Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids

Reactions of dichlorobis(cyclopentadienyl)zirconium(IV) with pyridinedicarboxylic acids viz. quinolinic acids (QAH2), 2,4-pyridine dicarboxylic acid (PAH2), isocinchomeronic acid (IAH2), cinchomeronic acid (CAH2) and dinicotinic acid (DAH2) were carried out in different stoichiometric ratios. Comple...

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Main Authors: Satish C. Dixit, Rohit K. Singh
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2012/631391
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author Satish C. Dixit
Rohit K. Singh
author_facet Satish C. Dixit
Rohit K. Singh
author_sort Satish C. Dixit
collection DOAJ
description Reactions of dichlorobis(cyclopentadienyl)zirconium(IV) with pyridinedicarboxylic acids viz. quinolinic acids (QAH2), 2,4-pyridine dicarboxylic acid (PAH2), isocinchomeronic acid (IAH2), cinchomeronic acid (CAH2) and dinicotinic acid (DAH2) were carried out in different stoichiometric ratios. Complexes of the type Cp2Zr(QAH)Cl, Cp2Zr(QAH)2, Cp2Zr(PAH)Cl, Cp2Zr(PAH)2, Cp2Zr(IAH)Cl, Cp2Zr(IAH)2, Cp2Zr(CAH)Cl, Cp2Zr(CAH)2, Cp2Zr(DAH)Cl and Cp2Zr(DAH)2 were obtained. These new complexes were characterized on the basis of their elemental analyses, electrical conductance, magnetic moment and spectral data.
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series E-Journal of Chemistry
spelling doaj-art-ab39797e0b364e50807bdbc2263898b12025-02-03T05:44:04ZengWileyE-Journal of Chemistry0973-49452090-98102012-01-019274474810.1155/2012/631391Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic AcidsSatish C. Dixit0Rohit K. Singh1Deptt. of Chemistry, D.B.S. College, Kanpur-208006, IndiaDeptt. of Chemistry, Pt. J.L.N. College, Banda (U.P.), IndiaReactions of dichlorobis(cyclopentadienyl)zirconium(IV) with pyridinedicarboxylic acids viz. quinolinic acids (QAH2), 2,4-pyridine dicarboxylic acid (PAH2), isocinchomeronic acid (IAH2), cinchomeronic acid (CAH2) and dinicotinic acid (DAH2) were carried out in different stoichiometric ratios. Complexes of the type Cp2Zr(QAH)Cl, Cp2Zr(QAH)2, Cp2Zr(PAH)Cl, Cp2Zr(PAH)2, Cp2Zr(IAH)Cl, Cp2Zr(IAH)2, Cp2Zr(CAH)Cl, Cp2Zr(CAH)2, Cp2Zr(DAH)Cl and Cp2Zr(DAH)2 were obtained. These new complexes were characterized on the basis of their elemental analyses, electrical conductance, magnetic moment and spectral data.http://dx.doi.org/10.1155/2012/631391
spellingShingle Satish C. Dixit
Rohit K. Singh
Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids
E-Journal of Chemistry
title Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids
title_full Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids
title_fullStr Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids
title_full_unstemmed Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids
title_short Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids
title_sort some new derivatives of organozirconium iv with pyridinedicarboxylic acids
url http://dx.doi.org/10.1155/2012/631391
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