Design and Synthesis of Metal Complexes of (2E)-2-[(2E)-3-Phenylprop-2-en-1-ylidene]hydrazinecarbothioamide and Their Photocatalytic Degradation of Methylene Blue
The photocatalytic degradation has been considered to be an efficient process for the degradation of organic pollutants, which are present in the effluents released by industries. The photocatalytic bleaching of cationic dye methylene blue was carried out spectrometrically on irradiation of UV ligh...
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| Format: | Article |
| Language: | English |
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Wiley
2013-01-01
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| Series: | The Scientific World Journal |
| Online Access: | http://dx.doi.org/10.1155/2013/828313 |
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| author | P. Murali Krishna N. B. Gopal Reddy Nagaraju Kottam B. C. Yallur Hussain Reddy Katreddi |
| author_facet | P. Murali Krishna N. B. Gopal Reddy Nagaraju Kottam B. C. Yallur Hussain Reddy Katreddi |
| author_sort | P. Murali Krishna |
| collection | DOAJ |
| description | The photocatalytic degradation has been considered to be an efficient process for the degradation of organic pollutants, which are present in the effluents released by industries. The photocatalytic bleaching of cationic dye methylene blue was carried out spectrometrically on irradiation of UV light using Cu(II), Ni(II), and Co(II) complexes of (2E)-2-[(2E)-3-phenylprop-2-en-1-ylidene]hydrazinecarbothioamide (HL). The effects of pH and metal ion were studied on the efficiency of the reaction. Cu(II) complex shows better catalytic activity and the highest percentage degradation (~88.8%) of methylene blue was observed at pH 12. A tentative mechanism has also been proposed for the photocatalytic degradation of methylene blue. |
| format | Article |
| id | doaj-art-a045d10fd6054b988c99349ad95ce443 |
| institution | Kabale University |
| issn | 1537-744X |
| language | English |
| publishDate | 2013-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | The Scientific World Journal |
| spelling | doaj-art-a045d10fd6054b988c99349ad95ce4432025-02-03T06:06:23ZengWileyThe Scientific World Journal1537-744X2013-01-01201310.1155/2013/828313828313Design and Synthesis of Metal Complexes of (2E)-2-[(2E)-3-Phenylprop-2-en-1-ylidene]hydrazinecarbothioamide and Their Photocatalytic Degradation of Methylene BlueP. Murali Krishna0N. B. Gopal Reddy1Nagaraju Kottam2B. C. Yallur3Hussain Reddy Katreddi4Department of Chemistry, M. S. Ramaiah Institute of Technology, Bangalore 560 054, IndiaDepartment of Chemistry, M. S. Ramaiah Institute of Technology, Bangalore 560 054, IndiaDepartment of Chemistry, M. S. Ramaiah Institute of Technology, Bangalore 560 054, IndiaDepartment of Chemistry, M. S. Ramaiah Institute of Technology, Bangalore 560 054, IndiaDepartment of Chemistry, Sri Krishnadevaraya University, Anantapur 515 006, IndiaThe photocatalytic degradation has been considered to be an efficient process for the degradation of organic pollutants, which are present in the effluents released by industries. The photocatalytic bleaching of cationic dye methylene blue was carried out spectrometrically on irradiation of UV light using Cu(II), Ni(II), and Co(II) complexes of (2E)-2-[(2E)-3-phenylprop-2-en-1-ylidene]hydrazinecarbothioamide (HL). The effects of pH and metal ion were studied on the efficiency of the reaction. Cu(II) complex shows better catalytic activity and the highest percentage degradation (~88.8%) of methylene blue was observed at pH 12. A tentative mechanism has also been proposed for the photocatalytic degradation of methylene blue.http://dx.doi.org/10.1155/2013/828313 |
| spellingShingle | P. Murali Krishna N. B. Gopal Reddy Nagaraju Kottam B. C. Yallur Hussain Reddy Katreddi Design and Synthesis of Metal Complexes of (2E)-2-[(2E)-3-Phenylprop-2-en-1-ylidene]hydrazinecarbothioamide and Their Photocatalytic Degradation of Methylene Blue The Scientific World Journal |
| title | Design and Synthesis of Metal Complexes of (2E)-2-[(2E)-3-Phenylprop-2-en-1-ylidene]hydrazinecarbothioamide and Their Photocatalytic Degradation of Methylene Blue |
| title_full | Design and Synthesis of Metal Complexes of (2E)-2-[(2E)-3-Phenylprop-2-en-1-ylidene]hydrazinecarbothioamide and Their Photocatalytic Degradation of Methylene Blue |
| title_fullStr | Design and Synthesis of Metal Complexes of (2E)-2-[(2E)-3-Phenylprop-2-en-1-ylidene]hydrazinecarbothioamide and Their Photocatalytic Degradation of Methylene Blue |
| title_full_unstemmed | Design and Synthesis of Metal Complexes of (2E)-2-[(2E)-3-Phenylprop-2-en-1-ylidene]hydrazinecarbothioamide and Their Photocatalytic Degradation of Methylene Blue |
| title_short | Design and Synthesis of Metal Complexes of (2E)-2-[(2E)-3-Phenylprop-2-en-1-ylidene]hydrazinecarbothioamide and Their Photocatalytic Degradation of Methylene Blue |
| title_sort | design and synthesis of metal complexes of 2e 2 2e 3 phenylprop 2 en 1 ylidene hydrazinecarbothioamide and their photocatalytic degradation of methylene blue |
| url | http://dx.doi.org/10.1155/2013/828313 |
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