Amino acid-derived imidazole zwitterion as green interfacial corrosion inhibitor for cold rolled steel

A natural amino acid methionine-derived imidazole zwitterion was synthesized and investigated as a corrosion inhibitor on cold-rolled steel in an acid environment using weight loss, electrochemistry, and SEM techniques. The synthesized imidazole zwitterion inhibitor was fulfilled with green paramete...

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Bibliographic Details
Main Authors: Wan Mohd Norsani Wan Nik, Jiyaul Haque, Mohd Sabri Mohd Ghazali, Atria Pradityana, Izionworu Vincent Onuegbu, Walid Daoudi, Elyor Berdimurodov, Ahmed Abdulamier Al-Amiery
Format: Article
Language:English
Published: Elsevier 2025-06-01
Series:Case Studies in Chemical and Environmental Engineering
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Online Access:http://www.sciencedirect.com/science/article/pii/S2666016425000106
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Summary:A natural amino acid methionine-derived imidazole zwitterion was synthesized and investigated as a corrosion inhibitor on cold-rolled steel in an acid environment using weight loss, electrochemistry, and SEM techniques. The synthesized imidazole zwitterion inhibitor was fulfilled with green parameters: multicomponent single-step reaction, reaction at ambient temperature, and water used as a solvent. The corrosion study results show that imidazole zwitterion exhibits effective inhibition efficiency (84 %) at very low concentrations (100 ppm). The imidazole zwitterion exhibited excellent inhibition efficiency (72 %) at high temperature (95 °C). SEM results supported the experimental findings. The adsorption of imidazole zwitterion obeys the Langmuir adsorption isotherm with a uniform inhibitor film achieved via physical and chemical adsorption mechanisms. Imidazole zwitterion can be useful in low inhibitor concentration applications such as pipeline flushing and cleaning.
ISSN:2666-0164