Effect of Pd and Au Sensitization of Bath Deposited Flowerlike TiO2 Thin Films on CO Sensing and Photocatalytic Properties

TiO2 thin films having flower structure with nanopetals are deposited by chemical bath deposition (CBD) method. Deposited TiO2 films are formed in pure anatase phase as confirmed by X-ray diffraction (XRD) analysis. Deposited films are used for detection of environmental hazardous carbon monoxide (C...

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Main Authors: Ashok K. Singh, S. B. Patil, Umesh T. Nakate, K. V. Gurav
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2013/370578
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author Ashok K. Singh
S. B. Patil
Umesh T. Nakate
K. V. Gurav
author_facet Ashok K. Singh
S. B. Patil
Umesh T. Nakate
K. V. Gurav
author_sort Ashok K. Singh
collection DOAJ
description TiO2 thin films having flower structure with nanopetals are deposited by chemical bath deposition (CBD) method. Deposited TiO2 films are formed in pure anatase phase as confirmed by X-ray diffraction (XRD) analysis. Deposited films are used for detection of environmental hazardous carbon monoxide (CO) gas and photocatalytic (PC) degradation of malachite green (MG) dye. Effect of Pd and Au catalysts sensitization on gas sensing as well as PC degradation properties is investigated. The use of catalyst led to enhancement in the gas sensitivity and reduction in the operating temperature as well as response and recovery times. The Au sensitized film showed better CO sensing performance and PC efficiency in comparison to unsensitized and Pd sensitized TiO2 thin films. For Au sensitized film, gas sensitivity, response time, and recovery time are found to be 32% (14% for TiO2), 80 s, and 100 s, respectively, and PC efficiency is found to be 26.6% (16.9% for TiO2).
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spelling doaj-art-9ee0f5884bb24e6d8c63806d86c83f2a2025-02-03T00:59:22ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/370578370578Effect of Pd and Au Sensitization of Bath Deposited Flowerlike TiO2 Thin Films on CO Sensing and Photocatalytic PropertiesAshok K. Singh0S. B. Patil1Umesh T. Nakate2K. V. Gurav3DRDO Center for Piezoceramics and Devices, ARDE, Pashan, Pune 411007, IndiaNanomaterials & Sensors Laboratory, Defence Institute of Advanced Technology (DU), Girinagar, Pune 411025, IndiaNanomaterials & Sensors Laboratory, Defence Institute of Advanced Technology (DU), Girinagar, Pune 411025, IndiaPhotonic and Electronic Thin Film Laboratory, Department of Material Science and Engineering, Chonnam National University, Gwangju 500-757, Republic of KoreaTiO2 thin films having flower structure with nanopetals are deposited by chemical bath deposition (CBD) method. Deposited TiO2 films are formed in pure anatase phase as confirmed by X-ray diffraction (XRD) analysis. Deposited films are used for detection of environmental hazardous carbon monoxide (CO) gas and photocatalytic (PC) degradation of malachite green (MG) dye. Effect of Pd and Au catalysts sensitization on gas sensing as well as PC degradation properties is investigated. The use of catalyst led to enhancement in the gas sensitivity and reduction in the operating temperature as well as response and recovery times. The Au sensitized film showed better CO sensing performance and PC efficiency in comparison to unsensitized and Pd sensitized TiO2 thin films. For Au sensitized film, gas sensitivity, response time, and recovery time are found to be 32% (14% for TiO2), 80 s, and 100 s, respectively, and PC efficiency is found to be 26.6% (16.9% for TiO2).http://dx.doi.org/10.1155/2013/370578
spellingShingle Ashok K. Singh
S. B. Patil
Umesh T. Nakate
K. V. Gurav
Effect of Pd and Au Sensitization of Bath Deposited Flowerlike TiO2 Thin Films on CO Sensing and Photocatalytic Properties
Journal of Chemistry
title Effect of Pd and Au Sensitization of Bath Deposited Flowerlike TiO2 Thin Films on CO Sensing and Photocatalytic Properties
title_full Effect of Pd and Au Sensitization of Bath Deposited Flowerlike TiO2 Thin Films on CO Sensing and Photocatalytic Properties
title_fullStr Effect of Pd and Au Sensitization of Bath Deposited Flowerlike TiO2 Thin Films on CO Sensing and Photocatalytic Properties
title_full_unstemmed Effect of Pd and Au Sensitization of Bath Deposited Flowerlike TiO2 Thin Films on CO Sensing and Photocatalytic Properties
title_short Effect of Pd and Au Sensitization of Bath Deposited Flowerlike TiO2 Thin Films on CO Sensing and Photocatalytic Properties
title_sort effect of pd and au sensitization of bath deposited flowerlike tio2 thin films on co sensing and photocatalytic properties
url http://dx.doi.org/10.1155/2013/370578
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