Adsorption Performance of La(III) and Y(III) on Orange Peel: Impact of Experimental Variables, Isotherms, and Kinetics
To alleviate the environmental problem associated with rare earth wastewater, this research applied waste orange peel (OP) for the adsorption of La(III) and Y(III) from aqueous solution. The adsorption properties of orange peel are characterized using scanning electron microscopy (SEM) and Fourier t...
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SAGE Publishing
2021-01-01
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Series: | Adsorption Science & Technology |
Online Access: | http://dx.doi.org/10.1155/2021/7189639 |
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author | Li Liu Yunzhang Rao Changshun Tian Tao Huang Jiacheng Lu Meidao Zhang Min Han |
author_facet | Li Liu Yunzhang Rao Changshun Tian Tao Huang Jiacheng Lu Meidao Zhang Min Han |
author_sort | Li Liu |
collection | DOAJ |
description | To alleviate the environmental problem associated with rare earth wastewater, this research applied waste orange peel (OP) for the adsorption of La(III) and Y(III) from aqueous solution. The adsorption properties of orange peel are characterized using scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR), and the participation of hydroxyl and other oxygen-containing groups that promote the physical-chemical interaction is verified. Batch adsorption results suggest that orange peel possesses a satisfactory adsorption performance for La(III) and Y(III). The optimal adsorption conditions were obtained at pH of 6, temperature of 40°C, appropriate dosage of 2 g/L and 3 g/L, contact time of 30 min, and initial ion concentration of 32 mg/L. Under the same condition, adsorption performance of La(III) is better than that of Y(III). The experimental data is well fitted by the Langmuir isotherm model with correlation coefficient R2>0.9 and the minimum standard error values. Equilibrium results show that Langmuir monolayer adsorption capacity of La(III) and Y(III) onto orange peel is up to 37.61 and 31.10 mg/g. The fitting results of kinetics prove that the adsorption process of La(III) and Y(III) follows the pseudosecond-order model. Thus, natural orange peel as a recyclable biosorbent has potential economic and applicative benefits to remove La(III) and Y(III) from aqueous solutions. |
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id | doaj-art-9c04d2565d454ab0a646367289ec28ad |
institution | Kabale University |
issn | 0263-6174 2048-4038 |
language | English |
publishDate | 2021-01-01 |
publisher | SAGE Publishing |
record_format | Article |
series | Adsorption Science & Technology |
spelling | doaj-art-9c04d2565d454ab0a646367289ec28ad2025-02-03T10:07:23ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382021-01-01202110.1155/2021/71896397189639Adsorption Performance of La(III) and Y(III) on Orange Peel: Impact of Experimental Variables, Isotherms, and KineticsLi Liu0Yunzhang Rao1Changshun Tian2Tao Huang3Jiacheng Lu4Meidao Zhang5Min Han6School of Resources and Environment Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaSchool of Resources and Environment Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaSchool of Resources and Environment Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaSchool of Resources and Environment Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaSchool of Resources and Environment Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaSchool of Resources and Environment Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaSchool of Resources and Environment Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaTo alleviate the environmental problem associated with rare earth wastewater, this research applied waste orange peel (OP) for the adsorption of La(III) and Y(III) from aqueous solution. The adsorption properties of orange peel are characterized using scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR), and the participation of hydroxyl and other oxygen-containing groups that promote the physical-chemical interaction is verified. Batch adsorption results suggest that orange peel possesses a satisfactory adsorption performance for La(III) and Y(III). The optimal adsorption conditions were obtained at pH of 6, temperature of 40°C, appropriate dosage of 2 g/L and 3 g/L, contact time of 30 min, and initial ion concentration of 32 mg/L. Under the same condition, adsorption performance of La(III) is better than that of Y(III). The experimental data is well fitted by the Langmuir isotherm model with correlation coefficient R2>0.9 and the minimum standard error values. Equilibrium results show that Langmuir monolayer adsorption capacity of La(III) and Y(III) onto orange peel is up to 37.61 and 31.10 mg/g. The fitting results of kinetics prove that the adsorption process of La(III) and Y(III) follows the pseudosecond-order model. Thus, natural orange peel as a recyclable biosorbent has potential economic and applicative benefits to remove La(III) and Y(III) from aqueous solutions.http://dx.doi.org/10.1155/2021/7189639 |
spellingShingle | Li Liu Yunzhang Rao Changshun Tian Tao Huang Jiacheng Lu Meidao Zhang Min Han Adsorption Performance of La(III) and Y(III) on Orange Peel: Impact of Experimental Variables, Isotherms, and Kinetics Adsorption Science & Technology |
title | Adsorption Performance of La(III) and Y(III) on Orange Peel: Impact of Experimental Variables, Isotherms, and Kinetics |
title_full | Adsorption Performance of La(III) and Y(III) on Orange Peel: Impact of Experimental Variables, Isotherms, and Kinetics |
title_fullStr | Adsorption Performance of La(III) and Y(III) on Orange Peel: Impact of Experimental Variables, Isotherms, and Kinetics |
title_full_unstemmed | Adsorption Performance of La(III) and Y(III) on Orange Peel: Impact of Experimental Variables, Isotherms, and Kinetics |
title_short | Adsorption Performance of La(III) and Y(III) on Orange Peel: Impact of Experimental Variables, Isotherms, and Kinetics |
title_sort | adsorption performance of la iii and y iii on orange peel impact of experimental variables isotherms and kinetics |
url | http://dx.doi.org/10.1155/2021/7189639 |
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