Adsorption Performance of La(III) and Y(III) on Orange Peel: Impact of Experimental Variables, Isotherms, and Kinetics

To alleviate the environmental problem associated with rare earth wastewater, this research applied waste orange peel (OP) for the adsorption of La(III) and Y(III) from aqueous solution. The adsorption properties of orange peel are characterized using scanning electron microscopy (SEM) and Fourier t...

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Main Authors: Li Liu, Yunzhang Rao, Changshun Tian, Tao Huang, Jiacheng Lu, Meidao Zhang, Min Han
Format: Article
Language:English
Published: SAGE Publishing 2021-01-01
Series:Adsorption Science & Technology
Online Access:http://dx.doi.org/10.1155/2021/7189639
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author Li Liu
Yunzhang Rao
Changshun Tian
Tao Huang
Jiacheng Lu
Meidao Zhang
Min Han
author_facet Li Liu
Yunzhang Rao
Changshun Tian
Tao Huang
Jiacheng Lu
Meidao Zhang
Min Han
author_sort Li Liu
collection DOAJ
description To alleviate the environmental problem associated with rare earth wastewater, this research applied waste orange peel (OP) for the adsorption of La(III) and Y(III) from aqueous solution. The adsorption properties of orange peel are characterized using scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR), and the participation of hydroxyl and other oxygen-containing groups that promote the physical-chemical interaction is verified. Batch adsorption results suggest that orange peel possesses a satisfactory adsorption performance for La(III) and Y(III). The optimal adsorption conditions were obtained at pH of 6, temperature of 40°C, appropriate dosage of 2 g/L and 3 g/L, contact time of 30 min, and initial ion concentration of 32 mg/L. Under the same condition, adsorption performance of La(III) is better than that of Y(III). The experimental data is well fitted by the Langmuir isotherm model with correlation coefficient R2>0.9 and the minimum standard error values. Equilibrium results show that Langmuir monolayer adsorption capacity of La(III) and Y(III) onto orange peel is up to 37.61 and 31.10 mg/g. The fitting results of kinetics prove that the adsorption process of La(III) and Y(III) follows the pseudosecond-order model. Thus, natural orange peel as a recyclable biosorbent has potential economic and applicative benefits to remove La(III) and Y(III) from aqueous solutions.
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institution Kabale University
issn 0263-6174
2048-4038
language English
publishDate 2021-01-01
publisher SAGE Publishing
record_format Article
series Adsorption Science & Technology
spelling doaj-art-9c04d2565d454ab0a646367289ec28ad2025-02-03T10:07:23ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382021-01-01202110.1155/2021/71896397189639Adsorption Performance of La(III) and Y(III) on Orange Peel: Impact of Experimental Variables, Isotherms, and KineticsLi Liu0Yunzhang Rao1Changshun Tian2Tao Huang3Jiacheng Lu4Meidao Zhang5Min Han6School of Resources and Environment Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaSchool of Resources and Environment Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaSchool of Resources and Environment Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaSchool of Resources and Environment Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaSchool of Resources and Environment Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaSchool of Resources and Environment Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaSchool of Resources and Environment Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaTo alleviate the environmental problem associated with rare earth wastewater, this research applied waste orange peel (OP) for the adsorption of La(III) and Y(III) from aqueous solution. The adsorption properties of orange peel are characterized using scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR), and the participation of hydroxyl and other oxygen-containing groups that promote the physical-chemical interaction is verified. Batch adsorption results suggest that orange peel possesses a satisfactory adsorption performance for La(III) and Y(III). The optimal adsorption conditions were obtained at pH of 6, temperature of 40°C, appropriate dosage of 2 g/L and 3 g/L, contact time of 30 min, and initial ion concentration of 32 mg/L. Under the same condition, adsorption performance of La(III) is better than that of Y(III). The experimental data is well fitted by the Langmuir isotherm model with correlation coefficient R2>0.9 and the minimum standard error values. Equilibrium results show that Langmuir monolayer adsorption capacity of La(III) and Y(III) onto orange peel is up to 37.61 and 31.10 mg/g. The fitting results of kinetics prove that the adsorption process of La(III) and Y(III) follows the pseudosecond-order model. Thus, natural orange peel as a recyclable biosorbent has potential economic and applicative benefits to remove La(III) and Y(III) from aqueous solutions.http://dx.doi.org/10.1155/2021/7189639
spellingShingle Li Liu
Yunzhang Rao
Changshun Tian
Tao Huang
Jiacheng Lu
Meidao Zhang
Min Han
Adsorption Performance of La(III) and Y(III) on Orange Peel: Impact of Experimental Variables, Isotherms, and Kinetics
Adsorption Science & Technology
title Adsorption Performance of La(III) and Y(III) on Orange Peel: Impact of Experimental Variables, Isotherms, and Kinetics
title_full Adsorption Performance of La(III) and Y(III) on Orange Peel: Impact of Experimental Variables, Isotherms, and Kinetics
title_fullStr Adsorption Performance of La(III) and Y(III) on Orange Peel: Impact of Experimental Variables, Isotherms, and Kinetics
title_full_unstemmed Adsorption Performance of La(III) and Y(III) on Orange Peel: Impact of Experimental Variables, Isotherms, and Kinetics
title_short Adsorption Performance of La(III) and Y(III) on Orange Peel: Impact of Experimental Variables, Isotherms, and Kinetics
title_sort adsorption performance of la iii and y iii on orange peel impact of experimental variables isotherms and kinetics
url http://dx.doi.org/10.1155/2021/7189639
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