Effect of Nickel Content on the Corrosion Resistance of Iron-Nickel Alloys in Concentrated Hydrochloric Acid Pickling Solutions
The effect of Ni content on the resistance against corrosion of Fe-36% Ni and Fe-45% Ni alloys in 1 M hydrochloric acid pickling solution was reported. Various electrochemical and spectroscopic techniques such as potentiodynamic cyclic polarization (CPP), open-circuit potential (OCP), electrochemica...
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Wiley
2017-01-01
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Series: | Advances in Materials Science and Engineering |
Online Access: | http://dx.doi.org/10.1155/2017/1893672 |
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author | Nabeel Alharthi El-Sayed M. Sherif Hany S. Abdo S. Zein El Abedin |
author_facet | Nabeel Alharthi El-Sayed M. Sherif Hany S. Abdo S. Zein El Abedin |
author_sort | Nabeel Alharthi |
collection | DOAJ |
description | The effect of Ni content on the resistance against corrosion of Fe-36% Ni and Fe-45% Ni alloys in 1 M hydrochloric acid pickling solution was reported. Various electrochemical and spectroscopic techniques such as potentiodynamic cyclic polarization (CPP), open-circuit potential (OCP), electrochemical impedance spectroscopy (EIS), potentiostatic current-time (PCT), and scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS) have been employed. CPP measurements indicated that the corrosion current and corrosion rate recorded lower values for the alloy that had higher nickel content. OCP curves proved that the presence of high Ni content shifts the absolute potential to the positive potential direction. EIS results revealed that the surface and polarization resistances were much higher for the alloy with higher Ni content. PCT curves also showed that the absolute currents were lower for Fe-45% Ni alloy. All results were in good agreement with others and confirmed clearly that the corrosion resistance in HCl solutions for Fe-45% Ni alloy was higher than that obtained for Fe-45% Ni alloy. |
format | Article |
id | doaj-art-a701613fbac14d41acd52ce8b44c8a5a |
institution | Kabale University |
issn | 1687-8434 1687-8442 |
language | English |
publishDate | 2017-01-01 |
publisher | Wiley |
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series | Advances in Materials Science and Engineering |
spelling | doaj-art-a701613fbac14d41acd52ce8b44c8a5a2025-02-03T01:09:03ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422017-01-01201710.1155/2017/18936721893672Effect of Nickel Content on the Corrosion Resistance of Iron-Nickel Alloys in Concentrated Hydrochloric Acid Pickling SolutionsNabeel Alharthi0El-Sayed M. Sherif1Hany S. Abdo2S. Zein El Abedin3Center of Excellence for Research in Engineering Materials (CEREM), Advanced Manufacturing Institute (AMI), King Saud University, P.O. Box 800, Al-Riyadh 11421, Saudi ArabiaCenter of Excellence for Research in Engineering Materials (CEREM), Advanced Manufacturing Institute (AMI), King Saud University, P.O. Box 800, Al-Riyadh 11421, Saudi ArabiaCenter of Excellence for Research in Engineering Materials (CEREM), Advanced Manufacturing Institute (AMI), King Saud University, P.O. Box 800, Al-Riyadh 11421, Saudi ArabiaElectrochemistry and Corrosion Laboratory, Department of Physical Chemistry, National Research Centre, El-Behoth St. 33, Dokki, Cairo 12622, EgyptThe effect of Ni content on the resistance against corrosion of Fe-36% Ni and Fe-45% Ni alloys in 1 M hydrochloric acid pickling solution was reported. Various electrochemical and spectroscopic techniques such as potentiodynamic cyclic polarization (CPP), open-circuit potential (OCP), electrochemical impedance spectroscopy (EIS), potentiostatic current-time (PCT), and scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS) have been employed. CPP measurements indicated that the corrosion current and corrosion rate recorded lower values for the alloy that had higher nickel content. OCP curves proved that the presence of high Ni content shifts the absolute potential to the positive potential direction. EIS results revealed that the surface and polarization resistances were much higher for the alloy with higher Ni content. PCT curves also showed that the absolute currents were lower for Fe-45% Ni alloy. All results were in good agreement with others and confirmed clearly that the corrosion resistance in HCl solutions for Fe-45% Ni alloy was higher than that obtained for Fe-45% Ni alloy.http://dx.doi.org/10.1155/2017/1893672 |
spellingShingle | Nabeel Alharthi El-Sayed M. Sherif Hany S. Abdo S. Zein El Abedin Effect of Nickel Content on the Corrosion Resistance of Iron-Nickel Alloys in Concentrated Hydrochloric Acid Pickling Solutions Advances in Materials Science and Engineering |
title | Effect of Nickel Content on the Corrosion Resistance of Iron-Nickel Alloys in Concentrated Hydrochloric Acid Pickling Solutions |
title_full | Effect of Nickel Content on the Corrosion Resistance of Iron-Nickel Alloys in Concentrated Hydrochloric Acid Pickling Solutions |
title_fullStr | Effect of Nickel Content on the Corrosion Resistance of Iron-Nickel Alloys in Concentrated Hydrochloric Acid Pickling Solutions |
title_full_unstemmed | Effect of Nickel Content on the Corrosion Resistance of Iron-Nickel Alloys in Concentrated Hydrochloric Acid Pickling Solutions |
title_short | Effect of Nickel Content on the Corrosion Resistance of Iron-Nickel Alloys in Concentrated Hydrochloric Acid Pickling Solutions |
title_sort | effect of nickel content on the corrosion resistance of iron nickel alloys in concentrated hydrochloric acid pickling solutions |
url | http://dx.doi.org/10.1155/2017/1893672 |
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