Local time statistics and permeable barrier crossing: From Poisson to birth-death diffusion equations

Barrier crossing is a widespread phenomenon across natural and engineering systems. While abundant cross-disciplinary literature on the topic has emerged over the years, the stochastic underpinnings of the process have yet to be linked quantitatively to easily measurable observables. We bridge this...

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Main Authors: Toby Kay, Luca Giuggioli
Format: Article
Language:English
Published: American Physical Society 2025-01-01
Series:Physical Review Research
Online Access:http://doi.org/10.1103/PhysRevResearch.7.013097
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author Toby Kay
Luca Giuggioli
author_facet Toby Kay
Luca Giuggioli
author_sort Toby Kay
collection DOAJ
description Barrier crossing is a widespread phenomenon across natural and engineering systems. While abundant cross-disciplinary literature on the topic has emerged over the years, the stochastic underpinnings of the process have yet to be linked quantitatively to easily measurable observables. We bridge this gap by developing a microscopic representation of Brownian motion in the presence of permeable barriers that allows us to treat barriers with constant asymmetric permeabilities. Our approach relies upon reflected Brownian motion and on the crossing events being Poisson processes subordinated by the local time of the underlying motion at the barrier. Within this paradigm, we derive the exact expression for the distribution of the number of crossings and find an experimentally measurable statistical definition of permeability. We employ Feynman-Kac theory to derive and solve a set of governing birth-death diffusion equations and extend them to the case when barrier permeability is constant and asymmetric. As an application, we study a system of infinite, identical, and periodically placed asymmetric barriers for which we derive analytically effective transport parameters. This periodic arrangement induces an effective drift at long times whose magnitude depends on the difference in the permeability on either side of the barrier as well as on their absolute values. As the asymmetric permeabilities act akin to localized ratchet potentials that break spatial symmetry and detailed balance, the proposed arrangement of asymmetric barriers provides an example of a noise-induced drift without the need to time modulate any external force or create temporal correlations on the motion of a diffusing particle. By placing only one asymmetric barrier in a periodic domain, we also show the emergence of a nonequilibrium steady state.
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spelling doaj-art-a291eba3523d4e6396dd45e4089db3022025-01-24T15:33:35ZengAmerican Physical SocietyPhysical Review Research2643-15642025-01-017101309710.1103/PhysRevResearch.7.013097Local time statistics and permeable barrier crossing: From Poisson to birth-death diffusion equationsToby KayLuca GiuggioliBarrier crossing is a widespread phenomenon across natural and engineering systems. While abundant cross-disciplinary literature on the topic has emerged over the years, the stochastic underpinnings of the process have yet to be linked quantitatively to easily measurable observables. We bridge this gap by developing a microscopic representation of Brownian motion in the presence of permeable barriers that allows us to treat barriers with constant asymmetric permeabilities. Our approach relies upon reflected Brownian motion and on the crossing events being Poisson processes subordinated by the local time of the underlying motion at the barrier. Within this paradigm, we derive the exact expression for the distribution of the number of crossings and find an experimentally measurable statistical definition of permeability. We employ Feynman-Kac theory to derive and solve a set of governing birth-death diffusion equations and extend them to the case when barrier permeability is constant and asymmetric. As an application, we study a system of infinite, identical, and periodically placed asymmetric barriers for which we derive analytically effective transport parameters. This periodic arrangement induces an effective drift at long times whose magnitude depends on the difference in the permeability on either side of the barrier as well as on their absolute values. As the asymmetric permeabilities act akin to localized ratchet potentials that break spatial symmetry and detailed balance, the proposed arrangement of asymmetric barriers provides an example of a noise-induced drift without the need to time modulate any external force or create temporal correlations on the motion of a diffusing particle. By placing only one asymmetric barrier in a periodic domain, we also show the emergence of a nonequilibrium steady state.http://doi.org/10.1103/PhysRevResearch.7.013097
spellingShingle Toby Kay
Luca Giuggioli
Local time statistics and permeable barrier crossing: From Poisson to birth-death diffusion equations
Physical Review Research
title Local time statistics and permeable barrier crossing: From Poisson to birth-death diffusion equations
title_full Local time statistics and permeable barrier crossing: From Poisson to birth-death diffusion equations
title_fullStr Local time statistics and permeable barrier crossing: From Poisson to birth-death diffusion equations
title_full_unstemmed Local time statistics and permeable barrier crossing: From Poisson to birth-death diffusion equations
title_short Local time statistics and permeable barrier crossing: From Poisson to birth-death diffusion equations
title_sort local time statistics and permeable barrier crossing from poisson to birth death diffusion equations
url http://doi.org/10.1103/PhysRevResearch.7.013097
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