Interdiffusion behavior in sigma-phase using Ni3Al/Mo diffusion couples

The sigmaNiMo( Al) phase was formed using Ni3Al/Mo diffusion couples at 1423, 1473 and 1523 K. The growth of formed phase and the concentration-distance profiles for each component in the diffusion couples were examined by electron probe microanalysis (EPMA). The activation energy for the parabol...

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Bibliographic Details
Main Authors: Zhou C., Gong W., Huang S., Wei H.
Format: Article
Language:English
Published: University of Belgrade, Technical Faculty, Bor 2011-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2011/1450-53391100012Z.pdf
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Summary:The sigmaNiMo( Al) phase was formed using Ni3Al/Mo diffusion couples at 1423, 1473 and 1523 K. The growth of formed phase and the concentration-distance profiles for each component in the diffusion couples were examined by electron probe microanalysis (EPMA). The activation energy for the parabolic growth of σ phase is found to be 525.3 kJ/mol. The concentration dependence and average ternary interdiffusion coefficients in single σ-NiMo(Al) phase were calculated, and the Arrhenius equations of the D for the σ-NiMo(Al) phase are calculated, the diffusional interaction between Ni, Mo and Al in σ-NiMo(Al) phase was studied by the crossinterdiffusion coefficients. Moreover, these results were utilized to explain the σ phase formation and growth in γ’ phase.
ISSN:1450-5339