Mechanochemical Halogenations and Rearrangement of Sydnones: Insight into Reaction Conditions and Mechanism

Mechanochemical Halogenations and Rearrangement of Sydnones: Insight into Reaction Conditions and Mechanism

Abstract New mechanochemical methods for sydnone halogenation and insights into an efficient ring rearrangement yielding 1,3,4‐oxadiazolin‐2‐ones by heated ball‐milling are reported herein. Using equimolar amounts of N‐chlorosuccinimide (NCS), oxone and sodium chloride, 3‐phenylsydnone was quantitat...

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Bibliographic Details
Main Authors: Dr. Florian Luttringer, Dr. Nicolas Pétry, Dr. Eric Clot, Prof. Dr. Xavier Bantreil, Dr. Frédéric Lamaty
Format: Article
Language:English
Published: Wiley-VCH 2025-01-01
Series:ChemistryEurope
Subjects:
sydnones
mechanochemistry
ball-milling
rearrangement
DFT calculations
Online Access:https://doi.org/10.1002/ceur.202400054
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