Amino acid-derived imidazole zwitterion as green interfacial corrosion inhibitor for cold rolled steel
A natural amino acid methionine-derived imidazole zwitterion was synthesized and investigated as a corrosion inhibitor on cold-rolled steel in an acid environment using weight loss, electrochemistry, and SEM techniques. The synthesized imidazole zwitterion inhibitor was fulfilled with green paramete...
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| Format: | Article |
| Language: | English |
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Elsevier
2025-06-01
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| Series: | Case Studies in Chemical and Environmental Engineering |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2666016425000106 |
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| author | Wan Mohd Norsani Wan Nik Jiyaul Haque Mohd Sabri Mohd Ghazali Atria Pradityana Izionworu Vincent Onuegbu Walid Daoudi Elyor Berdimurodov Ahmed Abdulamier Al-Amiery |
| author_facet | Wan Mohd Norsani Wan Nik Jiyaul Haque Mohd Sabri Mohd Ghazali Atria Pradityana Izionworu Vincent Onuegbu Walid Daoudi Elyor Berdimurodov Ahmed Abdulamier Al-Amiery |
| author_sort | Wan Mohd Norsani Wan Nik |
| collection | DOAJ |
| description | A natural amino acid methionine-derived imidazole zwitterion was synthesized and investigated as a corrosion inhibitor on cold-rolled steel in an acid environment using weight loss, electrochemistry, and SEM techniques. The synthesized imidazole zwitterion inhibitor was fulfilled with green parameters: multicomponent single-step reaction, reaction at ambient temperature, and water used as a solvent. The corrosion study results show that imidazole zwitterion exhibits effective inhibition efficiency (84 %) at very low concentrations (100 ppm). The imidazole zwitterion exhibited excellent inhibition efficiency (72 %) at high temperature (95 °C). SEM results supported the experimental findings. The adsorption of imidazole zwitterion obeys the Langmuir adsorption isotherm with a uniform inhibitor film achieved via physical and chemical adsorption mechanisms. Imidazole zwitterion can be useful in low inhibitor concentration applications such as pipeline flushing and cleaning. |
| format | Article |
| id | doaj-art-a1878690b0ad47cf9fae3f132eb80978 |
| institution | Kabale University |
| issn | 2666-0164 |
| language | English |
| publishDate | 2025-06-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Case Studies in Chemical and Environmental Engineering |
| spelling | doaj-art-a1878690b0ad47cf9fae3f132eb809782025-01-18T05:05:12ZengElsevierCase Studies in Chemical and Environmental Engineering2666-01642025-06-0111101103Amino acid-derived imidazole zwitterion as green interfacial corrosion inhibitor for cold rolled steelWan Mohd Norsani Wan Nik0Jiyaul Haque1Mohd Sabri Mohd Ghazali2Atria Pradityana3Izionworu Vincent Onuegbu4Walid Daoudi5Elyor Berdimurodov6Ahmed Abdulamier Al-Amiery7Faculty of Ocean Engineering Technology, Universiti Malaysia Terengganu, Kuala Nerus, 21030, MalaysiaFaculty of Ocean Engineering Technology, Universiti Malaysia Terengganu, Kuala Nerus, 21030, MalaysiaFaculty of Science and Marine Environment, Universiti Malaysia Terengganu, Kuala Nerus, 21030, MalaysiaDept. of Mechanical Industrial Engineering, Vocational Faculty, Institut Teknologi Sepuluh Nopember Surabaya, 60111, East Java, Indonesia; Corresponding author.Department of Chemical/Petrochemical Engineering. Rivers State University, Nkpolu-Oroworukwo, Port Harcourt, NigeriaDepartment of Chemistry, Multidisciplinary Faculty, University Mohamed I, 60700, Nador, MoroccoChemical & Materials Engineering, New Uzbekistan University, 54 Mustaqillik Ave., Tashkent, 100007, UzbekistanFaculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, Bangi, 43600, Selangor, MalaysiaA natural amino acid methionine-derived imidazole zwitterion was synthesized and investigated as a corrosion inhibitor on cold-rolled steel in an acid environment using weight loss, electrochemistry, and SEM techniques. The synthesized imidazole zwitterion inhibitor was fulfilled with green parameters: multicomponent single-step reaction, reaction at ambient temperature, and water used as a solvent. The corrosion study results show that imidazole zwitterion exhibits effective inhibition efficiency (84 %) at very low concentrations (100 ppm). The imidazole zwitterion exhibited excellent inhibition efficiency (72 %) at high temperature (95 °C). SEM results supported the experimental findings. The adsorption of imidazole zwitterion obeys the Langmuir adsorption isotherm with a uniform inhibitor film achieved via physical and chemical adsorption mechanisms. Imidazole zwitterion can be useful in low inhibitor concentration applications such as pipeline flushing and cleaning.http://www.sciencedirect.com/science/article/pii/S2666016425000106Imidazole zwitterionsGreen chemistryCorrosion inhibitorAdsorptionSEM |
| spellingShingle | Wan Mohd Norsani Wan Nik Jiyaul Haque Mohd Sabri Mohd Ghazali Atria Pradityana Izionworu Vincent Onuegbu Walid Daoudi Elyor Berdimurodov Ahmed Abdulamier Al-Amiery Amino acid-derived imidazole zwitterion as green interfacial corrosion inhibitor for cold rolled steel Case Studies in Chemical and Environmental Engineering Imidazole zwitterions Green chemistry Corrosion inhibitor Adsorption SEM |
| title | Amino acid-derived imidazole zwitterion as green interfacial corrosion inhibitor for cold rolled steel |
| title_full | Amino acid-derived imidazole zwitterion as green interfacial corrosion inhibitor for cold rolled steel |
| title_fullStr | Amino acid-derived imidazole zwitterion as green interfacial corrosion inhibitor for cold rolled steel |
| title_full_unstemmed | Amino acid-derived imidazole zwitterion as green interfacial corrosion inhibitor for cold rolled steel |
| title_short | Amino acid-derived imidazole zwitterion as green interfacial corrosion inhibitor for cold rolled steel |
| title_sort | amino acid derived imidazole zwitterion as green interfacial corrosion inhibitor for cold rolled steel |
| topic | Imidazole zwitterions Green chemistry Corrosion inhibitor Adsorption SEM |
| url | http://www.sciencedirect.com/science/article/pii/S2666016425000106 |
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