Binder-Free Hexagonal Boron Nitride Nanosheets (BNNSs) as Protective Coatings for Copper, Steel, and Wood: A Review

Hexagonal boron nitride (h-BN) has emerged as a promising dielectric material for protecting metallic substrates such as copper and steel under ambient conditions. The layered structure of h-BN offers significant potential in preventing the oxidation and corrosion of these substrates. Due to their i...

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Main Authors: Muhammad Faheem Maqsood, Syed Muhammad Zain Mehdi, Arslan Ashraf, Umair Azhar, Naseem Abbas, Muhammad Asim Raza, Mohammed Amer
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Crystals
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Online Access:https://www.mdpi.com/2073-4352/15/1/99
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author Muhammad Faheem Maqsood
Syed Muhammad Zain Mehdi
Arslan Ashraf
Umair Azhar
Naseem Abbas
Muhammad Asim Raza
Mohammed Amer
author_facet Muhammad Faheem Maqsood
Syed Muhammad Zain Mehdi
Arslan Ashraf
Umair Azhar
Naseem Abbas
Muhammad Asim Raza
Mohammed Amer
author_sort Muhammad Faheem Maqsood
collection DOAJ
description Hexagonal boron nitride (h-BN) has emerged as a promising dielectric material for protecting metallic substrates such as copper and steel under ambient conditions. The layered structure of h-BN offers significant potential in preventing the oxidation and corrosion of these substrates. Due to their impermeability, boron nitride nanosheets (BNNSs) do not form a galvanic cell with the underlying metals, enhancing their effectiveness as protective coatings. BNNSs are both thermally and chemically stable, making them suitable for coatings that protect against environmental degradation. Additionally, BNNSs have demonstrated excellent fire resistance, hydrophobicity, and oxidation resistance when applied to wood, functioning as a binder-free, retardant coating that remains effective up to 900 °C in air. This review focuses on the anti-corrosion properties of BNNSs, particularly on copper and steel substrates, and discusses various methods for their application. This article also discusses future perspectives in this field, including the innovative concept of wooden satellites designed for short- and long-term missions.
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series Crystals
spelling doaj-art-9e8601c84d6f44c8bde2bb32ee3feaa92025-01-24T13:28:18ZengMDPI AGCrystals2073-43522025-01-011519910.3390/cryst15010099Binder-Free Hexagonal Boron Nitride Nanosheets (BNNSs) as Protective Coatings for Copper, Steel, and Wood: A ReviewMuhammad Faheem Maqsood0Syed Muhammad Zain Mehdi1Arslan Ashraf2Umair Azhar3Naseem Abbas4Muhammad Asim Raza5Mohammed Amer6Hybrid Materials Centre, Department of Nanotechnology & Advanced Materials Engineering, Sejong University, Seoul 05006, Republic of KoreaHybrid Materials Centre, Department of Nanotechnology & Advanced Materials Engineering, Sejong University, Seoul 05006, Republic of KoreaInstitute of Metallurgy & Materials Engineering, Faculty of Chemical & Materials Engineering, University of Punjab, Lahore 54590, PakistanDepartment of Biology, Chemistry, and Environmental Sciences, American University of Sharjah, Sharjah 26666, United Arab EmiratesDepartment of Mechanical Engineering, Sejong University, Seoul 05006, Republic of KoreaSchool of Chemical Engineering, Yeungnam University, Gyeongbuk 38541, Republic of KoreaDepartment of Mechanical Engineering, Palestine Technical University—Kadoorie, Tulkarm P.O. Box 7, PalestineHexagonal boron nitride (h-BN) has emerged as a promising dielectric material for protecting metallic substrates such as copper and steel under ambient conditions. The layered structure of h-BN offers significant potential in preventing the oxidation and corrosion of these substrates. Due to their impermeability, boron nitride nanosheets (BNNSs) do not form a galvanic cell with the underlying metals, enhancing their effectiveness as protective coatings. BNNSs are both thermally and chemically stable, making them suitable for coatings that protect against environmental degradation. Additionally, BNNSs have demonstrated excellent fire resistance, hydrophobicity, and oxidation resistance when applied to wood, functioning as a binder-free, retardant coating that remains effective up to 900 °C in air. This review focuses on the anti-corrosion properties of BNNSs, particularly on copper and steel substrates, and discusses various methods for their application. This article also discusses future perspectives in this field, including the innovative concept of wooden satellites designed for short- and long-term missions.https://www.mdpi.com/2073-4352/15/1/99boron nitride nanosheets (BNNSs)binder-free coatingscorrosion resistancefire resistancewooden satellite
spellingShingle Muhammad Faheem Maqsood
Syed Muhammad Zain Mehdi
Arslan Ashraf
Umair Azhar
Naseem Abbas
Muhammad Asim Raza
Mohammed Amer
Binder-Free Hexagonal Boron Nitride Nanosheets (BNNSs) as Protective Coatings for Copper, Steel, and Wood: A Review
Crystals
boron nitride nanosheets (BNNSs)
binder-free coatings
corrosion resistance
fire resistance
wooden satellite
title Binder-Free Hexagonal Boron Nitride Nanosheets (BNNSs) as Protective Coatings for Copper, Steel, and Wood: A Review
title_full Binder-Free Hexagonal Boron Nitride Nanosheets (BNNSs) as Protective Coatings for Copper, Steel, and Wood: A Review
title_fullStr Binder-Free Hexagonal Boron Nitride Nanosheets (BNNSs) as Protective Coatings for Copper, Steel, and Wood: A Review
title_full_unstemmed Binder-Free Hexagonal Boron Nitride Nanosheets (BNNSs) as Protective Coatings for Copper, Steel, and Wood: A Review
title_short Binder-Free Hexagonal Boron Nitride Nanosheets (BNNSs) as Protective Coatings for Copper, Steel, and Wood: A Review
title_sort binder free hexagonal boron nitride nanosheets bnnss as protective coatings for copper steel and wood a review
topic boron nitride nanosheets (BNNSs)
binder-free coatings
corrosion resistance
fire resistance
wooden satellite
url https://www.mdpi.com/2073-4352/15/1/99
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