Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids
Reactions of dichlorobis(cyclopentadienyl)zirconium(IV) with pyridinedicarboxylic acids viz. quinolinic acids (QAH2), 2,4-pyridine dicarboxylic acid (PAH2), isocinchomeronic acid (IAH2), cinchomeronic acid (CAH2) and dinicotinic acid (DAH2) were carried out in different stoichiometric ratios. Comple...
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Language: | English |
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Wiley
2012-01-01
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Series: | E-Journal of Chemistry |
Online Access: | http://dx.doi.org/10.1155/2012/631391 |
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author | Satish C. Dixit Rohit K. Singh |
author_facet | Satish C. Dixit Rohit K. Singh |
author_sort | Satish C. Dixit |
collection | DOAJ |
description | Reactions of dichlorobis(cyclopentadienyl)zirconium(IV) with pyridinedicarboxylic acids viz. quinolinic acids (QAH2), 2,4-pyridine dicarboxylic acid (PAH2), isocinchomeronic acid (IAH2), cinchomeronic acid (CAH2) and dinicotinic acid (DAH2) were carried out in different stoichiometric ratios. Complexes of the type Cp2Zr(QAH)Cl, Cp2Zr(QAH)2, Cp2Zr(PAH)Cl, Cp2Zr(PAH)2, Cp2Zr(IAH)Cl, Cp2Zr(IAH)2, Cp2Zr(CAH)Cl, Cp2Zr(CAH)2, Cp2Zr(DAH)Cl and Cp2Zr(DAH)2 were obtained. These new complexes were characterized on the basis of their elemental analyses, electrical conductance, magnetic moment and spectral data. |
format | Article |
id | doaj-art-ab39797e0b364e50807bdbc2263898b1 |
institution | Kabale University |
issn | 0973-4945 2090-9810 |
language | English |
publishDate | 2012-01-01 |
publisher | Wiley |
record_format | Article |
series | E-Journal of Chemistry |
spelling | doaj-art-ab39797e0b364e50807bdbc2263898b12025-02-03T05:44:04ZengWileyE-Journal of Chemistry0973-49452090-98102012-01-019274474810.1155/2012/631391Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic AcidsSatish C. Dixit0Rohit K. Singh1Deptt. of Chemistry, D.B.S. College, Kanpur-208006, IndiaDeptt. of Chemistry, Pt. J.L.N. College, Banda (U.P.), IndiaReactions of dichlorobis(cyclopentadienyl)zirconium(IV) with pyridinedicarboxylic acids viz. quinolinic acids (QAH2), 2,4-pyridine dicarboxylic acid (PAH2), isocinchomeronic acid (IAH2), cinchomeronic acid (CAH2) and dinicotinic acid (DAH2) were carried out in different stoichiometric ratios. Complexes of the type Cp2Zr(QAH)Cl, Cp2Zr(QAH)2, Cp2Zr(PAH)Cl, Cp2Zr(PAH)2, Cp2Zr(IAH)Cl, Cp2Zr(IAH)2, Cp2Zr(CAH)Cl, Cp2Zr(CAH)2, Cp2Zr(DAH)Cl and Cp2Zr(DAH)2 were obtained. These new complexes were characterized on the basis of their elemental analyses, electrical conductance, magnetic moment and spectral data.http://dx.doi.org/10.1155/2012/631391 |
spellingShingle | Satish C. Dixit Rohit K. Singh Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids E-Journal of Chemistry |
title | Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids |
title_full | Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids |
title_fullStr | Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids |
title_full_unstemmed | Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids |
title_short | Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids |
title_sort | some new derivatives of organozirconium iv with pyridinedicarboxylic acids |
url | http://dx.doi.org/10.1155/2012/631391 |
work_keys_str_mv | AT satishcdixit somenewderivativesoforganozirconiumivwithpyridinedicarboxylicacids AT rohitksingh somenewderivativesoforganozirconiumivwithpyridinedicarboxylicacids |