Synthesis, Magnetization, and Electrical Transport Properties of Mn3Zn0.9Cu0.1N

We synthesized Mn3Zn0.9Cu0.1N by solid state reaction, and magnetic as well as electrical transport properties were investigated. It is found that Mn3Zn0.9Cu0.1N exhibits a first-order antiferromagnetism (AFM) to paramagnetic (PM) transition with the Néel temperature TN ~163 K, and substitution of C...

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Main Authors: Y. Yin, J. C. Han, T. P. Ying, J. K. Jian, Z. H. Zhang, L. S. Ling, L. Pi, B. Song
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Advances in Condensed Matter Physics
Online Access:http://dx.doi.org/10.1155/2013/863963
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author Y. Yin
J. C. Han
T. P. Ying
J. K. Jian
Z. H. Zhang
L. S. Ling
L. Pi
B. Song
author_facet Y. Yin
J. C. Han
T. P. Ying
J. K. Jian
Z. H. Zhang
L. S. Ling
L. Pi
B. Song
author_sort Y. Yin
collection DOAJ
description We synthesized Mn3Zn0.9Cu0.1N by solid state reaction, and magnetic as well as electrical transport properties were investigated. It is found that Mn3Zn0.9Cu0.1N exhibits a first-order antiferromagnetism (AFM) to paramagnetic (PM) transition with the Néel temperature TN ~163 K, and substitution of Cu for Zn would favor ferromagnetism (FM) state and weaken AFM ground state, leading to a convex curvature character of M(T) curve. With high external fields 10 kOe–50 kOe, magnetic transition remains a robust AFM-PM feature while FM phase is completely suppressed. Thermal hysteresis of M(T) under 500 Oe is also suppressed when the magnetic field exceeds 10 kOe. Mn3Zn0.9Cu0.1N exhibits a good metallic behavior except for a slope change around TN, which is closely related to AFM-PM magnetic transition. Compared with the first differential of resistivity with respect to temperature for (dρ/dT)Mn3ZnN in transition temperature range, the absolute value of (dρ/dT)Mn3Zn0.9Cu0.1N is much lower which is close to zero.
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institution Kabale University
issn 1687-8108
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language English
publishDate 2013-01-01
publisher Wiley
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series Advances in Condensed Matter Physics
spelling doaj-art-aea5ae80ed834139be5a56e0051eec5c2025-02-03T01:09:41ZengWileyAdvances in Condensed Matter Physics1687-81081687-81242013-01-01201310.1155/2013/863963863963Synthesis, Magnetization, and Electrical Transport Properties of Mn3Zn0.9Cu0.1NY. Yin0J. C. Han1T. P. Ying2J. K. Jian3Z. H. Zhang4L. S. Ling5L. Pi6B. Song7Center for Composite Materials, Harbin Institute of Technology, Harbin, Heilongjiang 150080, ChinaCenter for Composite Materials, Harbin Institute of Technology, Harbin, Heilongjiang 150080, ChinaResearch & Development Center for Functional Crystals, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, P.O. Box 603, Beijing 100190, ChinaDepartment of Physics, Xinjiang University, Urumchi 830046, ChinaLiaoning Key Materials Laboratory for Railway, School of Materials Science and Engineering, Dalian Jiaotong University, Dalian, Liaoning 116028, ChinaLaboratory of High Magnetic Field, Chinese Academy of Sciences, Hefei, Anhu 230031, ChinaLaboratory of High Magnetic Field, Chinese Academy of Sciences, Hefei, Anhu 230031, ChinaAcademy of Fundamental and Interdisciplinary Sciences, Harbin Institute of Technology, Harbin, Heilongjiang 150080, ChinaWe synthesized Mn3Zn0.9Cu0.1N by solid state reaction, and magnetic as well as electrical transport properties were investigated. It is found that Mn3Zn0.9Cu0.1N exhibits a first-order antiferromagnetism (AFM) to paramagnetic (PM) transition with the Néel temperature TN ~163 K, and substitution of Cu for Zn would favor ferromagnetism (FM) state and weaken AFM ground state, leading to a convex curvature character of M(T) curve. With high external fields 10 kOe–50 kOe, magnetic transition remains a robust AFM-PM feature while FM phase is completely suppressed. Thermal hysteresis of M(T) under 500 Oe is also suppressed when the magnetic field exceeds 10 kOe. Mn3Zn0.9Cu0.1N exhibits a good metallic behavior except for a slope change around TN, which is closely related to AFM-PM magnetic transition. Compared with the first differential of resistivity with respect to temperature for (dρ/dT)Mn3ZnN in transition temperature range, the absolute value of (dρ/dT)Mn3Zn0.9Cu0.1N is much lower which is close to zero.http://dx.doi.org/10.1155/2013/863963
spellingShingle Y. Yin
J. C. Han
T. P. Ying
J. K. Jian
Z. H. Zhang
L. S. Ling
L. Pi
B. Song
Synthesis, Magnetization, and Electrical Transport Properties of Mn3Zn0.9Cu0.1N
Advances in Condensed Matter Physics
title Synthesis, Magnetization, and Electrical Transport Properties of Mn3Zn0.9Cu0.1N
title_full Synthesis, Magnetization, and Electrical Transport Properties of Mn3Zn0.9Cu0.1N
title_fullStr Synthesis, Magnetization, and Electrical Transport Properties of Mn3Zn0.9Cu0.1N
title_full_unstemmed Synthesis, Magnetization, and Electrical Transport Properties of Mn3Zn0.9Cu0.1N
title_short Synthesis, Magnetization, and Electrical Transport Properties of Mn3Zn0.9Cu0.1N
title_sort synthesis magnetization and electrical transport properties of mn3zn0 9cu0 1n
url http://dx.doi.org/10.1155/2013/863963
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