Polydopamine Induced Wettability Switching of Cellulose Nanofibers/n-Dodecanethiol Composite Aerogels

The novel wettability switchable cellulose nanofiber- (CNF-) based aerogel was conveniently prepared by polydopamine mediated composition of CNF and n-dodecanethiol. The wettability of aerogels can be controlled by adjusting the PDA and n-dodecanethiol loading content, which leads to a variation of...

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Bibliographic Details
Main Authors: Runan Gao, Ying Shang, Peng Jiao, Yue Jiao, Jian Li, Yun Lu
Format: Article
Language:English
Published: Wiley 2022-01-01
Series:International Journal of Polymer Science
Online Access:http://dx.doi.org/10.1155/2022/5048717
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Summary:The novel wettability switchable cellulose nanofiber- (CNF-) based aerogel was conveniently prepared by polydopamine mediated composition of CNF and n-dodecanethiol. The wettability of aerogels can be controlled by adjusting the PDA and n-dodecanethiol loading content, which leads to a variation of water contact angle from 0-149°. The PDA was coated on cellulose nanofibers via hydrogen bonds and then n-dodecanethiol was anchored onto the scaffolds by Michael addition reaction, which was revealed by XPS and FTIR spectra. The composite aerogel can selectively absorb a series of oily liquids from the oil/water mixture, with the maximum absorption capacity of 68 g/g. This work presented a facile strategy to prepare wettability switchable CNF-based heterogenous aerogel and exhibited the potential of the composite aerogel for oil/water separation.
ISSN:1687-9430