Synthesis of Ruthenium Complex Based on 2,6-Bis(1-(phenyl)-1H-benzo[d]imidazol-2-yl)pyridine and 2-(1-Phenyl-1H-benzo[d]imidazol-2-yl)benzoate and Catalytical Oxidation Property of 1-(1H-Benzo[d]imidazol-2-yl)ethanol to 1-(1H-Benzo[d]imidazol-2-yl)ethanone with H2O2
A new ruthenium complex, Ru(bpbp)(pbb)Cl, based on 2,6-bis(1-(phenyl)-1H-benzo[d]imidazol-2-yl)pyridine (bpbp) and 2-(1-phenyl-1H-benzo[d]imidazol-2-yl)benzoate (pbb) was synthesized. The complex Ru(bpbp)(pbb)Cl could catalytically oxidize 1-(1H-benzo[d]imidazol-2-yl)ethanol to 1-(1H-benzo[d]imidazo...
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| Language: | English |
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Wiley
2017-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2017/8647419 |
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| author | Shenggui Liu Rongkai Pan Guobi Li Wenyi Su Chunlin Ni |
| author_facet | Shenggui Liu Rongkai Pan Guobi Li Wenyi Su Chunlin Ni |
| author_sort | Shenggui Liu |
| collection | DOAJ |
| description | A new ruthenium complex, Ru(bpbp)(pbb)Cl, based on 2,6-bis(1-(phenyl)-1H-benzo[d]imidazol-2-yl)pyridine (bpbp) and 2-(1-phenyl-1H-benzo[d]imidazol-2-yl)benzoate (pbb) was synthesized. The complex Ru(bpbp)(pbb)Cl could catalytically oxidize 1-(1H-benzo[d]imidazol-2-yl)ethanol to 1-(1H-benzo[d]imidazol-2-yl)ethanone with H2O2 as oxidant. Influence of temperature and catalyst amount on the oxidation reaction was evaluated. The reaction optimal conditions are as follows: molar ratio of catalyst to substrate to H2O2 is 1 : 1000 : 3000, the proper reaction temperature is 50°C and reaction time lasts 5 h, and the isolated yield of 1-(1H-benzo[d]imidazol-2-yl)ethanol to 1-(1H-benzo[d]imidazol-2-yl)ethanone under the optimal reaction conditions is 57%. |
| format | Article |
| id | doaj-art-ad23c6c5edca41be8755cd683fdaff06 |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2017-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-ad23c6c5edca41be8755cd683fdaff062025-02-03T00:59:32ZengWileyJournal of Chemistry2090-90632090-90712017-01-01201710.1155/2017/86474198647419Synthesis of Ruthenium Complex Based on 2,6-Bis(1-(phenyl)-1H-benzo[d]imidazol-2-yl)pyridine and 2-(1-Phenyl-1H-benzo[d]imidazol-2-yl)benzoate and Catalytical Oxidation Property of 1-(1H-Benzo[d]imidazol-2-yl)ethanol to 1-(1H-Benzo[d]imidazol-2-yl)ethanone with H2O2Shenggui Liu0Rongkai Pan1Guobi Li2Wenyi Su3Chunlin Ni4School of Chemistry & Chemical Engineering, Lingnan Normal University, Zhanjiang 524048, ChinaSchool of Chemistry & Chemical Engineering, Lingnan Normal University, Zhanjiang 524048, ChinaSchool of Chemistry & Chemical Engineering, Lingnan Normal University, Zhanjiang 524048, ChinaSchool of Chemistry & Chemical Engineering, Lingnan Normal University, Zhanjiang 524048, ChinaCollege of Materials and Energy, South China Agricultural University, Guangzhou 510642, ChinaA new ruthenium