Occurrence and Origin of H2S from Volcanic Reservoirs in Niudong Area of the Santanghu Basin, NW China

A series of samples including natural gas, formation water, and rocks were collected from volcanic rock reservoirs in the Niudong area of the Santanghu Oilfields and analyzed for their mineral and/or chemical compositions and sulfur and carbon isotopes in order to investigate the occurrence and orig...

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Main Authors: Xiangxian Ma, Guodong Zheng, Minliang Liang, Dianhe Xie, Giovanni Martinelli, Wasim Sajjad, Wang Xu, Qiaohui Fan, Liwu Li, Li Du, Yidong Zhao
Format: Article
Language:English
Published: Wiley 2019-01-01
Series:Geofluids
Online Access:http://dx.doi.org/10.1155/2019/1279658
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author Xiangxian Ma
Guodong Zheng
Minliang Liang
Dianhe Xie
Giovanni Martinelli
Wasim Sajjad
Wang Xu
Qiaohui Fan
Liwu Li
Li Du
Yidong Zhao
author_facet Xiangxian Ma
Guodong Zheng
Minliang Liang
Dianhe Xie
Giovanni Martinelli
Wasim Sajjad
Wang Xu
Qiaohui Fan
Liwu Li
Li Du
Yidong Zhao
author_sort Xiangxian Ma
collection DOAJ
description A series of samples including natural gas, formation water, and rocks were collected from volcanic rock reservoirs in the Niudong area of the Santanghu Oilfields and analyzed for their mineral and/or chemical compositions and sulfur and carbon isotopes in order to investigate the occurrence and origin of hydrogen sulfide (H2S). H2S was mostly dissolved in the formation water along with petroleum production in the study area. The δ34S values of on-well H2S samples varied in a range of 9.2‰ to 20.5‰, probably indicating thermochemical sulfate reduction (TSR) and/or thermal decomposition of organic sulfur-bearing compounds (TDS) as the genetic process for H2S. However, the chemical composition of formation waters from the Kalagang Formation (C2k) and their coefficient of desulfurization also revealed that TSR could be the main principle for H2S formation. Considering the regional geological background, especially the tectonic structures and thermal evolution features of the basin, it was concluded that H2S in the study area was dominantly produced by thermal genesis with TSR as a domain through interactions between hydrocarbons and aqueous sulfate dissolved from sulfate minerals.
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institution Kabale University
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publishDate 2019-01-01
publisher Wiley
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series Geofluids
spelling doaj-art-a2e1910af2224411b40d2e233948923a2025-02-03T01:22:23ZengWileyGeofluids1468-81151468-81232019-01-01201910.1155/2019/12796581279658Occurrence and Origin of H2S from Volcanic Reservoirs in Niudong Area of the Santanghu Basin, NW ChinaXiangxian Ma0Guodong Zheng1Minliang Liang2Dianhe Xie3Giovanni Martinelli4Wasim Sajjad5Wang Xu6Qiaohui Fan7Liwu Li8Li Du9Yidong Zhao10Northwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730000, ChinaNorthwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730000, ChinaInstitute of Geomechanics, Key Lab of Shale Oil and Gas Geological Survey, Chinese Academy of Geological Sciences, Beijing 100081, ChinaSantanghu Oil Production Plant, Tuha Oilfield Company, PetroChina, Hami 839009, ChinaNorthwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730000, ChinaNorthwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730000, ChinaNorthwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730000, ChinaNorthwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730000, ChinaNorthwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730000, ChinaNorthwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730000, ChinaBeijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, ChinaA series of samples including natural gas, formation water, and rocks were collected from volcanic rock reservoirs in the Niudong area of the Santanghu Oilfields and analyzed for their mineral and/or chemical compositions and sulfur and carbon isotopes in order to investigate the occurrence and origin of hydrogen sulfide (H2S). H2S was mostly dissolved in the formation water along with petroleum production in the study area. The δ34S values of on-well H2S samples varied in a range of 9.2‰ to 20.5‰, probably indicating thermochemical sulfate reduction (TSR) and/or thermal decomposition of organic sulfur-bearing compounds (TDS) as the genetic process for H2S. However, the chemical composition of formation waters from the Kalagang Formation (C2k) and their coefficient of desulfurization also revealed that TSR could be the main principle for H2S formation. Considering the regional geological background, especially the tectonic structures and thermal evolution features of the basin, it was concluded that H2S in the study area was dominantly produced by thermal genesis with TSR as a domain through interactions between hydrocarbons and aqueous sulfate dissolved from sulfate minerals.http://dx.doi.org/10.1155/2019/1279658
spellingShingle Xiangxian Ma
Guodong Zheng
Minliang Liang
Dianhe Xie
Giovanni Martinelli
Wasim Sajjad
Wang Xu
Qiaohui Fan
Liwu Li
Li Du
Yidong Zhao
Occurrence and Origin of H2S from Volcanic Reservoirs in Niudong Area of the Santanghu Basin, NW China
Geofluids
title Occurrence and Origin of H2S from Volcanic Reservoirs in Niudong Area of the Santanghu Basin, NW China
title_full Occurrence and Origin of H2S from Volcanic Reservoirs in Niudong Area of the Santanghu Basin, NW China
title_fullStr Occurrence and Origin of H2S from Volcanic Reservoirs in Niudong Area of the Santanghu Basin, NW China
title_full_unstemmed Occurrence and Origin of H2S from Volcanic Reservoirs in Niudong Area of the Santanghu Basin, NW China
title_short Occurrence and Origin of H2S from Volcanic Reservoirs in Niudong Area of the Santanghu Basin, NW China
title_sort occurrence and origin of h2s from volcanic reservoirs in niudong area of the santanghu basin nw china
url http://dx.doi.org/10.1155/2019/1279658
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