Structural and Electrical Conductivity Properties of a Newly Synthesized 3-Methoxybenzylammonium Cation Diphosphate
The structure of the newly synthesized material, [3-(CH3O)C6H4CH2NH3]2H2P2O7 can be described as inorganic layers (H2P2O72-)n stacked perpendicular to the c-axis at z = 0 and z = 1/2 interleaved with organic cations [3-(CH3O)C6H4CH2NH3]+. The connection of the independent entities are assured by a s...
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| Format: | Article |
| Language: | English |
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Wiley
2012-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2012/731585 |
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| author | A. Elboulali S. Akriche M. Rzaigui S. S. Al-Deyab |
| author_facet | A. Elboulali S. Akriche M. Rzaigui S. S. Al-Deyab |
| author_sort | A. Elboulali |
| collection | DOAJ |
| description | The structure of the newly synthesized material, [3-(CH3O)C6H4CH2NH3]2H2P2O7 can be described as inorganic layers (H2P2O72-)n stacked perpendicular to the c-axis at z = 0 and z = 1/2 interleaved with organic cations [3-(CH3O)C6H4CH2NH3]+. The connection of the independent entities are assured by a set of N—H…O and C—H…O H-bonds in addition to electrostatic and Van der Waals interactions, generating a non-centrosymetric three-dimensional network. On the basis of electrical conductivity measurements, it was found that, at higher temperature conductivity increases linearly, showing medium conducting behaviour of the organic diphosphate salt with values lying in the range of σ= 0.69 10−4 Ω−1cm−1 at 328 K to 2.66 10−4 Ω−1cm−1 at 405 K and activation energy of Ea = 0.23 eV. Its characterization by IR absorption spectroscopy is described too. |
| format | Article |
| id | doaj-art-a3eddff0a89446c1bb88b1ea74eecbde |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2012-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-a3eddff0a89446c1bb88b1ea74eecbde2025-02-03T07:25:57ZengWileyE-Journal of Chemistry0973-49452090-98102012-01-01942029203610.1155/2012/731585Structural and Electrical Conductivity Properties of a Newly Synthesized 3-Methoxybenzylammonium Cation DiphosphateA. Elboulali0S. Akriche1M. Rzaigui2S. S. Al-Deyab3Laboratoire de Chimie des Matériaux, Faculté des Sciences 7021 Zarzouna, Bizerte, TunisiaLaboratoire de Chimie des Matériaux, Faculté des Sciences 7021 Zarzouna, Bizerte, TunisiaLaboratoire de Chimie des Matériaux, Faculté des Sciences 7021 Zarzouna, Bizerte, TunisiaPetrochemical Research Chair, College of Science, King Saud University, Riyadh, Saudi ArabiaThe structure of the newly synthesized material, [3-(CH3O)C6H4CH2NH3]2H2P2O7 can be described as inorganic layers (H2P2O72-)n stacked perpendicular to the c-axis at z = 0 and z = 1/2 interleaved with organic cations [3-(CH3O)C6H4CH2NH3]+. The connection of the independent entities are assured by a set of N—H…O and C—H…O H-bonds in addition to electrostatic and Van der Waals interactions, generating a non-centrosymetric three-dimensional network. On the basis of electrical conductivity measurements, it was found that, at higher temperature conductivity increases linearly, showing medium conducting behaviour of the organic diphosphate salt with values lying in the range of σ= 0.69 10−4 Ω−1cm−1 at 328 K to 2.66 10−4 Ω−1cm−1 at 405 K and activation energy of Ea = 0.23 eV. Its characterization by IR absorption spectroscopy is described too.http://dx.doi.org/10.1155/2012/731585 |
| spellingShingle | A. Elboulali S. Akriche M. Rzaigui S. S. Al-Deyab Structural and Electrical Conductivity Properties of a Newly Synthesized 3-Methoxybenzylammonium Cation Diphosphate E-Journal of Chemistry |
| title | Structural and Electrical Conductivity Properties of a Newly Synthesized 3-Methoxybenzylammonium Cation Diphosphate |
| title_full | Structural and Electrical Conductivity Properties of a Newly Synthesized 3-Methoxybenzylammonium Cation Diphosphate |
| title_fullStr | Structural and Electrical Conductivity Properties of a Newly Synthesized 3-Methoxybenzylammonium Cation Diphosphate |
| title_full_unstemmed | Structural and Electrical Conductivity Properties of a Newly Synthesized 3-Methoxybenzylammonium Cation Diphosphate |
| title_short | Structural and Electrical Conductivity Properties of a Newly Synthesized 3-Methoxybenzylammonium Cation Diphosphate |
| title_sort | structural and electrical conductivity properties of a newly synthesized 3 methoxybenzylammonium cation diphosphate |
| url | http://dx.doi.org/10.1155/2012/731585 |
| work_keys_str_mv | AT aelboulali structuralandelectricalconductivitypropertiesofanewlysynthesized3methoxybenzylammoniumcationdiphosphate AT sakriche structuralandelectricalconductivitypropertiesofanewlysynthesized3methoxybenzylammoniumcationdiphosphate AT mrzaigui structuralandelectricalconductivitypropertiesofanewlysynthesized3methoxybenzylammoniumcationdiphosphate AT ssaldeyab structuralandelectricalconductivitypropertiesofanewlysynthesized3methoxybenzylammoniumcationdiphosphate |