complex, Ru(bpbp)(pbb)Cl, based on 2,6-bis(1-(phenyl)-1H-benzo[d]imidazol-2-yl)pyridine (bpbp) and 2-(1-phenyl-1H-benzo[d]imidazol-2-yl)benzoate (pbb) was synthesized. The complex Ru(bpbp)(pbb)Cl could catalytically oxidize 1-(1H-benzo[d]imidazol-2-yl)ethanol to 1-(1H-benzo[d]imidazol-2-yl)ethanone with H2O2 as oxidant. Influence of temperature and catalyst amount on the oxidation reaction was evaluated. The reaction optimal conditions are as follows: molar ratio of catalyst to substrate to H2O2 is 1 : 1000 : 3000, the proper reaction temperature is 50°C and reaction time lasts 5 h, and the isolated yield of 1-(1H-benzo[d]imidazol-2-yl)ethanol to 1-(1H-benzo[d]imidazol-2-yl)ethanone under the optimal reaction conditions is 57%.http://dx.doi.org/10.1155/2017/8647419 |
| spellingShingle | Shenggui Liu Rongkai Pan Guobi Li Wenyi Su Chunlin Ni Synthesis of Ruthenium Complex Based on 2,6-Bis(1-(phenyl)-1H-benzo[d]imidazol-2-yl)pyridine and 2-(1-Phenyl-1H-benzo[d]imidazol-2-yl)benzoate and Catalytical Oxidation Property of 1-(1H-Benzo[d]imidazol-2-yl)ethanol to 1-(1H-Benzo[d]imidazol-2-yl)ethanone with H2O2 Journal of Chemistry |
| title | Synthesis of Ruthenium Complex Based on 2,6-Bis(1-(phenyl)-1H-benzo[d]imidazol-2-yl)pyridine and 2-(1-Phenyl-1H-benzo[d]imidazol-2-yl)benzoate and Catalytical Oxidation Property of 1-(1H-Benzo[d]imidazol-2-yl)ethanol to 1-(1H-Benzo[d]imidazol-2-yl)ethanone with H2O2 |
| title_full | Synthesis of Ruthenium Complex Based on 2,6-Bis(1-(phenyl)-1H-benzo[d]imidazol-2-yl)pyridine and 2-(1-Phenyl-1H-benzo[d]imidazol-2-yl)benzoate and Catalytical Oxidation Property of 1-(1H-Benzo[d]imidazol-2-yl)ethanol to 1-(1H-Benzo[d]imidazol-2-yl)ethanone with H2O2 |
| title_fullStr | Synthesis of Ruthenium Complex Based on 2,6-Bis(1-(phenyl)-1H-benzo[d]imidazol-2-yl)pyridine and 2-(1-Phenyl-1H-benzo[d]imidazol-2-yl)benzoate and Catalytical Oxidation Property of 1-(1H-Benzo[d]imidazol-2-yl)ethanol to 1-(1H-Benzo[d]imidazol-2-yl)ethanone with H2O2 |
| title_full_unstemmed | Synthesis of Ruthenium Complex Based on 2,6-Bis(1-(phenyl)-1H-benzo[d]imidazol-2-yl)pyridine and 2-(1-Phenyl-1H-benzo[d]imidazol-2-yl)benzoate and Catalytical Oxidation Property of 1-(1H-Benzo[d]imidazol-2-yl)ethanol to 1-(1H-Benzo[d]imidazol-2-yl)ethanone with H2O2 |
| title_short | Synthesis of Ruthenium Complex Based on 2,6-Bis(1-(phenyl)-1H-benzo[d]imidazol-2-yl)pyridine and 2-(1-Phenyl-1H-benzo[d]imidazol-2-yl)benzoate and Catalytical Oxidation Property of 1-(1H-Benzo[d]imidazol-2-yl)ethanol to 1-(1H-Benzo[d]imidazol-2-yl)ethanone with H2O2 |
| title_sort | synthesis of ruthenium complex based on 2 6 bis 1 phenyl 1h benzo d imidazol 2 yl pyridine and 2 1 phenyl 1h benzo d imidazol 2 yl benzoate and catalytical oxidation property of 1 1h benzo d imidazol 2 yl ethanol to 1 1h benzo d imidazol 2 yl ethanone with h2o2 |
| url | http://dx.doi.org/10.1155/2017/8647419 |
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