Oxidation behavior of a low-cost second-generation Ni-based single crystal superalloy at 900 °C and 1000 °C

The temperature dependence on the oxide layer and the oxidation mechanism was systematically investigated at 900 °C and 1000 °C in a low-cost second-generation Ni-based single crystal superalloy. The oxidation kinetics could be divided into three stages. The initial stage followed a parabolic law wi...

Full description

Saved in:
Bibliographic Details
Main Authors: Haitao Fu, Wenchao Yang, Qiang Wang, Chen Liu, Jiarun Qin, Yuzhang Lu, Jian Shen, Haijun Su, Lin Liu
Format: Article
Language:English
Published: Elsevier 2025-01-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785424029168
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832595344749232128
author Haitao Fu
Wenchao Yang
Qiang Wang
Chen Liu
Jiarun Qin
Yuzhang Lu
Jian Shen
Haijun Su
Lin Liu
author_facet Haitao Fu
Wenchao Yang
Qiang Wang
Chen Liu
Jiarun Qin
Yuzhang Lu
Jian Shen
Haijun Su
Lin Liu
author_sort Haitao Fu
collection DOAJ
description The temperature dependence on the oxide layer and the oxidation mechanism was systematically investigated at 900 °C and 1000 °C in a low-cost second-generation Ni-based single crystal superalloy. The oxidation kinetics could be divided into three stages. The initial stage followed a parabolic law with an activation energy of 60.08 kJ mol−1. A linear law was observed in the second stage due to the formation of Al2O3. However, the last stage showed different trends, following an almost flat linear law at 900 °C, while an abnormal increase was observed at 1000 °C. The difference was attributed to the rapid growth of intermediate layer at 1000 °C, while the slight increase at 900 °C resulted in higher growth stress at 1000 °C. Meanwhile, the thermal stress was generated during the cooling process of specimens, which promoted the spallation of the oxide layer. As a result, the spallation of the oxide layer was more severe at 1000 °C, causing the abnormal increase of oxidation kinetics at this stage.
format Article
id doaj-art-a4ee9c5c0dd54c8e832faae995dd3064
institution Kabale University
issn 2238-7854
language English
publishDate 2025-01-01
publisher Elsevier
record_format Article
series Journal of Materials Research and Technology
spelling doaj-art-a4ee9c5c0dd54c8e832faae995dd30642025-01-19T06:25:31ZengElsevierJournal of Materials Research and Technology2238-78542025-01-0134797806Oxidation behavior of a low-cost second-generation Ni-based single crystal superalloy at 900 °C and 1000 °CHaitao Fu0Wenchao Yang1Qiang Wang2Chen Liu3Jiarun Qin4Yuzhang Lu5Jian Shen6Haijun Su7Lin Liu8State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an, 710072, ChinaState Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an, 710072, China; Corresponding author.State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an, 710072, ChinaState Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an, 710072, ChinaState Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an, 710072, ChinaInstitute of Metal Research, Chinese Academy of Sciences, Shenyang, 110016, ChinaInstitute of Metal Research, Chinese Academy of Sciences, Shenyang, 110016, ChinaState Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an, 710072, ChinaState Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an, 710072, ChinaThe temperature dependence on the oxide layer and the oxidation mechanism was systematically investigated at 900 °C and 1000 °C in a low-cost second-generation Ni-based single crystal superalloy. The oxidation kinetics could be divided into three stages. The initial stage followed a parabolic law with an activation energy of 60.08 kJ mol−1. A linear law was observed in the second stage due to the formation of Al2O3. However, the last stage showed different trends, following an almost flat linear law at 900 °C, while an abnormal increase was observed at 1000 °C. The difference was attributed to the rapid growth of intermediate layer at 1000 °C, while the slight increase at 900 °C resulted in higher growth stress at 1000 °C. Meanwhile, the thermal stress was generated during the cooling process of specimens, which promoted the spallation of the oxide layer. As a result, the spallation of the oxide layer was more severe at 1000 °C, causing the abnormal increase of oxidation kinetics at this stage.http://www.sciencedirect.com/science/article/pii/S2238785424029168Ni-based single crystal superalloyOxidation behaviorOxidation kineticsOxide layer
spellingShingle Haitao Fu
Wenchao Yang
Qiang Wang
Chen Liu
Jiarun Qin
Yuzhang Lu
Jian Shen
Haijun Su
Lin Liu
Oxidation behavior of a low-cost second-generation Ni-based single crystal superalloy at 900 °C and 1000 °C
Journal of Materials Research and Technology
Ni-based single crystal superalloy
Oxidation behavior
Oxidation kinetics
Oxide layer
title Oxidation behavior of a low-cost second-generation Ni-based single crystal superalloy at 900 °C and 1000 °C
title_full Oxidation behavior of a low-cost second-generation Ni-based single crystal superalloy at 900 °C and 1000 °C
title_fullStr Oxidation behavior of a low-cost second-generation Ni-based single crystal superalloy at 900 °C and 1000 °C
title_full_unstemmed Oxidation behavior of a low-cost second-generation Ni-based single crystal superalloy at 900 °C and 1000 °C
title_short Oxidation behavior of a low-cost second-generation Ni-based single crystal superalloy at 900 °C and 1000 °C
title_sort oxidation behavior of a low cost second generation ni based single crystal superalloy at 900 °c and 1000 °c
topic Ni-based single crystal superalloy
Oxidation behavior
Oxidation kinetics
Oxide layer
url http://www.sciencedirect.com/science/article/pii/S2238785424029168
work_keys_str_mv AT haitaofu oxidationbehaviorofalowcostsecondgenerationnibasedsinglecrystalsuperalloyat900cand1000c
AT wenchaoyang oxidationbehaviorofalowcostsecondgenerationnibasedsinglecrystalsuperalloyat900cand1000c
AT qiangwang oxidationbehaviorofalowcostsecondgenerationnibasedsinglecrystalsuperalloyat900cand1000c
AT chenliu oxidationbehaviorofalowcostsecondgenerationnibasedsinglecrystalsuperalloyat900cand1000c
AT jiarunqin oxidationbehaviorofalowcostsecondgenerationnibasedsinglecrystalsuperalloyat900cand1000c
AT yuzhanglu oxidationbehaviorofalowcostsecondgenerationnibasedsinglecrystalsuperalloyat900cand1000c
AT jianshen oxidationbehaviorofalowcostsecondgenerationnibasedsinglecrystalsuperalloyat900cand1000c
AT haijunsu oxidationbehaviorofalowcostsecondgenerationnibasedsinglecrystalsuperalloyat900cand1000c
AT linliu oxidationbehaviorofalowcostsecondgenerationnibasedsinglecrystalsuperalloyat900cand1000c