Adsorptive Removal of Cd(II) Ions from Wastewater Using Maleic Anhydride Nanocellulose
In this study, both pristine cellulose nanocrystalline (CNC) and maleic anhydride functionalized cellulose nanocrystalline (MA-CNC) were prepared from the stems of Eichhornia crassipes weed by the sulfuric acid hydrolysis method. The as-prepared adsorbents were characterized by using X-ray diffracti...
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Wiley
2021-01-01
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Series: | Journal of Nanotechnology |
Online Access: | http://dx.doi.org/10.1155/2021/9966811 |
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author | Hizkeal Tsade Kara Sisay Tadesse Anshebo Fedlu Kedir Sabir |
author_facet | Hizkeal Tsade Kara Sisay Tadesse Anshebo Fedlu Kedir Sabir |
author_sort | Hizkeal Tsade Kara |
collection | DOAJ |
description | In this study, both pristine cellulose nanocrystalline (CNC) and maleic anhydride functionalized cellulose nanocrystalline (MA-CNC) were prepared from the stems of Eichhornia crassipes weed by the sulfuric acid hydrolysis method. The as-prepared adsorbents were characterized by using X-ray diffraction (XRD), Fourier-transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), energy-dispersive X-ray (EDX), and Brunauer–Emmett–Teller (BET) instruments. These materials were applied for the removal of Cd(II) ions from WW. The uptake mechanism was fixed to both Langmuir and Freundlich adsorption isotherms with a maximum Cd(II) ion uptake capability (qmax) of 75.76 and 215.52 mg g−1 by CNC and MA-CNC adsorbents, respectively. Pseudo-second-order (PSO) kinetic model was well fitted to the uptake process. The adsorbent regeneration study was done after desorption of Cd(II) ions from the adsorbent by HCl washing. Results exhibited that the adsorbent was reused for the removal of Cd(II) ions from real WW after successive 13th cycle. |
format | Article |
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institution | Kabale University |
issn | 1687-9503 1687-9511 |
language | English |
publishDate | 2021-01-01 |
publisher | Wiley |
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series | Journal of Nanotechnology |
spelling | doaj-art-a8c41d256c18493abb7e78b801b785c92025-02-03T01:13:07ZengWileyJournal of Nanotechnology1687-95031687-95112021-01-01202110.1155/2021/99668119966811Adsorptive Removal of Cd(II) Ions from Wastewater Using Maleic Anhydride NanocelluloseHizkeal Tsade Kara0Sisay Tadesse Anshebo1Fedlu Kedir Sabir2Department of Applied Chemistry, School of Applied Natural Science, Adama Science and Technology University, P.O.Box 1888, Adama, EthiopiaDepartment of Chemistry, College of Natural and Computational Science, Hawassa University, P.O. Box 05, Hawassa, EthiopiaDepartment of Applied Chemistry, School of Applied Natural Science, Adama Science and Technology University, P.O.Box 1888, Adama, EthiopiaIn this study, both pristine cellulose nanocrystalline (CNC) and maleic anhydride functionalized cellulose nanocrystalline (MA-CNC) were prepared from the stems of Eichhornia crassipes weed by the sulfuric acid hydrolysis method. The as-prepared adsorbents were characterized by using X-ray diffraction (XRD), Fourier-transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), energy-dispersive X-ray (EDX), and Brunauer–Emmett–Teller (BET) instruments. These materials were applied for the removal of Cd(II) ions from WW. The uptake mechanism was fixed to both Langmuir and Freundlich adsorption isotherms with a maximum Cd(II) ion uptake capability (qmax) of 75.76 and 215.52 mg g−1 by CNC and MA-CNC adsorbents, respectively. Pseudo-second-order (PSO) kinetic model was well fitted to the uptake process. The adsorbent regeneration study was done after desorption of Cd(II) ions from the adsorbent by HCl washing. Results exhibited that the adsorbent was reused for the removal of Cd(II) ions from real WW after successive 13th cycle.http://dx.doi.org/10.1155/2021/9966811 |
spellingShingle | Hizkeal Tsade Kara Sisay Tadesse Anshebo Fedlu Kedir Sabir Adsorptive Removal of Cd(II) Ions from Wastewater Using Maleic Anhydride Nanocellulose Journal of Nanotechnology |
title | Adsorptive Removal of Cd(II) Ions from Wastewater Using Maleic Anhydride Nanocellulose |
title_full | Adsorptive Removal of Cd(II) Ions from Wastewater Using Maleic Anhydride Nanocellulose |
title_fullStr | Adsorptive Removal of Cd(II) Ions from Wastewater Using Maleic Anhydride Nanocellulose |
title_full_unstemmed | Adsorptive Removal of Cd(II) Ions from Wastewater Using Maleic Anhydride Nanocellulose |
title_short | Adsorptive Removal of Cd(II) Ions from Wastewater Using Maleic Anhydride Nanocellulose |
title_sort | adsorptive removal of cd ii ions from wastewater using maleic anhydride nanocellulose |
url | http://dx.doi.org/10.1155/2021/9966811 |
work_keys_str_mv | AT hizkealtsadekara adsorptiveremovalofcdiiionsfromwastewaterusingmaleicanhydridenanocellulose AT sisaytadesseanshebo adsorptiveremovalofcdiiionsfromwastewaterusingmaleicanhydridenanocellulose AT fedlukedirsabir adsorptiveremovalofcdiiionsfromwastewaterusingmaleicanhydridenanocellulose |