2013/256161256161Controlled Morphology and Mechanical Characterisation of Electrospun Cellulose Acetate Fibre WebsB. Ghorani0S. J. Russell1P. Goswami2Nonwovens Research Group, Centre for Technical Textiles, University of Leeds, Leeds LS2 9JT, UKNonwovens Research Group, Centre for Technical Textiles, University of Leeds, Leeds LS2 9JT, UKNonwovens Research Group, Centre for Technical Textiles, University of Leeds, Leeds LS2 9JT, UKThe purpose was to interpret the varying morphology of electrospun cellulose acetate (CA) fibres produced from single and binary solvent systems based on solubility parameters to identify processing conditions for the production of defect-free CA fibrous webs by electrospinning. The Hildebrand solubility parameter () and the radius of the sphere in the Hansen space () of acetone, acetic acid, water, N,N-dimethylacetamide (DMAc), methanol, and chloroform were examined and discussed for the electrospinning of CA. The Hildebrand solubility parameter () of acetone and DMAc were found to be within an appropriate range for the dissolution of CA. The suitability of the binary solvent system of acetone: DMAc (2 : 1) for the continuous electrospinning of defect-free CA fibres was confirmed. Electrospun webs exhibited improved tensile strength and modulus after heat and alkali treatment (deacetylation) of the as-spun material, and no major fibre morphological degradation occurred during the deacetylation process.http://dx.doi.org/10.1155/2013/256161 |
| spellingShingle | B. Ghorani S. J. Russell P. Goswami Controlled Morphology and Mechanical Characterisation of Electrospun Cellulose Acetate Fibre Webs International Journal of Polymer Science |
| title | Controlled Morphology and Mechanical Characterisation of Electrospun Cellulose Acetate Fibre Webs |
| title_full | Controlled Morphology and Mechanical Characterisation of Electrospun Cellulose Acetate Fibre Webs |
| title_fullStr | Controlled Morphology and Mechanical Characterisation of Electrospun Cellulose Acetate Fibre Webs |
| title_full_unstemmed | Controlled Morphology and Mechanical Characterisation of Electrospun Cellulose Acetate Fibre Webs |
| title_short | Controlled Morphology and Mechanical Characterisation of Electrospun Cellulose Acetate Fibre Webs |
| title_sort | controlled morphology and mechanical characterisation of electrospun cellulose acetate fibre webs |
| url | http://dx.doi.org/10.1155/2013/256161 |
| work_keys_str_mv | AT bghorani controlledmorphologyandmechanicalcharacterisationofelectrospuncelluloseacetatefibrewebs AT sjrussell controlledmorphologyandmechanicalcharacterisationofelectrospuncelluloseacetatefibrewebs AT pgoswami controlledmorphologyandmechanicalcharacterisationofelectrospuncelluloseacetatefibrewebs |