Marine Antifouling for Underwater Archaeological Sites: TiO2 and Ag-Doped TiO2

Marine fouling plays a crucial role in the degradation of underwater archaeological sites. Limitation of fouling activity and its damages are one of the most critical issues for archaeologists and conservators. The common cleaning procedure, consisting in the manual removal of fouling, requires a co...

Full description

Saved in:
Bibliographic Details
Main Authors: Silvestro A. Ruffolo, Andrea Macchia, Mauro F. La Russa, Lorenzo Mazza, Clara Urzì, Filomena De Leo, Marianna Barberio, Gino M. Crisci
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2013/251647
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Marine fouling plays a crucial role in the degradation of underwater archaeological sites. Limitation of fouling activity and its damages are one of the most critical issues for archaeologists and conservators. The common cleaning procedure, consisting in the manual removal of fouling, requires a continuous maintenance, while a proper inhibition of biological colonisation would provide a long-time protection against biofouling. On the other hand, the most used antifouling paints, especially for ship hulls, show considerable toxicity level. Since submerged archaeological sites are often included in environmental protected areas, more eco-friendly products must be used. We have explored the possibility to use titanium dioxide and Ag-doped titanium dioxide as antifouling agents. For this purpose, they have been synthetized by sol-gel method, and then XRD, XPS, and reflectance spectroscopy measurements have been carried out to gain structural information. The powders have been dispersed in a polymer and then applied to marble surface to evaluate the chromatic alteration induced by the treatments. By means of biological tests, it was possible to assess their behaviour as biofouling agents. Results show a decreasing of biofouling activity on treated stony surfaces.
ISSN:1110-662X
1687-529X